Abstract: The invention generally relates to linear-bottlebrush-linear copolymer blocks and methods of making and using same. The disclosed copolymer blocks can be useful in, for example, the formation of polymer networks that replicate biological stress-strain behavior. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: A functionalized macromolecule includes a hydrogenated interpolymer portion, a non-hydrogenated polymer portion, and the radical of a functional coupling agent covalently bonded to and linking those portions. The functional group of the coupling agent exhibits interactivity with silica. The interpolymer can include vinyl aromatic mer and conjugated diene mer, with at least some of the latter, typically at least 50 mole percent, having been hydrogenated.

Abstract: A 1,3-dipolar compound including an epoxide group is provided. The epoxide group is a 3-membered ether ring in which a first member is a carbon atom having an attachment to the dipole of the 1,3-dipolar compound and a second member is a tertiary or quaternary carbon. The use of the 1,3-dipolar compound in the modification of a diene polymer makes it possible to improve the rupture properties of a rubber composition comprising the modified polymer, without the expense of its hysteresis properties, while at the same time improving its implementation.

Abstract: A method for forming a benzophenone-containing emulsion is provided. The method includes a step of forming a pre-emulsion by combining a monomer composition with a benzophenone or a benzophenone derivative in water, the monomer composition including one or more monomers selected from the group consisting of (meth)acrylic acid monomers and (meth)acrylic monomers, vinyl acetate, aromatic monomers, vinyl neodecanoate, and combinations thereof. The pre-emulsion is polymerized by combining the pre-emulsion with a radical initiator in a reactor to form a reaction mixture that polymerizes to form an emulsion polymer. This procedure implements novel and easily polymerizable benzophenone (meth)acrylates) into the polymer backbone preventing them from leaching out of finished coatings. Advantageously, the benzophenone-containing emulsions can be used to form paint coatings with dirt pick-up resistance while maintaining the excellent flexibility of paint finishes to limit cracking of the final film.

Abstract: Provided is a powder mixture for powder metallurgy that has excellent fluidity, can be ejected from a green compacting die with little force, and can suppress die galling in forming. The powder mixture comprises: a raw material powder; a copper powder; a binder; a graphite powder; and carbon black. The raw material powder contains an iron-based powder in an amount of 90 mass % or more with respect to the raw material powder. An average particle size of the graphite powder is less than 5 ?m. Additive amounts of the binder, the graphite powder, the copper powder, and the carbon black are in specific ranges. A surface of the raw material powder is coated with at least part of the binder. A surface of the binder is coated with at least part of the graphite powder, at least part of the copper powder, and at least part of the carbon black.

Abstract: Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

Abstract: A polyarylene sulfide resin composition which yields a molded article with excellent toughness, as well as a molded article and an optical ferrule, which are produced using the polyarylene sulfide resin composition. In a polyarylene sulfide resin composition containing a polyarylene sulfide resin and silica particles, a specific amount of a polyarylene sulfide resin having a melt viscosity of 35 to 80 Pa·s, and a specific amount of silica particles having a lower content of coarse powders with a particle size of 45 ?m or more are employed.

Abstract: The present invention is related to the use of ethylene alkanoate-alkyl acrylate bipolymers with a high randomness monomers distribution, which are synthesized by semicontinuous emulsion polymerization process, characterized because it is carried out using slow addition rate of the pre-emulsion feeding ({dot over (q)}?0.009 kgL·L?1·min?1), stabilized this last one by alkyl glycol ether type surfactants, at temperatures higher than 75° C. and with solids contents above 25 wt %, which avoids the formation of large sequences (blocks) of a same monomer. This structural characteristic gives the ethylene alkanoate-alkyl acrylate bipolymers a high efficiency as chemical agents for removal of complex water/crude oil emulsions of crude oil blends.

Abstract: The present disclosure provides a composition for preparing a vinyl chloride-based polymer, including a vinyl chloride-based first seed; a vinyl chloride-based second seed; an initiator composition including a water-soluble initiator and an oil-soluble initiator; a reducing agent; and a vinyl chloride-based monomer, wherein a metal catalyst is not included in the composition, and a method for preparing a vinyl chloride-based polymer using the same.

Abstract: The present invention relates to a hot melt film containing a biomass-based thermoplastic polyurethane resin, and is not only environmentally friendly to the human body as it contains a biomass-based thermoplastic polyurethane resin prepared by reacting a biomass-derived polyol with a diol-based chain extender and diisocyanate in a range of 20-70% by weight, accordingly, by containing hydrophobic nano-silica, it is possible to secure properties such as excellent high heat resistance, elasticity, uniform adhesion strength, and excellent durability at the petroleum-based level, and also provides a hot melt film containing a biomass-based thermoplastic polyurethane resin that can prevent overflow during the bonding process and improve the weight and texture of the product.

Abstract: The present invention relates to a resin composition including (A) a polycarbonate resin; (B) an inorganic filler including at least one of calcium carbonate, talc, and wollastonite; (C) a polyolefin-based resin including a glycidyl group; and (D) a phosphorus-based flame retardant, and a molded article manufactured using the same.

