Abstract: An aqueous dispersion of a hydrophobically-modified alkali-soluble multistage polymer useful as a thickener affording high thickening efficiency and an aqueous coating composition comprising such aqueous dispersion showing good stability after heat aging without compromising stability upon addition of colorants.
Type:
Grant
Filed:
December 25, 2017
Date of Patent:
November 15, 2022
Assignees:
Dow Global Technologies LLC, Rohm and Haas Company
Abstract: A process for producing a thermoformable and/or -embossable fiber/polymer composite using a fibrous lignocellulosic substrate S and a polymer P, which contains i) homogeneously mixing the substrate S and the polymer P, then ii) converting the substrate S/polymer P mixture to a fiber web, and then iii) compacting the resultant fiber web at a temperature not less than the glass transition temperature of the polymer P [TgP] to give a thermoformable and/or -embossable fiber/polymer composite, wherein a) the substrate S comprises acetylated lignocellulosic fibers, and b) the polymer P is thermoplastic and has a TgP?20° C. The invention relates to a fiber/polymer molding obtainable by the process and a component in motor vehicle construction, in built structures and in furniture which contains the fiber/polymer molding.
Type:
Grant
Filed:
May 22, 2020
Date of Patent:
November 15, 2022
Assignee:
BASF SE
Inventors:
Mirko Flory, Michael Kalbe, Hans Horler
Abstract: An impact-modified composition and a method of making an impact-modified composition are provided. In an embodiment, the method includes reacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material; initiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material; and adding the an impact-modified phosphazene material to a polymeric material.
Type:
Grant
Filed:
January 2, 2020
Date of Patent:
November 1, 2022
Assignee:
International Business Machines Corporation
Inventors:
Brandon M. Kobilka, Joseph Kuczynski, Jacob T. Porter, Jason T. Wertz
Abstract: A modified conjugated diene-based polymer and a rubber composition including the same are disclosed herein. In some embodiments, the modified conjugated diene-based polymer includes a functional group derived from a modification monomer represented by Formula 1 and a functional group derived from a modifier, and the polymer has a unimodal molecular weight distribution, and a polydispersity index of 1.0 to less than 1.7. The polymer has excellent processability, tensile properties and viscoelasticity properties.
Type:
Grant
Filed:
May 8, 2019
Date of Patent:
November 1, 2022
Inventors:
Tae Chul Lee, Min Soo Kim, Ki Seok Son, No Ma Kim
Abstract: A process for preparing a functionalized polybutadiene is provided. The process comprises the following steps: a) homopolymerising butadiene with a catalytic system based on at least one preforming conjugated diene, a salt of one or more rare earth metals of an organic phosphoric acid, an aluminium-containing alkylating agent, an alkylaluminium halide; b) adding a polyfunctional compound to the pseudo-living elastomer formed in step (a); and c) adding a functionalizing agent to the mixture formed in step (b). The total molar amount of aluminium in the polymerization medium is such that the (aluminium/rare earth salt) molar ratio has a value between 1 and 5 and the polymerization is carried out at a temperature between 40° C. and 90° C. A functionalized polybutadiene that can be obtained by the process, and a rubber composition containing the functionalized polybutadiene is also provided.
Type:
Grant
Filed:
May 23, 2019
Date of Patent:
October 25, 2022
Assignee:
COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Inventors:
Florent Vaultier, Gael Courbes, Rokhiyatou Said-Diatta, Benoit De Gaudemaris
Abstract: Particles of an acrylic polymer comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from a (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms, wherein the particles having electrostatic buildup inhibition rate of 90 to 99.9° as obtained by a specific method.
Abstract: A curable composition comprises: a) 91 to 98.2 weight percent of: (i) at least one polymerizable compound containing at least one carbamylene group; or (ii) at least one polyurethane precursor system; and b) 0.2 to 9 weight percent of alpha alumina particles having a particle size distribution with a Dv50 of from 0.1 to 1 micron, wherein the weight percentages of a) and b) are based upon the total amount of a) and b). Cured compositions and their use in thermoforming are also disclosed.
