Abstract: Provided is a method of synthesizing apatite powder by emitting a laser beam to a surface of a substrate immersed in a precursor solution. The method is including immersing a substrate in an apatite-forming precursor solution, emitting a laser beam to a region on a surface of the substrate immersed in the precursor solution, and obtaining apatite powder generated in the precursor solution.

Abstract: The present invention relates to a method for preparing carbon nanotubes, the method including: preparing a support including AlO(OH) by primary heat treatment of Al(OH)3; preparing an active carrier by supporting a mixture including a main catalyst precursor and a cocatalyst precursor on the support; drying the active carrier through multi-stage drying including vacuum drying; preparing a supported catalyst by secondary heat treatment of the dried active support; and preparing carbon nanotubes in the presence of the supported catalyst, and the carbon nanotubes prepared by the method as described above can remarkably improve conductivity.

Abstract: Superficially porous particles are disclosed, each including a solid core and a layered porous shell. The layered porous shell includes a porous inner layer and at least one porous outer layer, a shell skeleton thickness greater than 1 nm, and constitutes from 10 vol % to 90 vol % of the plurality of superficially porous particles. The porous inner layer includes an inner layer thickness of less than 300 nm. The at least one porous outer layer includes a cumulative outer layer thickness ranging from 1 to 100 times the inner layer thickness, a predominately radial pore orientation, and an outer layer pore structure which is more organized than the inner layer pore structure. A layer-by-layer process for forming a plurality of superficially porous particles with layered structure is disclosed. A post-modification process for preparing a plurality of chromatographically enhanced superficially porous properties is also disclosed.

Abstract: A method for synthesizing a pre-hydrolyzed polysilicate, wherein a polysilicate is applied as a reactant when synthesizing the pre-hydrolyzed polysilicate, and the total amount of water added in the reaction system is specified. The method is capable of omitting a condensation reaction by applying a polysilicate as a reactant, thereby significantly shortening synthesis time and reducing production costs when compared with a typical synthesis method in which alkoxysilane-based monomer compound is used as a reactant. In addition, the gelation reaction time and the weight average molecular weight can be easily controlled, and a pre-hydrolyzed polysilicate excellent in storage stability and processability can be synthesized.

Abstract: The invention discloses a coordination type zirconium phosphotungstate catalyst and its application in catalytic hydrogenation of furfural, belonging to the field of heterogeneous catalysis. The zirconium phosphotungstate catalyst prepared by the invention not only has good catalytic effect on the conversion of furfural to furfuryl alcohol, but also has mild reaction conditions. The yield of solid line furfuryl alcohol can be 98% if it can be reacted for 1 h at 120 ° C., and the amount of catalyst is less, which greatly reduces the energy consumption in the prior art. In addition, the zirconium phosphotungstate prepared by the invention is easy to separate, has good stability for catalyzing the hydrogenation of furfural to furfuryl alcohol, and is a new, efficient and green catalyst.

Abstract: A process for the hydrophobization of a porous silica based compound involves the steps of providing a composition (I) containing a porous silica based compound, treating the composition (I) with a composition (II) containing hexamethyldisiloxane or its hydrolyzed form, and removing the treated silica based compound. The porous silica based compound obtained by the process is useful. A porous silica based compound obtained or obtainable by the process can be used for medical and pharmaceutical applications, as adsorbents, for cosmetic applications, as an additive for food, as a catalyst support, for the preparation of sensors, or for thermal insulation.

Abstract: The present invention relates to catalysts, methods of making catalysts, and methods of using catalysts, where the catalysts include: at least one of a transition metal and a transition metal oxide supported by yttria-stabilized zirconia (YSZ), where the transition metal is promoted by at least one of an alkali metal and an alkaline-earth metal.

Abstract: Provided is an aerogel blanket and a method for producing the same, wherein a catalyzed sol I sufficiently and uniformly impregnated into a blanket in an impregnation tank, and the catalyzed sol is allowed to stay in the impregnation tank for a specific time to control fluidity while achieving a viscosity at which the catalyzed sol can be easily introduced into the blanket, thereby forming a uniform aerogel in the blanket. As a result, the uniformity of pore structure and thermal insulation performance of an aerogel blanket are improved, the loss of raw materials is reduced through the impregnation process, the occurrence of process problems is reduced, and the generation of dust is reduced.

