Abstract: A cyclopentene ring-opening copolymer having a branch structure contains a structure in which at least four cyclopentene ring-opening polymer chains are linked via a branch-structural unit. At least part of the cyclopentene ring-opening polymer chains is terminally modified.
Abstract: Provided are a method for preparing a conjugated diene-based polymer and a method for preparing a graft copolymer including the same. The method for preparing a conjugated diene-based polymer includes enlarging a first conjugated diene-based polymer in multiple stages to prepare a second conjugated diene-based polymer, wherein the multi-stage enlargement includes a primary enlargement stage and a secondary enlargement stage, and a weight ratio of acids added in the primary enlargement stage and the secondary enlargement stage is 70:30 to 90:10. A graft copolymer prepared by the above-described method can be used to form a thermoplastic resin molded article excellent in all of plating characteristics, mechanical properties, surface characteristics, colorability, and processability.
Type:
Grant
Filed:
April 15, 2019
Date of Patent:
March 29, 2022
Assignee:
LG CHEM, LTD.
Inventors:
Joo Byung Chai, Yu Sung Jung, Jong Beom Kim, Chang Sull Kim, Eun Seon Park, Tae Young Jeon
Abstract: A composite including a plurality of block copolymer chains dispersed in a base polymer, the block copolymer chains including a polymer block (A) and a polymer block (B) having lower affinity for the base polymer than that of the polymer block (A), wherein each of the block copolymer chains has the polymer block (A) at two or more locations of the block copolymer chain, and in at least some of the block copolymer chains, the polymer blocks (A) are at least partially located in the base polymer and the polymer blocks (B) are at least partially exposed from the base polymer.
Type:
Grant
Filed:
March 2, 2018
Date of Patent:
March 15, 2022
Assignees:
NATIONAL INSTITUTE OF TECHNOLOGY, NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, KYOTO UNIVERSITY, NISSHINBO HOLDINGS INC.
Abstract: Methods of forming acrylate polymers using emulsion polymerization techniques are described. The resulting acrylate polymers exhibit characteristics enabling their use in adhesives and replacing acrylic polymers formed by solvent-based polymerization methods. Various polymers and adhesives utilizing such polymers are also described.
Type:
Grant
Filed:
January 31, 2019
Date of Patent:
March 8, 2022
Assignee:
Avery Dennison Corporation
Inventors:
Mark D. Gower, Eric L. Bartholomew, Qiang Luo, Charles R. Williams, Jr.
Abstract: A composition contains a polyorganosiloxane dispersed in a combination of a condensation product of a polysiloxane resin and a polyoxyalkylene polymer, and a non-aqueous fluid carrier; wherein the weight-ratio of non-aqueous fluid carrier to condensation product is 0.5 or more and 10 or less; the weight-ratio of the combination of condensation product and non-aqueous fluid carrier to polyorganosiloxane is 0.01 or more and 0.50 or less; and wherein the composition contains less than one weight-part aromatic solvent per million weight parts composition.
Type:
Grant
Filed:
April 16, 2020
Date of Patent:
March 8, 2022
Assignee:
Dow Silicones Corporation
Inventors:
Patrick J. Fryfogle, Yihan Liu, Timothy P. Mitchell, Jennifer A. Reil, Michael R. Reiter, John Roberts, Gary M. Wieber, Brett L. Zimmerman
Abstract: The present invention aims to provide a rubber composition having sufficient reinforcement and fatigue resistance even when a large strain is applied thereto, and the present invention is to provide a substituted carboxy group-containing modified cellulose nanofiber wherein at least part thereof has at least any one of a substituent represented by Formula (a): —CONH—R1 and a substituent represented by Formula (b): —COO—R1 (in Formulae (a) and (b), R1 is independently a C3-30 hydrocarbon having at least one unsaturated bond), and a rubber composition including the same.
Abstract: The invention relates to benzothiazole-containing silanes of the formula I which are prepared by reacting benzothiazole-containing silanes of the formula II with a compound of formula III R2—H??(III). The benzothiazole-containing silanes of the formula I can be used in rubber mixtures.
Type:
Grant
Filed:
April 25, 2018
Date of Patent:
February 22, 2022
Assignee:
Evonik Operations GmbH
Inventors:
Alexander Koepfer, Oliver Klockmann, Olga Kufelt, Stefanie Mayer, Caren Roeben, Sebastian Rosenstingl, Andre Wehmeier
Abstract: A process for preparing an aqueous polymer dispersion, the process including forming a copolymer A from at least one ?,?-monoethylenically unsaturated C3 to C6 monocarboxylic acid (monomers A1) and at least one other monoethylenically unsaturated compound (monomers A2); reacting the copolymer A with a metal compound M in an aqueous medium; and conducting free-radical polymerization of at least one ethylenically unsaturated compound (monomer P) in the presence of the copolymer A in an aqueous medium.
Abstract: An organic polymer comprising an organic polymer fragment and at least one S-alkylsilyl hydrocarbonthioate group or at least one S-alkylstannyl hydrocarbonthioate group bonded to the backbone of the organic polymer fragment through a C—Si covalent bond and their methods or production are provided. The organic polymer backbone can be derived from the anionic polymerization of monomers containing C—C unsaturation. The silicon or tin atom can be further bonded to two alkoxy groups, two hydrocarbon groups or to one alkoxy group and one hydrocarbon group.