Type:
Grant
Filed:
December 6, 2018
Date of Patent:
September 20, 2022
Assignee:
3M Innovative Properties Company
Inventors:
Thomas P. Klun, Chunjie Zhang, Richard J. Pokorny, Benjamin R. Coonce, Benjamin G. Sonnek, Gregg A. Ambur, Jung-Sheng Wu
Abstract: A multistage emulsion polymerization process comprises polymerizing a first monomer composition comprising from 50 to 95 weight percent of vinyl acetate, from 5 to 40 weight percent of at least one vinyl ester of a C5 to C18 unsaturated carboxylic acid, and optionally up to 40 weight percent of ethylene, all based on the total weight of monomers in the first monomer composition, to produce a first stage polymer. A second monomer composition comprising 40 to 89.95 weight percent of at least one ester of methacrylic acid or a vinyl aromatic monomer, 10 to 59.95 weight percent of at least one ester of acrylic acid, and from 0.05 to 10 weight percent of at least one comonomer with acid functionality, based on the total weight of monomers in the second monomer composition, is then polymerized in the presence of the first stage polymer to produce a second stage polymer.
Type:
Grant
Filed:
May 30, 2019
Date of Patent:
September 13, 2022
Assignee:
CELANESE INTERNATIONAL CORPORATION
Inventors:
Kerstin Wenzel, Matthias Junk, Thomas Fichtner, Stephan Krieger
Abstract: The invention relates to a composition, more particularly, to a two-component composition comprising component I comprising at least one methylene malonate monomer (A), at least one polymer (B) and at least one acidic stabilizer (C), and component comprising at least one alkali accelerator, to the preparation thereof, and to the use of the composition as a waterproofing coat in construction applications.
Type:
Grant
Filed:
December 18, 2018
Date of Patent:
September 6, 2022
Assignee:
BASF SE
Inventors:
Lei Meng, Sheng Zhong Zhou, Alfons Smeets, Harald Roeckel
Abstract: The present invention provides a dispersion stabilizer for suspension polymerization that, when used for suspension polymerization of a vinyl compound, provides excellent polymerization stability, and can produce a vinyl polymer having a reduced number of coarse particles, and a reduced number of fisheyes when molded into a sheet form. The present invention also provides a method therewith. The present invention relates to a dispersion stabilizer for suspension polymerization of a vinyl compound, the dispersion stabilizer comprising a vinyl alcohol polymer (A) having a viscosity-average degree of polymerization of more than 400 and less than 1,000, a degree of saponification of more than 67 mol % and less than 78 mol %, 0.02 mol % to 1.0 mol % of a group having an ethylenic double bond in its side chain, and an absorbance (x) at 280 nm of more than 0.17 and less than 0.65 in an ultraviolet absorption spectrum of a 0.1 mass % aqueous solution.
Abstract: Particles of an acrylic polymer comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from a (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms, wherein the particles having electrostatic buildup inhibition rate of 90 to 99.9° as obtained by a specific method.
Abstract: To provide a curable composition capable of obtaining a cured product which has a high Abbe number, is excellent in transparency and crack resistance, and is capable of suppressing a decrease in transparency over a long period of time; and such a cured product. This curable composition comprises solid silica fine particles A, of which an organic component is at most 5 mass % and the median diameter is from 5 to 20 nm, (meth)acrylate B which has an alicyclic condensed ring, and of which the glass transition temperature of the homopolymer is from 90 to 350° C., epoxy(meth)acrylate C which has no aromatic ring, and in which the amount of substance of ethylenically unsaturated groups is from 0.1 to 3.
Abstract: A microparticle comprised of dried cellulose nanocrystals agglomerated together and forming said microparticle is provided, wherein the CNCs are surfaced-reduced carboxylated CNCs, and wherein the microparticle is nanoredispersible into its constituting cellulose nanocrystals in both aqueous and non-aqueous solvents. A method for producing nanoredispersible microparticles comprised of dried CNCs is also provided.
Type:
Grant
Filed:
February 11, 2020
Date of Patent:
August 23, 2022
Assignee:
ANOMERA INC.
Inventors:
Mark P. Andrews, Timothy Morse, Amir Khabibullin, Muntaser Farooque, Monika Rak
Abstract: A PETx polymer including a main backbone which is a first poly-L-lysine, and a side chain which is sequentially connected with a first polyethylene glycol and a second poly-L-lysine, where the second poly-L-lysine is saturately connected with a second polyethylene glycol and a third polyethylene glycol with no remaining amino groups, and the third polyethylene glycol is connected with a functional group at its end, where the first poly-L-lysine and the second poly-L-lysine have the same or different chain lengths, and the first polyethylene glycol, the second polyethylene glycol and the third polyethylene glycol have the same or different chain lengths. Preferably, the PETx polymer is PLL-g-{PEGk-PLL-g-[(PEGj-biological recognition group)y %(PEGi)1-y %]}x %, where i, j, k, m, and n are all integers greater than or equal to 1, j is not equal to i, and x and y are all greater than 0 and less than 100.
