Patents Examined by John F. Terapane
  • Patent number: 4941996
    Abstract: Inclusion complexes, comprising a host and a guest, that exhibit greater second harmonic generation efficiency than either the host or the guest exhibits by itself. Preferred hosts can be selected from cyclodextrins, cyclodextrin derivatives, and cyclodextrin polymers. Preferred guests can be selected from aromatic compounds in which the molecule contains both an electron-donating functional group and an electron-withdrawing functional group.
    Type: Grant
    Filed: October 19, 1987
    Date of Patent: July 17, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John E. Trend, Kent B. Rochford
  • Patent number: 4938925
    Abstract: A method of inhibiting corrosion of metal equipment in wells comprises contacting the metal surfaces with an inhibiting amount of a corrosion inhibitor which is the reaction product of a compound containing a carbonyl group (e.g. aldehydes), an amine, and a thiocyanate.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: July 3, 1990
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Philip R. Petersen, Larry G. Coker, Daniel S. Sullivan, III
  • Patent number: 4938900
    Abstract: Microcapsules are prepared by adding a methylolated melamine or methylolated urea to an aqueous emulsion of the core material dispersed in an aqueous solution of a styrene/maleic anhydride copolymer partially hydrolyzed in an alkaline condition and heating the mixture at 40.degree. to 90.degree. C. in an acidic condition so that a reaction product forming the capsule walls is produced by the esterification reaction between the carboxyl groups in the partial hydrolysis product and the methylol groups in the methylolated melamine or urea and the amidation reaction between the carboxylic anhydride groups in the former and the amino groups in the latter. By virtue of the three dimensional network structure, the capsule walls are very dense and highly resistant against heat, water and solvents.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: July 3, 1990
    Assignee: Toppan Moore Co., Ltd.
    Inventors: Masafumi Moriwaki, Kei Etoh, Hiroyuki Sekihara
  • Patent number: 4936995
    Abstract: Described are novel spiro(benzindolino) benzoxazine compounds and compositions containing such compounds. Photochromic sprio(benzindolino) benzoxazines may be incorporated into plastic host materials to produce photochromic articles.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: June 26, 1990
    Assignee: PPG Industries, Inc.
    Inventor: Patricia L. Kwiatkowski
  • Patent number: 4935557
    Abstract: This invention relates to the preparation of a mixture of nitroaromatic compositions, particularly a mixture of mononitrobenzene and dinitrotoluene. The conitration of a mixture of aromatic hydrocarbons is accomplished by contacting the mixture of hydrocarbons with nitric acid, in the absence of sulfuric acid, at temperatures of from about 40.degree. to 70.degree. C. By the use of nitric acid alone, one avoids the heterogeneous nitration associated with the use of sulfuric acid and thereby one can effectively produce a reaction mixture containing mononitrobenzene and dinitrotoluene.
    Type: Grant
    Filed: August 7, 1984
    Date of Patent: June 19, 1990
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Richard V. Carr, Bernard A. Toseland
  • Patent number: 4933055
    Abstract: A novel method for the production of bis(arene) technetium radiodiagnostic imaging agents is herein disclosed. The method consists of employing Fischer synthesis reactants in an ultrasonic bath. The products are virtually pure, thus lacking the severe degree of disproportionation which routinely occurs when partially alkylated bis(arene)technetium compounds are produced by thermally driven reactions.
    Type: Grant
    Filed: June 17, 1987
    Date of Patent: June 12, 1990
    Assignee: Mallinckrodt, Inc.
    Inventor: Dennis W. Wester
  • Patent number: 4931208
    Abstract: A ferroelectric liquid crystal composition having a long helical pitch and a light switching element having a quick response property are provided. This composition comprises (1) at least one member selected from the group consisting of liquid crystal compounds having a smectic C phase and no helical structure and liquid crystal compounds having only a nematic phase as a liquid crystal phase and no helical structure and (2) at least one chiral smectic liquid crystal compound.
    Type: Grant
    Filed: August 3, 1988
    Date of Patent: June 5, 1990
    Assignees: Chisso Corporation, Hitachi, Ltd.
