Abstract: A composition useful as a blowing agent having no flash point or reduced combustibility comprising 2-chloropropane and a gas selected from the group consisting of a fluorohydrocarbon, perfluorocarbons, fluoroethers, hydrofluoropolyethers and mixtures thereof is disclosed. A polyisocyanurate foam or a polyurethane modified polyisocyanurate foam having a mainly closed cell structure and also a method for preparing this foam, the latter comprising closed cells wherein a foam blowing agent consisting of a mixture of 2-chloropropane and one or more HFC compounds including pentafluoropropane, pentafluorobutane, heptafluoropropane, hexafluoropropane or pentafluoroethane are disclosed. Pentanes can be added if desired. Azeotropic mixtures in which 2-chloropropane is an ingredient are disclosed.

Abstract: The invention relates to a flame-retardant coating which forms an insulating layer and is based on substances which carbonize and which form a foam layer in the event of a fire, on film-forming binders, on blowing agents and on customary auxiliaries and additives, wherein the blowing agent and foam layer forming substance present comprises melamine polyphosphate. The novel flame-retardant coating which forms an insulating layer is particularly stable under tropical conditions (at up to 100% rel. humidity, about 75° C.), i.e. it releases only an extremely small amount of NH3.

Abstract: Rigid foams having excellent compression strength, dimensional stability, flame retardance and adhesion are produced by reacting an active hydrogen compound having at least two functionalities with a polyisocyanate compound in the presence of a catalyst and a blowing agent comprising either water alone or a mixture of water and a low boiling compound, wherein (1) the polyisocyanate compound is a prepolymer obtained by reacting a polymeric MDI with 5 to 30% by weight, based on the polymeric MDI, of a polyether polyol and/or polyester polyol having a hydroxyl value of at most 100 mg KOH/g, and (2) the number of isocyanate groups in the polyisocyanate compound is at least 1.5 times by mole as large as the number of active hydrogen atoms in the active hydrogen compound and water.

Abstract: This invention relates to flame-laminable polyurethane block foams having high peel strength, a process for their production and the use thereof for textile lamination.

Abstract: This invention provides azeotrope-like compositions of 1,1,1,2-tetrafluoroethane, 1,1,1,3,3-pentafluoropropane-245fa and water that are environmentally desirable for use as refrigerants, aerosol propellants, metered dose inhalers, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.

Abstract: Reticulated flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture (b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and further assistants and additives (f), by a process in which the polyetherol mixture (b) comprises b1) at least one difunctional or polyfunctional polyetherol having an OH number of from 20 to 150 mg KOH/g, based on propylene oxide and/or butylene oxide and ethylene oxide and having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, (b1.

Abstract: A process for producing a rigid polyurethane foam provides a rigid polyurethane foam having a closed-cell size of about 80-130 &mgr;m and thus, improved heat insulating properties.

Abstract: This invention provides azeotrope-like compositions of 1,1,1,2-tetrafluoroethane, 1,1,1,3,3-pentafluoropropane-245fa and 2-methylbutane that are environmentally desirable for use as refrigerants, aerosol propellants, metered dose inhalers, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.

Abstract: Integrally bonded composite polyurethane foams substantially free from coalescence and with no discernable bond or structural interface layer when viewed at 50× magnification can be formed by wet casting a second foamed polyurethane composition onto a first wet cast foamed polyurethane composition and simultaneously curing the cast foams. In a preferred embodiment, one curable polyurethane composition forms a slow recovery foam and the other curable polyurethane composition forms a resilient foam.

Abstract: Microporous materials and articles are disclosed. The microporous materials contain a crystallizable propylene-containing polymer, a beta-nucleating agent, and a diluent that is miscible with the polymer at a temperature above the melting temperature of the polymer and that phase separates from the polymer at a temperature below the polymer crystallization temperature. The invention is also directed to methods of forming the microporous material using thermal induced phase separation and subsequent processing.

Abstract: This invention relates to flame-laminable polyurethane block foams having high peel strength, a process for their production and the use thereof for textile lamination.

