Abstract: A process for producing SiOC-bonded polyether siloxanes by transesterification of alkoxysiloxanes with polyetherols in the presence of zinc acetylacetonate as catalyst is described.
Type:
Grant
Filed:
July 9, 2018
Date of Patent:
September 17, 2019
Assignee:
Evonik Degussa GmbH
Inventors:
Wilfried Knott, Horst Dudzik, Olga Fiedel, Philippe Favresse, Ute Hesse
Abstract: The present invention relates to a process for producing hydrosilylatable, eugenol-based polyethers, to the conversion thereof into polyether siloxanes and also to the products that may be produced by this process and to the use of said products as surfactants.
Type:
Grant
Filed:
November 1, 2018
Date of Patent:
September 10, 2019
Assignee:
Evonik Degussa GmbH
Inventors:
Matthias Lobert, Michael Ferenz, Katrin Roland, Thorsten Schierle
Abstract: Mixtures of cyclic branched siloxanes having exclusively D and T units, with the proviso that the cumulative proportion of the D and T units having Si-alkoxy and/or SiOH groups that are present in the siloxane matrix, determinable by 29Si NMR spectroscopy, is greater than 2 and less than 10 mole percent, are described, as are branched organomodified siloxanes obtainable therefrom.
Abstract: A siloxane oligomer of the following formula is provided. This siloxane can increase the hydrophobicity and/or the lipophobicity of a surface of a solid substrate and/or self-propel when deposited in solution on a surface of a solid substrate.
Abstract: Methods of synthesizing Si—H containing iodosilanes, such as diiodosilane or pentaiododisilane, using a halide exchange reaction are disclosed.
Type:
Grant
Filed:
December 8, 2017
Date of Patent:
August 20, 2019
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Inventors:
Cole Ritter, Gennadiy Itov, Manish Khandelwal, Jean-Marc Girard, Glenn Kuchenbeiser, Sean Kerrigan, Peng Zhang, Larry Kit-wing Leung, Nicolas Blasco
Abstract: Fluorinated cyclopentene moieties and fluorinated cyclopentene functionalized silica materials are provided. The fluorinated cyclopentene functionalized silica materials include a silica material having the fluorinated cyclopentene moiety covalently bonded thereto. Exemplary silica materials include a polysilsesquioxane, a nanosilica, a microsilica, a silica gel, a silica aerogel, or combinations thereof. The fluorinated cyclopentene moieties are based on a modification of perfluorocyclopentene (i.e., 1,2,3,3,4,4,5,5-octafluoro-1-cyclopentene) by nucleophilic substitution with an appropriate nucleophile having a reactive functional group. Methods for preparing fluorinated cyclopentene moieties and the corresponding fluorinated cyclopentene functionalized silica materials are also provided.
Type:
Grant
Filed:
February 7, 2019
Date of Patent:
August 20, 2019
Assignee:
United States of America as represented by the Secretary of the Air Force
Abstract: The application describes catalytic materials for hydrogenation or asymmetric hydrogenation. In particular, the application describes iron(II) complexes containing tridentate diphosphine PNP ligands useful for catalytic hydrogenation.
Type:
Grant
Filed:
January 8, 2015
Date of Patent:
August 20, 2019
Assignee:
THE GOVERNING COUNCIL OF THE UNIVERSITY OF TORONTO
Inventors:
Robert H. Morris, Paraskevi Olympia Lagaditis, Jessica Sonnenberg
Abstract: A transformed metal oxide sol, according to the present invention, has as main components: a hydrolysis product of a surface-active silane coupling agent, a transformed metal oxide sol which has been transformed by means of a hydrolysis product of a surface-active silane coupling agent, or a mixture and/or a condensate of the hydrolysis product of the surface-active silane coupling agent and the transformed metal oxide sol which has been transformed by means of the hydrolysis product of the surface-active silane coupling agent; and a mixture of transformed metal oxide sols which have been transformed by means of sulfur-containing functional groups, wherein a raw metal oxide sol of the transformed metal oxide sol is preferably an organosilica sol.
Abstract: A method simply produces a narrowly distributed and high-purity polyalkylene glycol derivative having an amino group at an end without using a heavy metal catalyst.
Abstract: A functionalized magnetic nanoparticle including an organometallic sandwich compound and a magnetic metal oxide. The functionalized magnetic nanoparticle may be reacted with a metal precursor to form a catalyst for various C—C bond forming reactions. The catalyst may be recovered with ease by attracting the catalyst with a magnet.
Type:
Grant
Filed:
October 4, 2018
Date of Patent:
August 6, 2019
Assignee:
Kind Fahd University of Petroleum and Minerals
Inventors:
M. Nasiruzzaman Shaikh, Md. Abdul Aziz, Aasif Helal
Abstract: A polyurethane polyurea having strong thickening and gelling effects, obtained by reacting a polyurethane polyurea prepolymer obtained from a silicone derivative starting material having a specific structure, a specific diisocyanate compound starting material and a starting material made up of a compound represented by General Formula (C) (each of which is set forth in the Description), with either or both of a nitrogen compound having a specific structure and a hydroxyl group-containing compound having a specific structure (each of which is set forth in the Description.