Abstract: A modified natural rubber includes a linking structure represented by general formula (C), the linking structure having been formed by allowing polyisoprene, having a structure represented by general formula (A) and/or general formula (B), to bind in the structure to an amino compound having two or more primary amino groups. In the formulae (A) and (B), X represents a hydrogen atom or a methyl group, and Ps represent a polyisoprene unit. In the formula (C), W represents a residue of the amino compound from which amino end groups are removed, and Q represents at least one selected from the group consisting of general formulae (Q-1) to (Q-4), and m represents 2 to 4. In the general formulae (Q-1) to (Q-4), *1 indicates binding to a carbon atom of a polyisoprene unit, and *2 indicates binding to a carbon atom of the residue represented by W.

Abstract: An aqueous acrylic resin with high heat resistance, a polymeric composition, and a method for preparing the aqueous acrylic resin with high heat resistance are provided. The polymeric composition includes a monomer composition and a reactive emulsifier. Based on 100 wt % of the monomer composition, the monomer composition includes at least one alkyl group containing methyl acrylate, at least one carboxyl group containing methacrylic acid, an alkene-based unsaturated group containing methyl acrylate, a hydroxyl group containing acrylic polyester polyol and/or a hydroxyl group containing acrylic polyether polyol, and an alkoxysilane.

Abstract: A breathable and waterproof membrane is made from a modified thermoplastic polyester elastomer. The breathable and waterproof membrane has a moisture permeability of greater than or equal to 25000 g/m2·day. The modified thermoplastic polyester elastomer is formed from a thermoplastic polyester elastomer, a regenerated polyethylene terephthalate, and a compatibilizer. Based on a total weight of the modified thermoplastic polyester elastomer being 100 phr, a content of the regenerated polyethylene terephthalate is greater than 0 phr and up to 50 phr. Based on a total weight of the thermoplastic polyester elastomer being 100 wt %, the thermoplastic polyester elastomer includes 25 wt % to 75 wt % of hard segments and 25 wt % to 75 wt % of soft segments.

Abstract: The present disclosure concerns non-aqueous gel writing ink including a solvent, a coloring agent and a gelling agent, in which the gelling agent is a mixture of silica particles and of a fatty acid amide wax. It also concerns the process of preparation of the non-aqueous gel writing ink and the use of a mixture of silica particles and of a fatty acid amide wax, as a gelling agent in a non-aqueous gel writing ink. It finally concerns a writing instrument containing the ink according to the present disclosure.

Abstract: A biodegradable polymer blend contains at least one component (A), at least one component (B) and at least one component (D), wherein —component (A) includes polymers based on lactic acid —component (B) includes thermoplastic starch (TPS) representing a mixture of starch, at least one plasticizer from the group of substances (C), and at least one modifier from the group of substances (E); —group of substances (C) includes plasticizers for starch —group of substances (E) includes modifiers —component (D) includes homopolymers or copolymers of polyhydroxyalkanoates (PHAs), and/or mixtures thereof, and the biodegradable polymer blend can optionally contain a component (F), wherein —component (F) includes plasticizers for PLAs and/or for PHAs, and the biodegradable polymer blend is prepared in a such way that a composition containing the components (A), (B) and (D) is prepared by blending the components (A) and (B), wherein the component (B) is present in the blend at least in one phase of the blending process wh

Abstract: A production method for a branched conjugated diene-based polymer, comprising: a polymerizing step of obtaining a conjugated diene-based polymer having an active end by polymerizing or copolymerizing a conjugated diene compound, or a conjugated diene compound and an aromatic vinyl compound with an alkali metal compound or an alkaline earth metal compound used as a polymerization initiator; and a branching step of introducing a branch structure by reacting a styrene derivative as a branching agent with the active end of the conjugated diene-based polymer.

Abstract: Disclosed herein are styrene butadiene rubber latex compositions with high solids content and methods for making and using these compositions. The method for making the styrene butadiene rubber latex compositions can include mixing a seed, a styrene, an initiator, a base, a surfactant, and a solvent; adding a first portion of 1,3-butadiene to make a first reaction mixture; heating the first reaction mixture for a first reaction time to make a first styrene butadiene rubber latex; mixing the first styrene butadiene rubber latex, a styrene, a base, an initiator, a surfactant, and a solvent; adding a second portion of 1,3-butadiene to make a second reaction mixture; and heating the second reaction mixture for a second reaction time to make a second styrene butadiene rubber latex, where the second styrene butadiene rubber latex has a solids content higher than that of the first styrene butadiene rubber latex.

Abstract: A method for producing conjugated diene rubber is provided, including: a first step of obtaining a conjugated diene polymer chain having an active end by polymerizing a monomer comprising a conjugated diene compound and a vinyl compound having a functional group interactive with silica using a polymerization initiator in an inert solvent; a second step of reacting a siloxane compound with the active end of the conjugated diene polymer chain having the active end; and a third step of reacting a hydrocarbyloxysilane compound with the conjugated diene polymer chain with which the siloxane compound has been reacted that is obtained in the second step.

Abstract: A method of damping mechanical vibration includes applying on a source of mechanical vibration a formulation including an aqueous polymer emulsion prepared by an emulsion polymerization reaction of at least one emulsion-polymerizable monomer and a support resin.