    Inventors: Kenji Furukawa, Kanetsugu Terashima
  • Patent number: 4931194
    Abstract: The recovery of oil or gas from underground porous formations bearing such hydrocarbons is enhanced by using an injection fluid containing a viscosifying amount of a poly(vinylamine) formed in-situ by hydrolysis of a high molecular weight poly(N-vinylamide). The hydrolysis conditions are strongly acidic or highly alkaline and include the elevated temperature of the formation.The poly(N-vinylamide), such as poly(N-vinylformamide), can be made by inverse emulsion polymerization and the high solids emulsion mixed directly with the acidic or basic solutions to form the injection fluid.The process is applicable to enhanced oil recovery using fluids for water-flooding, well completion or workover, and acidifying or fracturing.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: June 5, 1990
    Inventors: Robert K. Pinschmidt, Jr., Ta-Wang Lai
  • Patent number: 4929091
    Abstract: Thermochromic compounds containing the [Pt(dipic)Cl].sup.- anion. These compounds are yellow and monomeric at high temperatures or in low concentrations and abruptly change to red and polymeric at low temperatures or higher solution concentrations. This unusual property allows them to be used as temperature sensors.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: May 29, 1990
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Nenad M. Kostic, Xia-Ying Zhou
  • Patent number: 4927980
    Abstract: A process is disclosed for preparing fluoroaromatic compounds (such as fluoronitrobenzene compounds) by reaction of corresponding chloroaromatic compounds (such as chloronitrobenzene compounds) with alkali metal fluoride salts in the presence of alkyldiorganoaminopyridinium salts as phase transfer catalysts. A secondary carbon atom is directly attached to the alkyl carbon atom which is directly attached to the ring nitrogen atom. A preferred catalyst is N-(2-ethylhexyl)-4-(N',N'- dimethylamino)pyridinium chloride.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: May 22, 1990
    Assignee: Mallinckrodt Inc.
    Inventor: Gary L. Cantrell
  • Patent number: 4925592
    Abstract: A liquid crystal composition comprising at least a compound I represented by the following general formula (I) and a compound II represented by the following general formula (II): ##STR1## where n, m are natural numbers, R.sub.1 and R.sub.2 indicate alkyl group having different asymetric carbon structures on their derivatives. Thus, the lower limiting of temperature the Sc* phase of the liquid crystal composition can be reduced by adding in combination the compounds I and II to a liquid crystal composition. The mixture will exhibit an Sc* phase at the room temperature and especially at much lower temperatures.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: May 15, 1990
    Assignee: Alps Electric Co., Ltd.
    Inventor: Mitsuru Kano
  • Patent number: 4925578
    Abstract: Improved solutions are proposed for an oil recovery process in which oil is displaced by a viscous alkaline aqueous solution. The improved aqueous alkaline solution contains a water-thickening partially hydrolyzed polyacrylamide polymer and a stabilizer consisting essentially of a 2-mercaptobenzothiazole in the presence of a sulfur-containing oxygen scavenger. A readily oxidizable alcohol or glycol may also be included.
    Type: Grant
    Filed: July 29, 1988
    Date of Patent: May 15, 1990
    Assignee: Shell Oil Company
    Inventors: Jeffrey G. Southwick, Richard C. Nelson
  • Patent number: 4925278
    Abstract: Compounds of the formula ##STR1## wherein m represents is the number 0 or 1; A is a single covalent bond, --CH.sub.2 --CH.sub.2 --, --OCH.sub.2 --, --COO-- or --OOC--; rings B, C and D are 1,4-phenylene optionally substituted with cyano, halogen or lower alkyl; Y.sup.1 and Y.sup.2 are hydrogen or one of them also is cyano; and R.sup.1 and R.sup.2 each represents C.sub.1 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 alkenyl, either of which is optionally halogen-substituted, in which one CH.sub.2 group or two non-adjacent CH.sub.2 groups is/are optionally replaced by oxygen; with the provisos that at least one of R.sup.1 and R.sup.2 has a chiral carbon atom or a C-C double bond or both when A is --COO-- and at least one of R.sup.1 and R.sup.2 has a C-C double bond when A is a single covalent bond, their preparation, liquid crystalline mixtures containing these compounds and their use for electro-optical purposes are described.