Abstract: A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound.
Type:
Grant
Filed:
March 8, 2016
Date of Patent:
July 30, 2019
Assignees:
KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, SHIN-ETSU CHEMICAL CO., LTD.
Inventors:
Hideo Nagashima, Yusuke Sunada, Mina Sawano, Daisuke Noda, Koji Sakuta
Abstract: The present invention relates to a method for producing amino acid group-containing organosilicon compounds (O), wherein the epoxy group-bearing organosilicon compounds are reacted with a stoichiometric excess of amino acids or the salts thereof in the presence of an alcohol.
Abstract: A monoallophanate can be used in paint or adhesive compositions. The monoallophanate has the formula 1: where R, R1-R6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and m and n are each independently 0-2.
Type:
Grant
Filed:
October 11, 2016
Date of Patent:
July 16, 2019
Assignee:
Evonik Degussa GmbH
Inventors:
Emmanouil Spyrou, Manfred Kreczinski, Tobias Unkelhaeusser, Sabine Naumann, Holger Loesch, Marion Ewald, Thomas Weihrauch
Abstract: This patent relates to invert water in oil (w/o) and water in silicone (w/si) emulsions made using non PEG/PPG containing polyhydric silicone emulsifiers. The polyhydric silicone polymers are based on allyl trimethylolpropane and pentaerythritol modified organic groups and do not contain any PEG and/or PPG groups (also known as polyethylene glycol and polypropylene glycols, polyethers, polyglycols,). These emulsions show improved emulsification stability and provide a light feel compared to emulsions made with other silicone based PEG/PPG compounds which are commonly used in the field.
Type:
Grant
Filed:
March 29, 2017
Date of Patent:
July 2, 2019
Assignee:
SILTECH CORP
Inventors:
Rick Vrckovnik, Fenbao David Zhang, Mark Riddle
Abstract: (Meth)acrylate-functionalized silicon compounds are easily prepared by the reaction of a (meth)acryloyl-functionalized chlorosilane with an organosilicon compound having silicon-bonded hydroxy groups. The carbon atom adjacent to the resulting O—Si linkage is bonded to at least one further carbon, rendering the product stable to hydrolysis despite the C—O—Si linkage.
Abstract: An object of the invention is to provide a method for efficiently producing an acyloxysilane which is useful as a functional chemical, an acyloxysilane obtained thereby, and the use thereof. The present invention provides: a method for producing an acyloxysilane, including a reaction step of reacting an alkoxysilane with a carboxylic anhydride in the presence of a catalyst, wherein the alkoxysilane is a specified alkoxysilane represented by General Formula (I), the carboxylic anhydride is a specified carboxylic acid represented by General Formula (IIA) or (IIB), the catalyst is an acid catalyst, and an acyloxysilane obtained in the reaction step is a specified acyloxysilane represented by General Formula (IIIA) or (IIIB); and the use of the acyloxysilane as a surface treatment agent or the like.
Type:
Grant
Filed:
March 9, 2016
Date of Patent:
June 11, 2019
Assignee:
NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
Abstract: Atomic layer deposition (ALD) processes for forming Te-containing thin films, such as Sb—Te, Ge—Te, Ge—Sb—Te, Bi—Te, and Zn—Te thin films are provided. ALD processes are also provided for forming Se-containing thin films, such as Sb—Se, Ge—Se, Ge—Sb—Se, Bi—Se, and Zn—Se thin films are also provided. Te and Se precursors of the formula (Te,Se)(SiR1R2R3)2 are preferably used, wherein R1, R2, and R3 are alkyl groups. Methods are also provided for synthesizing these Te and Se precursors. Methods are also provided for using the Te and Se thin films in phase change memory devices.
Type:
Grant
Filed:
September 21, 2017
Date of Patent:
June 4, 2019
Assignee:
ASM International N.V.
Inventors:
Viljami Pore, Timo Hatanpaa, Mikko Ritala, Markku Leskelä
Abstract: Coordination polymers of MOF type, comprising a repeating unit of the general formula [M2(dcx)2L2], wherein M represents a metal cation (M2+), dcx represents an anion of a dicarboxylic acid and L represents a neutral molecule of hydrazone. A method for preparation of coordination polymers of MOF type, wherein in the first step a compound of aldehyde or ketone group is condensed with a hydrazide, and in the second step the condensation product is reacted using a metal compound and a dicarboxylic acid. An application of coordination polymers of MOF type for the detection, capturing, separation, or storage of molecules, for the fabrication of ionic conductors, for the construction of batteries and fuel cells, as well as drug carriers.
Abstract: A long life catalyst is provided that is conveniently and inexpensively capable of being produced and that is highly active and has inhibited metal leakage. According to aspects of the present invention, a catalyst is provided that includes: a polymer including a plurality of first structural units and a plurality of second structural units; and metal acting as a catalytic center, wherein at least part of the metal is covered with the polymer, each of the plurality of first structural units has a first atom constituting a main chain of the polymer and a first substituent group bonded to the first atom, a second atom included in each of the plurality of second structural units is bonded to the first atom, and the second atom is different from the first atom, or at least one of all substituent groups on the second atom is different from the first substituent group.