Abstract: The present invention relates to a process for preparing waterglass-based silica aerogels, wherein the process comprises (a) subjecting a certain amount of a vinyltrialcoxysilane to hydrolysis in the presence of water and an inorganic acid under stirring conditions to produce a hydrolyzed vinyltrialcoxysilane solution; (b) treating a waterglass solution with an acidic cationic-exchange resin to produce a silicic acid solution; (c) forming a sol phase by contacting the hydrolyzed vinylalcoxysilane solution with the silicic acid solution; (d) forming a gel phase by adjusting the pH of the sol phase to a value in the range of from 4 to 6; and (e) subjecting the gel phase to supercritical drying to produce an aerogel. The present invention is also related to waterglass-based silica aerogels obtained by the process according to the invention, which are functionalized with vinyl groups.

Abstract: The invention relates to a method for producing alkali metal cyanides as solids, comprising the steps: i) an absorption step in the form of the absorption of hydrogen cyanide from a syngas containing hydrogen cyanide in an aqueous alkali metal hydroxide solution; ii) a preparation step for the waste gases containing cyanide that have accumulated in step i); iii) a crystallization step in the form of the introduction of the alkali metal cyanide solution into an evaporative crystallizer; iv) a condensation step for the vapour containing cyanide that has accumulated in step iii) to obtain a vapour condensate containing cyanide; v) a recirculation step, in which the vapour condensate containing cyanide that has been obtained in step iv) is used as an aqueous liquid in step ii).

Abstract: A system and method of combusting aluminium comprising i) feeding aluminium wire to a substantially oxygen-free furnace comprising a. a first low-temperature section in communication with b. a second high-temperature section ii) forming aluminium particles with an average particle size ranging from 1 ?m to 200 ?m from said aluminium wire in said first section iii) feeding water and/or steam to said first and/or second section to provide an oxidizer for oxidizing said aluminium particles in the second section iv) conveying aluminium particles from the first section to the second section v) oxidizing said aluminium particles in the presence of steam in said second section.

Abstract: Methods for fabricating thermally stable reducible metal oxide catalyst support structures on a base material using a multi-step incipient wetness impregnation (IWI) process are disclosed. For example, reducible metal oxide catalyst support structures having high surface area and high thermal stability may be formed using a multi-step IWI process, where the support structure is generated through high-temperature calcination between IWI steps. The metal or metal oxide catalysts fabricated using the methods are also disclosed. The generation of engineered surface defects on reducible metal oxides using a gas reduction process to serve as anchoring sites for metal or metal oxide catalysts is also disclosed. Generating engineered defects through a gas reduction process may be a relatively low-cost and scalable process suitable for fabricating efficient catalysts using a wide range of materials.

Abstract: A catalyst obtainable by exsolving particles of Ni, Co and/or a mixture of Ni and Co from a perovskite metal oxide of formula (I) (M1aM2b)(COxNiyM3z)O3, wherein M1 and M2 are each independently an alkali earth metal or a rare earth metal, M3 is Ti or Cr, 0?a?1, 0?b?1, 0<a+b?1, 0?x<1, 0?y<1, 0?z<1, x+y+z=1 and where at least one of x and y>0. The invention includes methods of converting this catalyst into one or more catalytically active forms. The catalysts and the activated forms of same are useful in the catalysing CO oxidation and/or NO oxidation.

Abstract: A method for regenerating a deactivated denitration catalyst includes steps of preparing a washing fluid including a water-contained liquid and entrained carbon dioxide bubbles, and subjecting the deactivated denitration catalyst to a treatment with the washing fluid. An apparatus for regenerating the deactivated denitration catalyst is also provided.