Abstract: A modified conjugated diene-based polymer according to the present invention has a weight average molecular weight of 20×104 or more and 300×104 or less, has a molecular weight distribution Mw/Mn of 1.6 or more and 4.0 or less, has a modification ratio of 30% by mass or more and 80% by mass or less with respect to a total amount of the conjugated diene-based polymer, and includes 5% by mass or more and 50% by mass or less of a component having a molecular weight of 1,000,000 or more and 5,000,000 or less in GPC (gel permeation chromatography), wherein a modification ratio of the component having a molecular weight of 1,000,000 or more and 5,000,000 or less is 90% by mass or more and 100% by mass or less.
Abstract: Provide is a polyamide resin that can yield a molded article with good appearance and good solder reflowability, while keeping low water absorption rate; a molded article; and a method for manufacturing a polyamide resin. The polyamide resin, which is composed of a structural unit derived from diamine and a structural unit derived from dicarboxylic acid; 70 mol % or more of the structural unit derived from diamine being derived from 1,4-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane having a molar ratio (cis:trans) of 35:65 to 0:100, 70 mol % or more of the structural unit derived from dicarboxylic acid being derived from a straight chain aliphatic ?,?-dicarboxylic acid having 8 to 12 carbon atoms, the polyamide resin containing 20 to 100 ppm by mass of phosphorus atom, and containing calcium atom so that the molar ratio given by (phosphorus atom):(calcium atom) will be 1:0.3 to 0.7.
Abstract: Subject matter are aqueous, low-VOC/SVOC universal pigment preparations comprising a pigment component; a water-soluble, nonionic, surface-active additive comprising a copolymer formed from a vinyl monomer and from an ethylenically unsaturated monomer selected from the group consisting of monocarboxylic esters, dicarboxylic esters, monocarboxamides, and dicarboxamides, the vinyl monomer and/or the ethylenically unsaturated monomer containing an N-containing group with pigment affinity; a phosphoric or phosphonic ester, and optionally customary additives. The aqueous pigment preparations are suitable for the coloring of inks, paints, and renders, especially in metering systems at the point of sale or in in-plant tinting systems.
Abstract: The present invention relates to a tyre for vehicle wheels comprising at least one structural element comprising a cross-linked elastomeric material obtained by cross-linking a cross-linkable elastomeric composition comprising carbon nanotubes, wherein said carbon nanotubes are obtained with an iron oxides and/or aluminium oxides based catalyst substantially free of Co, Ni and Mo.
Type:
Grant
Filed:
December 12, 2017
Date of Patent:
December 28, 2021
Assignee:
PIRELLI TYRE S.p.A.
Inventors:
Carlo Vittorio Mazzocchia, Matteo Antonio Daghetta, Lorenzo Pellegrino, Attillio Citterio, Enrico Albizzati, Luca Giannini, Thomas Hanel
Abstract: This invention relates to the use of ethylene/propylene random copolymers for the production of films having low-haze. In particular, the present invention involves the use of ethylene/propylene random copolymer comprising 90-96.5 wt % propylene and 3.5-10 wt % ethylene demonstrated to have low haze. This invention also relates to an ethylene/propylene random copolymer composition comprising about 3.5-10 wt % ethylene content and about 90-96.5 wt % propylene content, for production of a low-haze film.
Abstract: A method for making thermosetting polyimides from resveratrol including converting resveratrol to trisaniline, reacting trisaniline with one or more dianhydride and thermosetting endcap to form amic acid, thermally imidizing amic acid to form polyimide oligomer, and cross-linking polyimide oligomer with heat and pressure to generate polyimide thermoset.
Type:
Grant
Filed:
June 5, 2019
Date of Patent:
December 7, 2021
Assignee:
The United States of America, as represented by the Secretary of the Navy
Inventors:
Benjamin G. Harvey, Andrew Chafin, Matthew C. Davis
Abstract: The current invention relates to a process for preparing an aqueous binder composition, the process comprising at least the following steps A) and B): A) preparing carboxylic acid-functional vinyl polymer (Polymer A) by emulsion polymerisation of a monomer composition A comprising the following monomers: Ai) at least one carboxylic acid functional olefinically unsaturated monomer; and Aii) at least one olefinically unsaturated monomer different than Ai); B) preparing vinyl polymer (Polymer B) by emulsion polymerization of a monomer composition B in the presence of Polymer A where the monomer composition B comprises the following monomer(s): Bi) at least one olefinically unsaturated monomer; Bii) optionally carboxylic acid functional olefinically unsaturated monomer different than Bi); where at least part of the carboxylic acid groups of Polymer A are deprotonated to obtain ionic or potentially ionic water-dispersing groups; where the acid value of Polymer B is lower than the acid value of Polymer A; where the
Abstract: A method of preparing a polymer dispersion comprising (i) contacting an aqueous dispersion of de-ionized acidic colloidal silica particles with a first mixture of monomers to form a combination; (ii) polymerizing such combination at an initial pH of from 2 to 5 to at least 90% in completion; and (iii) adding a second mixture of monomers at a rate substantially equal to the rate of consumption of such second mixture of monomers to continue and complete the polymerization. The present invention further provides a polymer dispersion made from the above method.
Abstract: The invention relates to a method for the production of thermally stabilised melt-spun fibres in which polyacrilonitrile (PAN) fibres or PAN fibre precursors produced by melt-spinning are treated in an aqueous alkaline solution, comprising in addition a solvent for PAN. Likewise, the invention relates to fibres which are producible according to this method.
Type:
Grant
Filed:
March 22, 2016
Date of Patent:
November 23, 2021
Assignee:
Fraunhofer-Gesellschaft zur förderung der angewandten Forschung e.V.