Patents Examined by Kumar R Bhushan
  • Patent number: 10975289
    Abstract: A hydrocarbon formation treatment micellar solution fluid and its use in treating underperforming hydrocarbon formations is described and claimed. A hydrocarbon formation treatment micellar solution fluid wherein the micellar solution fluid comprises water, a non-terpene oil-based moiety, a brine resistant aqueous colloidal silica sol; and optionally a terpene or a terpenoid, wherein the brine resistant aqueous colloidal silica sol has silica particles with a surface that is functionalized with at least one moiety selected from the group consisting of a hydrophilic organosilane, a mixture of hydrophilic and hydrophobic organosilanes, or a polysiloxane oligomer, wherein the brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter, and wherein, when a terpene or terpenoid is present, the ratio of total water to terpene or terpenoid is at least about 15 to 1.
    Type: Grant
    Filed: June 26, 2019
    Date of Patent: April 13, 2021
    Assignee: Nissan Chemical America Corporation
    Inventors: John Edmond Southwell, Yusra Khan Ahmad
  • Patent number: 10975286
    Abstract: A cement slurry suitable for use in the presence of high salt concentrations may include a base fluid and dry components that include: a cementitious material, a pozzolanic material, a salt additive, and a salt-tolerant fluid loss additive. The salt-tolerant fluid loss additive may be at least one of the following zwitterionic polymers: (1) a copolymer of at least one anionic monomer and at least one cationic monomer, (2) a copolymer of at least one anionic monomer, at least one cationic monomer, and at least one zwitterionic monomer, (3) a homopolymer of a zwitterionic monomer, or (4) a copolymer of at least one zwitterionic monomer.
    Type: Grant
    Filed: August 28, 2014
    Date of Patent: April 13, 2021
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Gary P. Funkhouser, Samuel J. Lewis
  • Patent number: 10961442
    Abstract: On-line diverting acids for continuous injection into water injection wells and methods of preparing the diverting acid are disclosed. The on-line diverting acids have a raw material composition of: 5.0-25.0% of hydrochloric acid, 3.0%-6.0% of ammonium fluoride, 4.0%-8.0% of a diverting agent, 3.0%-7.0% of a chelating agent, 1.0-3.0% of a corrosion inhibitor, 1.0-3.0% of an anti-swelling/swelled-clay-shrinking agent and a balance of water. The on-line diverting acids can remove plugging from deep zones of high and low permeability layers, and can be continuously injected to simplify the construction process, to achieve the purpose of reducing the pressure and stimulating the injection.
    Type: Grant
    Filed: January 4, 2019
    Date of Patent: March 30, 2021
    Assignee: PetroChina Company Limited
    Inventors: Lijun Mu, Xianwen Li, Hongjun Lu, Zhiying Deng, Yong Wang, Bin Yao, Zhenning Ji, Suiwang Zhang, Xiaobing Lu, Zhaojie Song, Lei Sui, Erzhen Wang
  • Patent number: 10961180
    Abstract: The invention provides branched trialkylamine oxides with improved properties. The trialkylamine oxides of the invention produced from branched trialkylamines, in one embodiment, can be made using certain branched C10-12 enals and aldehydes. The invention also provides an trialkylamine oxide having the formula: wherein R5, R6 and R7 are independently at least one of C3H7, C2H5, CH3, or H, or mixtures thereof; and wherein R5 and R6 are not H at the same time. In one embodiment, the trialkylamine oxides of the invention can be useful in making various products, for example, as surfactants.
    Type: Grant
    Filed: January 9, 2019
    Date of Patent: March 30, 2021
    Assignee: Eastman Chemical Company
    Inventors: Stephanie Kay Clendennen, Vasudev R. Bhonde, Damon Ray Billodeaux, Matthew Allen Boone, Kim Dumoleijn, Stijn Simonne Paul Van de Vyver, Kristof Moonen, Neil Warren Boaz
  • Patent number: 10954423
    Abstract: A method of servicing a wellbore in a subterranean formation having one or more lost circulation zones comprising placing a wellbore servicing fluid comprising a sealing composition into the wellbore, wherein the sealing composition comprises a latex and an accelerator and wherein the latex, the accelerator or both are encapsulated with an encapsulation material. A wellbore servicing fluid comprising a latex and an accelerator wherein the latex, the accelerator, or both are encapsulated.
    Type: Grant
    Filed: October 8, 2018
    Date of Patent: March 23, 2021
    Assignee: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Nicholas Charles Braley, Anthony M. Badalamenti, Jay Paul Deville
  • Patent number: 10954430
    Abstract: Improved hydraulic fracturing compositions are disclosed which help reduce potential negative environmental impact by hydraulic fracturing. The disclosed compositions have flammability and toxicity and are relatively safe for the environment. The compositions may also contain biodegradable components.
    Type: Grant
    Filed: December 19, 2016
    Date of Patent: March 23, 2021
    Inventor: Courtney Gene Rogers
  • Patent number: 10947446
    Abstract: A dual-phase acid-based fracturing composition with corrosion inhibitors and method for use in acid-based matrix and fracturing operations in oil and gas wells is provided. The composition includes an acid, a hydrocarbon, a hydrocarbon-soluble corrosion inhibitor, an acid-soluble corrosion inhibitor, and an acid-soluble inhibitor aid.