Abstract: A method for producing hydrotalcite particles includes dissolving aluminum hydroxide in an alkaline solution to prepare an aluminate solution, causing a reaction of the aluminate solution prepared in the first step with carbon dioxide to precipitate a low-crystallinity aluminum compound, causing a first-order reaction by mixing the low-crystallinity aluminum compound with a magnesium compound to prepare a reactant containing hydrotalcite nuclear particles, and causing a hydrothermal reaction of the reactant to synthesize hydrotalcite particles. The hydrotalcite particles can impart excellent heat resistance, transparency, flowability, and are useful as a resin stabilizer.

Abstract: The present disclosure relates to the technical field of catalysts, and specifically to a Zn—Al slurry catalyst, its preparation method and its application in preparing ethanol from syngas. The preparation method provided in the disclosure prepares the Zn—Al slurry catalyst by introducing a zinc component into an aluminum sol, and the preparation method has a simple operation and a lower cost. The Zn—Al slurry catalyst prepared in the disclosure includes the Zn component and the Al component, which may catalyze syngas to generate ethanol under mild conditions. Also, the catalyst has stable properties, is not easy to be deactivated, and reduces the cost of preparing ethanol from syngas. When the Zn—Al slurry catalyst provided in the disclosure is used as the catalyst for preparing ethanol from syngas, the reaction conditions are mild, and the syngas may be catalyzed to generate ethanol under the conditions of 250-340° C. and 3-5 MPa.

Abstract: A method for preparing a graphene based composite wave-absorbing material includes: dissolving a water soluble barium salt and a water soluble iron salt into deionized water, respectively; mixing barium salt solution and iron salt solution according to a molar ratio of Ba:Fe of 1:12 to obtain a precursor solution; dispersing a graphene material in deionized water to form a graphene dispersion; adding citric acid, nitric acid and the graphene dispersion into the precursor solution in sequence to form a mixture solution; stirring the mixture solution at a temperature of 50 to 75° C. to obtain a sol; coating and drying aged sol on a substrate to obtain a coating layer; and sintering the coating layer by a laser irradiation.

Abstract: Provided is polycrystalline diamond having a diamond single phase as basic composition, in which the polycrystalline diamond includes a plurality of crystal grains and contains boron, hydrogen, oxygen, and the remainder including carbon and trace impurities; the boron is dispersed in the crystal grains at an atomic level, and greater than or equal to 90 atomic % of the boron is present in an isolated substitutional type; hydrogen and oxygen are present in an isolated substitutional type or an interstitial type in the crystal grains; each of the crystal grains has a grain size of less than or equal to 500 nm; and the polycrystalline diamond has a surface covered with a protective film.

Abstract: A phosphorus production method can include reducing feed containing phosphate ore and providing a silica ratio from 0.3 to 0.7 in a reaction chamber from 1250 to 1380° C. Less than 20% of the phosphate remains in the residue. Another phosphorus production method includes continuously moving a reducing bed through the reaction chamber with the feed agglomerates substantially stable while in the reducing bed. Reaction chamber temperature can be from 1250 to 1380° C. A phosphorus production system includes a barrier wall segmenting the reaction chamber into a reduction zone differentiated from a preheat zone. The bed floor is configured to move continuously from the preheat zone to the reduction zone during operation. A method for producing a reduction product includes exothermically oxidizing reduction/oxidation products in the reaction chamber, thereby adding heat to the reducing bed from the freeboard as a second heat source.

Abstract: A method for preparing carbon-functionalized praseodymium oxide includes the following steps: dissolving Pr(NO3)3·6H2O in an acid dye solution and stirring to form a mixed solution; adding NH3H2O dropwise in the mixed solution while stirring to adjust a pH value of the mixed solution, thereby forming a suspension, and then aging the suspension for 2 to 4 hours; filtering, washing with water, washing with alcohol, and drying the aged suspension to obtain a carbon-functionalized Pr6O11 precursor; and placing the carbon-functionalized Pr6O11 precursor in a tube furnace under a protection of nitrogen, heating the carbon-functionalized Pr6O11 precursor to a sintering temperature at a heating rate of 4 to 6 degrees Celsius/min, keeping at the sintering temperature for 3 to 4 hours, and then cooling to room temperature, thereby obtaining the carbon-functionalized Pr6O11.