Abstract: A mold manufacturing method of an embodiment of the present invention includes the steps of: (a) providing a mold base; (b) partially anodizing the aluminum layer to form a porous alumina layer, the porous alumina layer having a porous layer which defines a plurality of minute recessed portions and a barrier layer which is provided at a bottom of each of the plurality of minute recessed portions; and (c) after step (b), performing etching, thereby enlarging the plurality of minute recessed portions of the porous alumina layer, wherein in step (c) the etching is performed such that an average depth of the plurality of minute recessed portions increases but does not exceed a 1/7 of an average thickness of the barrier layer before the etching.

Abstract: A plurality of cup-shaped workpieces are anodized by first securing each of them in a downwardly open position on an electrically conductive and flat workpiece frame that is then inverted such that the workpieces are open upward and lowered into a body of anodizing liquid in a treatment bath until the workpieces are wholly immersed and the frame is in contact with a horizontal rail. Thereafter the frame is moved horizontally while wholly immersed in the anodizing liquid while electricity flows between the rail and a cathode immersed in the bath below the workpieces such the liquid anodizes surfaces of the workpieces. The frame is raised out of the body of liquid with the workpieces open upward, and, while the workpieces are still above the body of liquid, inverting the frame and the workpieces so that the workpieces are open downward and any treatment liquid drains downward into the bath.

Abstract: Techniques for electrodeposition of thin film solar panels are provided. In one aspect, an electrodeposition apparatus is provided. The electrodeposition apparatus includes at least one electroplating cell; and a conveyor for moving panels over the electroplating cell, wherein the conveyor comprises at least one metal belted track over the electroplating cell surrounding a plurality of metal rollers. The electroplating cell can include an anode at a bottom of the electroplating cell; and a plurality of paddles at a top of the electroplating cell. A baffle may be located in between the anode and the paddles. An electroplating process is also provided.

Abstract: According to one embodiment, a method of separating and recovering metals whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising: a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit; a first electrolysis step of electrolyzing the first metal; a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step; a second electrolysis step of electrolyzing the second metal; and a second recovery step of recovering a pre

Abstract: In a method for generating formic acid by reducing carbon dioxide, a formic acid generation apparatus is prepared. The apparatus includes: a cathode container for storing a first electrolyte solution containing carbon dioxide; an anode container for storing a second electrolyte solution; a solid electrolyte membrane sandwiched between the cathode and anode containers; a cathode electrode provided in the cathode container in contact with the first electrolyte solution, the cathode electrode having a gallium oxide region on a surface thereof; an anode electrode provided in the anode container in contact with the second electrolyte solution; and an external power supply for applying a negative voltage and a positive voltage to the cathode electrode and the anode electrode, respectively. A negative voltage and a positive voltage are applied to the cathode electrode and the anode electrode, respectively, using the external power supply to generate formic acid on the cathode electrode.

Abstract: An apparatus for electroplating a layer of metal onto the surface of a wafer includes an ionically resistive ionically permeable element located in close proximity of the wafer and an auxiliary cathode located between the anode and the ionically resistive ionically permeable element. The ionically resistive ionically permeable element serves to modulate ionic current at the wafer surface. The auxiliary cathode is configured to shape the current distribution from the anode. The provided configuration effectively redistributes ionic current in the plating system allowing plating of uniform metal layers and mitigating the terminal effect.

Abstract: A copper foil structure having blackened ultra-thin copper foil of the instant disclosure includes a carrier foil, a blackened layer, a release layer, and an ultra-thin copper foil. The carrier foil includes a matte surface and a shiny surface wherein the blackened layer is disposed thereon. The release layer is disposed on the blackened layer formed with one selected from the group: copper, cobalt, nickel, and manganese while the release layer is formed with one selected from the group: molybdenum, nickel, chromium, and potassium. Successively, the ultra-thin copper foil is disposed on the release layer. Laser drilling can apply to the blackened ultra-thin copper foil on the inner layers of a high density multi-layer printed wiring board, thus eliminating the traditional blackening or browning chemical process. The blackened ultra-thin copper foil in combination with a polyimide thin (PI) or other substrate materials displays desirable appearance.

Abstract: A method for electrochemically reducing CO2 is provided. A cathode is provided, wherein the cathode comprises a conductive substrate with a catalyst of a metal and a metal oxide based coating on a side of the cathode. An anode is spaced apart from the cathode. An ionic transport is provided between the anode and cathode. The cathode is exposed to CO2 and H2O. The anode is exposed to H2O. A voltage is provided between the cathode and anode.

Abstract: A method of using clathrate hydrates (including ammonia clathrates), in electrochemical transformations. Noted are converting clathrate guest molecules such as CO2, CH4, alkanes, and alkenes; and, optionally, the use of clathrates-promoting molecules such as tetra hydro furan, to produce higher value carbon molecules including propane and formic acid.

Abstract: A method for producing methanol from methane in which methane is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing methanol and electrons on the anode side. The electrons are conducted to a cathode electrode disposed on a cathode side of the electrolyte membrane, thereby transforming water provided to the cathode side to H2 gas and hydroxide ions. The method is carried out at a temperature less than or equal to about 160° C., preferably at room temperature.

Abstract: An apparatus and method for CO2 reduction using an Au25 electrode. The Au25 electrode is comprised of ligand-protected Au25 having a structure comprising an icosahedral core of 13 atoms surrounded by a shell of six semi-ring structures bonded to the core of 13 atoms, where each semi-ring structure is typically —SR—Au—SR—Au—SR or —SeR—Au—SeR—Au—SeR. The 12 semi-ring gold atoms within the six semi-ring structures are stellated on 12 of the 20 faces of the icosahedron of the Au13 core, and organic ligand —SR or —SeR groups are bonded to the Au13 core with sulfur or selenium atoms. The Au25 electrode and a counter-electrode are in contact with an electrolyte comprising CO2 and H+, and a potential of at least ?0.1 volts is applied from the Au25 electrode to the counter-electrode.

Abstract: A method for preparation of highly porous and preferentially-oriented {100} platinum on a substrate by electrodeposition in a deposition bath, comprising using a deposition potential Edep lower than ERHE+150 mV and an acidified platinum salt solution having a Pt salt concentration less than 5.0 mmole L?1 or, in presence of hydrogen, comprising limiting the concentration of Pt salts in the electrolyte to less than 5.0 mmole L?1 and controlling the temperature of the electrolyte. Preferentially-oriented {100} platinum nanowires and thin films, comprising Pt{100} in a range between about 20 and about 60% and having a roughness factor of at least 50 are produced.