    Type: Grant
    Filed: May 13, 2019
    Date of Patent: March 16, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Saleh H. Al-Mutairi, Yaser K. Al-Duailej, Ibrahim S. Al-Yami, Abdullah M. Al-Hajri, Hameed H. Al-Badairy
  • Patent number: 10947795
    Abstract: An oil-swellable lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may be formed from elastomeric polymer particles, a crosslinker amine, an anti-agglomerating agent, and may also be formed using a cure accelerator. A mixture of the elastomeric polymer particles, the crosslinker amine, the anti-agglomerating agent, and in some mixtures the cure accelerator, may be hot rolled at a temperature of at least 120° F. for a duration. The resulting LCM may swell by absorbing about 20 to about 34 times its weight when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.
    Type: Grant
    Filed: February 17, 2020
    Date of Patent: March 16, 2021
    Assignee: Saudi Arabian Oil Company
    Inventor: B. Raghava Reddy
  • Patent number: 10941335
    Abstract: A fines-fixing agent that has improved compatibility with organic complexed borate fracturing fluids is disclosed. Existing fines fixing agents have a high concentration of unreacted caustic that results in a product pH of approximately 12. This high pH affects the crosslinker and the overall fracturing fluid system stability, promoting precipitation of the organic crosslinker. These effects can be mitigated by neutralizing the fines fixing agents with an acid such as hydrochloric or acetic acid to a pH of 6 or lower.
    Type: Grant
    Filed: January 31, 2017
    Date of Patent: March 9, 2021
    Assignee: BAKER HUGHES, A GE COMPANY, LLC
    Inventors: Paul S. Carman, D. V. Satyanarayana Gupta, Jennifer L. Cutler
  • Patent number: 10934472
    Abstract: Compositions comprising non-halogenated solvents for use in various aspects of a life cycle of an oil and/or gas well, and related methods, are provided. In some embodiments, the composition comprises a solvent blend and one or more surfactants. In some embodiments, the solvent blend comprises a first type of solvent (e.g., a terpene) and a second type of solvent (e.g., a non-halogenated solvent). The composition may comprise about 90 wt % to 99.9 wt % of the solvent blend, and about 0.1 wt % to 10 wt % of one or more surfactants, versus the total weight of the composition. In some embodiments, compositions can be used in methods for treating an oil and/or gas well, having a wellbore that comprises one or more fluids. A composition may be delivered into the wellbore, passing through the one or more fluids to reduce residues comprising asphaltenes, paraffins or combinations thereof on or near the wellbore.
    Type: Grant
    Filed: August 18, 2017
    Date of Patent: March 2, 2021
    Assignee: Flotek Chemistry, LLC
    Inventor: Richard Harlen Smith, Jr.
  • Patent number: 10934468
    Abstract: The present application provides an aqueous fluid containing a gas-generating compound such as an azo compound, a hydrazide compound, or a semicarbazide compound. The aqueous fluid may also contain an amine compound, an oxidizer, or viscosifier, and a foaming surfactant. The aqueous composition may be storable at pH of less than about 5 without any appreciable gas generation, and may be activated to produce gas when mixed with a wellbore fluid for use in downhole applications.
    Type: Grant
    Filed: March 3, 2020
    Date of Patent: March 2, 2021
    Assignee: Saudi Arabian Oil Company
    Inventor: B. Raghava Reddy
  • Patent number: 10927282
    Abstract: A date tree product lost circulation material (LCM) is provided. The date tree product LCM includes date tree seed particles, a first group of date tree waste fibers, a second group of date tree waste fibers, scrap tire particles, an acid-soluble particulate material, marble particles, flaked calcium carbonate, and polymer fibers. The LCM may be mixed with a carrier fluid, such as a drilling mud, to form a fluid pill. Methods of lost circulation control using the date tree product LCM and manufacture of the date tree product LCM are also provided.
    Type: Grant
    Filed: April 4, 2019
    Date of Patent: February 23, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Md Amanullah, Turki Al-Subaie
  • Patent number: 10927281
    Abstract: A date tree product lost circulation material (LCM) is provided. The date tree product LCM includes date tree seed particles, date tree trunk fibers, an acid-soluble particulate material, marble particles, flaked calcium carbonate, and polymer fibers. The LCM may be mixed with a carrier fluid, such as a drilling mud, to form a fluid pill. Methods of lost circulation control using the date tree product LCM and manufacture of the date tree product LCM are also provided.
    Type: Grant
    Filed: April 4, 2019
    Date of Patent: February 23, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Md Amanullah, Turki Al-Subaie
  • Patent number: 10920123
    Abstract: The present disclosure relates to a thermosensitive self-plugging bentonite, a preparation method thereof, and a water-based drilling fluid.
