Abstract: The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers. The improved aqueous dispersions comprise polymer particles of a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized thereon, which are shelf stable and self crosslinkable at a low temperature. The polyurethanes have pendant carboxyl functionality in quaternary form and pendant epoxide groups provided by glycidyl acrylates and/or methacrylates. When the aqueous dispersions are cast as film and the water is removed, crosslinking between the carboxyl group and the epoxide group occurs.
Type:
Grant
Filed:
June 16, 1997
Date of Patent:
November 2, 1999
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Chao-Fong Tien, Chung-Ling Mao, Jeanine M. Snyder, Adalgery Beck