    Type: Grant
    Filed: December 13, 1988
    Date of Patent: May 15, 1990
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Richard Buchecker, Hans-Jurgen Fromm, Stephen Kelly, Martin Schadt
  • Patent number: 4925591
    Abstract: Disclosed is a mesomorphic compound having a .beta.-hydroxycarboxyl group as the chiral source, which is represented by the formula: ##STR1## wherein m and n are integers of from 1 to 18, X.sub.1 and X.sub.2 independently represent fluorine, chlorine or hydrogen, Y represents ##STR2## or --O--, Z represents a direct bond, ##STR3## --CH hd 2O-- or --OCH.sub.2 --, and * indicates the asymmetric carbon. The mesomorphic compound is valuable as a ferroelectric liquid crystal or an additive to a ferroelectric liquid crystal or to a compound showing the SmC phase and having no chiral group.
    Type: Grant
    Filed: December 22, 1988
    Date of Patent: May 15, 1990
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Jun Nakauchi, Mioko Uematsu, Keiichi Sakashita, Yoshitaka Kageyama, Seiji Hayashi, Kenji Mori
  • Patent number: 4923634
    Abstract: A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: May 8, 1990
    Assignee: Nalco Chemical Company
    Inventors: John E. Hoots, Donald A. Johnson, Dodd W. Fong, James F. Kneller
  • Patent number: 4923753
    Abstract: A controlled release composition for use with liquid acids, and a method of preparation is disclosed. The composition comprises (1) a porous matrix comprising and substantially inert to an absorbed acid; (2) a midlayer surrounding the matrix, this midlayer consisting essentially of a salt of the absorbed acid; and (3) a membrane surrounding the matrix, the membrane being exterior of the midlayer, the membrane further being substantially inert to the midlayer and permeable to a selected environment, the thickness and permeability of the membrane comprising means for controlling diffusion of the environment therethrough.The midlayer can be applied as a coating to the acid-bearing matrix, or it can be evolved by exposing the acid-bearing matrix to a base such as ammonia gas or a solid metal oxide for a time sufficient to allow reaction of a proportion of the acid at or near the surface of the matrix with the base to form a layer of the corresponding salt.
    Type: Grant
    Filed: March 26, 1987
    Date of Patent: May 8, 1990
    Assignee: The Dow Chemical Company
    Inventors: Wilhelm E. Walles, Donald L. Tomkinson
  • Patent number: H788
    Abstract: A method for bonding plastic to a metallic member is described which comprises the steps of forming a preselected pattern of etched cavities in the metallic surface to be bonded, which cavities at least in part increase in width with depth of etching, and subsequently applying a plastic layer to the metallic surface so that a portion of the applied plastic layer fills the cavities and form an interlock with the metallic surface.
    Type: Grant
    Filed: May 31, 1989
    Date of Patent: June 5, 1990
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: Clayton J. Schneider, Jr.
  • Patent number: H790
    Abstract: The present invention relates to a thermally stable modified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein a primary or secondary amine functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: June 5, 1990
    Inventors: William P. Gergen, Robert G. Lutz, Carl L. Willis
  • Patent number: H791
    Abstract: A multilayer analytical element for quantitative analysis of bilirubin in a liquid sample by a diazo method, which comprises a laminated structure consisting essentially of:(1) a porous reagent layer containing an acidic binder and a diazonium salt being reactive to bilirubin to produce azobilirubin;(2) an absorbent layer capable of absorbing an excessive liquid portion; and(3) a liquid-impermeable light-transmissive support.
    Type: Grant
    Filed: October 8, 1987
    Date of Patent: June 5, 1990
    Inventors: Harumi Katsuyama, Shigeki Kageyama, Shigeru Nagatomo
  • Patent number: H799
    Abstract: An apparatus which produces an aerosol having a narrow size distribution. e apparatus includes a supply means for providing a primary aerosol stream having a wide size distribution. Concentration means are positioned to receive the stream and this concentration means includes means for reducing volume flow rate without disregarding a proportionate fraction of the particles to provide a reduced flow rate stream. Venturi means are provided to monitor the stream and transfer the stream. Impactor means are provided for receiving the stream and introducing a core of clean air into the center of the stream. Means are provided for adjusting the relative velocities of the stream and the core to exclude particles having an inertia below a predetermined size, thereby eliminating smaller particles. Outlet impactor means are positioned to receive the stream and the core, for removing particles larger than a predetermined size.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: July 3, 1990
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: William E. Farthing, Randal S. Martin, Kenneth M. Cushing