    Type: Grant
    Filed: March 3, 2020
    Date of Patent: February 16, 2021
    Assignee: SOUTHWEST PETROLEUM UNIVERSITY
    Inventors: Xiaolin Pu, Wenxin Dong
  • Patent number: 10913813
    Abstract: A vinylamide block copolymer kinetic hydrate inhibitor and a preparation method thereof are disclosed. The vinylamide block copolymer kinetic hydrate inhibitor has a structural formula as shown in formula I. Through reverse atom transfer radical polymerization, under an anaerobic operating condition, with vinylcaprolactam and acrylamide as monomers, dimethylformamide as a solvent, azobisisobutyronitrile as an initiator, and a transition metal complex composed of a catalyst anhydrous copper chloride and a ligand 2,2?-bipyridine as a catalytic system, the method has achieved to catalyze a controllable free radical solution polymerization to obtain a poly(vinylcaprolactam-acrylamide) block copolymer kinetic hydrate inhibitor. The synthesized kinetic hydrate inhibitor has a controllable molecular weight, a narrow molecular weight distribution, and a controllable synthesis process, and exhibits an excellent inhibitory effect.
    Type: Grant
    Filed: May 31, 2018
    Date of Patent: February 9, 2021
    Assignee: GUANGZHOU INSTITUTE OF ENERGY CONVERSION, CHINESE ACADEMY OF SCIENCES
    Inventors: Zhen Long, Qihang Ding, Deqing Liang
  • Patent number: 10913884
    Abstract: A stabilized composition for use as a well fluid is provided. The stabilized composition includes a brine, a polyol, the polyol in an amount operable to inhibit solid formation, the polyol further operable to dissolve within the brine; and a stabilization compound, the stabilization compound operable to stabilize the polyol, such that the polyol does not degrade at a bottom hole temperature.
    Type: Grant
    Filed: March 24, 2017
    Date of Patent: February 9, 2021
    Inventors: Arthur G. Mack, Stanley Gunawan, Katrina Schultz
  • Patent number: 10906994
    Abstract: Processes disclosed are capable of converting biomass into high-crystallinity nanocellulose with surprisingly low mechanical energy input. In some variations, the process includes fractionating biomass with an acid (such as sulfur dioxide), a solvent (such as ethanol), and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; and mechanically treating the cellulose-rich solids to form nanofibrils and/or nanocrystals. The crystallinity of the nanocellulose material may be 80% or higher, translating into good reinforcing properties for composites. The nanocellulose material may include nanofibrillated cellulose, nanocrystalline cellulose, or both. In some embodiments, the nanocellulose material is hydrophobic via deposition of some lignin onto the cellulose surface. Optionally, sugars derived from amorphous cellulose and hemicellulose may be separately fermented, such as to monomers for various polymers.
    Type: Grant
    Filed: October 4, 2018
    Date of Patent: February 2, 2021
    Assignee: GranBio Intellectual Property Holdings, LLC
    Inventors: Kimberly Nelson, Theodora Retsina, Vesa Pylkkanen, Ryan O'Connor
  • Patent number: 10899693
    Abstract: Provided herein are compounds, compositions, and methods having application in the field of enhanced oil recovery (EOR). In particular, provided herein are co-solvents, as well as aqueous compositions comprising these co-solvents, that can be used for the recovery of a large range of crude oil compositions from reservoirs.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: January 26, 2021
    Assignee: Board of Regents, The University of Texas System
    Inventors: Upali P. Weerasooriya, Gary A. Pope
  • Patent number: 10883035
    Abstract: Wellbore fluids, and methods of use thereof, are disclosed. Wellbore fluids may include a non-oleaginous internal phase; an oleaginous external phase; at least one two-dimensional platelet-like material; a first latex-containing copolymer comprising at least one copolymer formed from at least one natural polymer and at least one latex monomer; and a second latex polymer distinct from the first latex polymer.
    Type: Grant
    Filed: April 29, 2016
    Date of Patent: January 5, 2021
    Assignee: M-I L.L.C.
    Inventors: Guido De Stefano, Brandi Katherine Price Hoelscher, Aaron Blue, Clint Falgout
  • Patent number: 10876043
    Abstract: A chelating agent may be used for reservoir acidification and stimulating injection. The raw material composition of the chelating agent comprises: 10.0%-20.0% of methanesulfonic acid, 10.0%-20.0% of methanol, 10.0%-20.0% of polyaspartic acid, 10.0%-15.0% of epoxy succinic acid, 5.0%-10.0% of sodium cetyl sulfonate, 10.0%-15.0% of cetyltrimethylammonium bromide and the balance of water. The present disclosure also provides a preparation method of the above chelating agent. The chelating agent for reservoir acidification and stimulating injection may be used in an acidizing and stimulating injection process, wherein it can effectively dissolve rock cracks, be used directly without need to be reversed.
    Type: Grant
    Filed: January 23, 2019
    Date of Patent: December 29, 2020
    Assignee: PetroChina Company Limited
    Inventors: Lijun Mu, Xianwen Li, Hongjun Lu, Yong Wang, Bin Yao, Zhenning Ji, Suiwang Zhang, Xiaobing Lu, Zhiying Deng, Lei SUi, Erzhen Wang, Zhaojie Song