Abstract: New, useful and surprisingly effective antiscorch compositions for utilization within polyurethane foam production methods which utilize very popular tertiary amine catalysts are provided. Such compositions require the presence of nominal yet effective amounts of organic cyclic ester materials. The ring systems of such materials appear to open during exposure to heat (during the curing process) and release carboxylic acids into the curing formulation. The tertiary amines become quenched by the carboxylic acids and thus do not exhibit heat destabilization. The resultant foams exhibit extremely low, if no, areas of excessive heating (i.e., scorch) and thus are substantially uniformly colored throughout. The processes and resultant foams are also contemplated within this invention.

Abstract: Foam forming techniques capable of permitting foaming of biodegradable resin to be positively and uniformly accomplished to provide a biodegradable resin foam with satisfactory quality. The biodegradable resin foam is made of biodegradable resin consisting of a main biodegradable resin ingredient of 100° C. or more in melting point and a low-melting biodegradable resin ingredient of 100° C. or less in melting point. The biodegradable resin foam is produced by placing a starting material consisting of at least biodegradable resin and a substantial amount of moisture in a heated and pressurized environment, releasing the starting material from the environment to foam the biodegradable resin, and subjecting the foamed resin to forming by means of a forming mold. An apparatus for producing the foamed biodegradable resin foam includes a pressure adjusting chamber, an air-permeable forming mold, a pressure reducing tank and an injection machine.

Abstract: Urethane molded products for polishing pad comprise two types of cells having different sizes in urethane molded products formed by mixing and curing an isocyanate-terminated urethane prepolymer and an active hydrogen-containing compound. The molded products may be made by a procedure comprising mixing expanded microballoons or non-expanded, thermally expandable microspheres and water with the isocyanate-terminated urethane prepolymer and active hydrogen-containing compound and curing the mixture.

Abstract: In a method for improving antistatic properties, the improvement comprising the use of an antistatic composition comprising an ionic antistatic compound and a polar organic solvent; an antistatic composition comprising a nonmetallic antistatic compound, a metallic antistatic compound and a polar organic solvent; a formed article containing an antistatic composition comprising an ionic antistatic compound and a polar organic solvent; and a process for producing a polyurethane foam comprising reacting a polyol solution comprising a polyol component, a blowing agent and a catalyst, with an isocyanate prepolymer in the presence of an antistatic composition comprising an ionic antistatic compound and a polar organic solvent. The antistatic composition can be suitably used as shoe soles for safety shoes, working shoes, and the like.

Abstract: An internal gear set comprising an inner rotor having a number of radially projecting cylindrical tooth members engaging a conjugate internally toothed outer rotor. The latter has one more tooth than there are tooth members on the inner rotor and is mounted eccentrically to the inner rotor so that the rotors move conjugately relative to one other.

Abstract: The invention relates to a one-shot or prepolymer process for preparing a visco-elastic polyurethane foam by reacting a polyisocyanate composition with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; and b4) a polyalkyleneglycol; according to the following proportions: b1: 30-85 wt %, b2: 5-65 wt %, b3: 5-40 wt %, b4: 0-50 wt %. The invention also relates to reaction systems comprising the above components and to the polyol composition.

Abstract: The invention relates to the use of silicone-polyether copolymers of the formula I as surface-active substances in the production of polyurethane foams.

Abstract: This invention relates to a process for the preparation of an isotropic rigid foam comprising the step of reacting: (A) an organic polyisocyanate component selected from the group consisting of: (1) a polymethylene poly(phenylisocyanate) and (2) an NCO-terminated prepolymer, and comprising the reaction product of: (a) a polyester comprising the reaction product of (i) pure ortho-phthalic acid or phthalic anhydride and (ii) a glycol and (b) a polymethylene poly(phenylisocyanate); with (B) an isocyanate-reactive component comprising: (1) a liquid OH-terminated prepolymer having a viscosity of more than about 100,000 mPa·s at 25° C.

Abstract: A composition for production of cover packing, comprising: (A) a blocked isocyanate, (B) an active hydrogen group-containing compound having average two or more functional groups, (C) an organic substance powder having an average particle diameter of 40 to 250 &mgr;m, and (D) an inorganic substance powder having an average particle diameter of less than 40 &mgr;m; and a method for production of cover packing using the composition. With this composition which is a one-pack type, curable composition, no apparatus for mixing the main material and the curing agent is required; by heating, dissociation of blocking agent and completion of reaction are allowed to take place simultaneously; and a cover packing superior in mechanical strength, etc. can be formed.