Abstract: An acrylic copolymer is provided. The acrylic copolymer includes: a main monomer-derived repeating unit; and a chain transfer agent-derived part, wherein the main monomer-derived repeating unit includes a (meth)acrylic acid alkyl ester monomer-derived repeating unit, a (meth)acrylic acid alkoxy alkyl ester monomer-derived repeating unit, and a crosslinking monomer-derived repeating unit, the chain transfer agent-derived part is derived from a chain transfer agent having a carbonothioylthio group, and the chain transfer agent-derived part is included in an amount of 0.03 parts by weight to 0.08 parts by weight with respect to 100 parts by weight of the main monomer-derived repeating unit. A method of preparing the same, and an acrylic copolymer composition including the same is also provided.
Type:
Grant
Filed:
November 7, 2019
Date of Patent:
August 23, 2022
Inventors:
Sang Jin Shin, Jung Su Han, Seung Uk Yeu, Yong Seok Jung
Abstract: The present invention relates to a modified conjugated diene-based polymer, and more particularly, to a modified conjugated diene-based polymer prepared by continuous polymerization and having a specific polymer structure and molecular weight distribution degree and shape, and thus, having remarkable processability and narrow molecular weight distribution, and thus, having excellent physical properties, and a rubber composition including the same.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
August 16, 2022
Inventors:
Jung Hwan Oh, You Seok Seo, Jae Hoon Choe, Min Soo Kim, No Ma Kim
Abstract: A cross-linkable nitrile rubber composition that includes a nitrile group-containing copolymer rubber (A), silica (B1), clay (B2), calcium carbonate (B3), and a polyamine-based cross-linking agent (C). A total amount of the silica (B1), the clay (B2), and the calcium carbonate (B3) is 150 to 200 parts by weight with respect to 100 parts by weight of the nitrile group-containing copolymer rubber (A), a content ratio of the silica (B1) is greater than 0 wt % and 50 wt % or less with respect to the total amount of the silica (B1), the clay (B2), and the calcium carbonate (B3), and a content ratio of the clay (B2) and the calcium carbonate (B3) is 30:70 to 90:10 in a weight ratio of “clay (B2):calcium carbonate (B3)”.
Abstract: A modified conjugated diene-based polymer, including a coupling polymer, wherein a ratio of the coupling polymer, obtained by gel permeation chromatography (GPC), is 30% by mass or more and less than 70% by mass in the entire modified conjugated diene-based polymer, and a modification ratio obtained by adsorption GPC is 30% by mass or more and less than 70% by mass in the entire modified conjugated diene-based polymer, when a peak top molecular weight, obtained by the GPC, of the coupling polymer of the modified conjugated diene-based polymer is represented by Mp1 and a peak top molecular weight of a non-coupling polymer is represented by Mp2, (Mp1/Mp2)?3.4, and a shrinking factor (g?) is less than 0.60.
Abstract: An object of the present invention is to provide a paint which is excellent in various performances such as resistance to various organic solvents and hydraulic fluid, corrosion resistance, weather resistance, heat resistance, adhesion to substrates, and coating film appearance, and which in particular, can be suitably used for aircraft applications. Specifically, the invention provides a paint which contains, as an essential component of a main agent, a polyester resin (A) having a hydroxyl value in a range of 150 to 400 mg KOH/g and a weight average molecular weight (Mw) in a range of 500 to 5,000, and a polyisocyanate compound (B) as an essential component of a curing agent; an aircraft paint using the paint; and an aircraft using the aircraft paint.
Abstract: This disclosure relates to an inorganic-organic metal phosphate ceramic coating from the reaction of an inorganic phosphate of the formulas (i) Am(H2PO4)m.nH2O or (ii) AH3(PO4)2.nH2O; where A is ammonium or an m-valent metal element; m=1, 2, or 3; and n is 0 to 25; and at least one metal oxide or hydroxide represented by the formula B2mOm or B(OH)2m, where B is a 2m-valent metal; and m=1 or 1.5; thereof; and at least one polymer capable of reacting with at least the one metal oxide or hydroxide; or a first organic precursor combined with the inorganic phosphate and a second organic precursor combined with the at least one metal oxide or hydroxide, the second organic precursor configured to chemically react with the one or more first organic precursor.