Patents Examined by Louis M. Troilo
  • Patent number: 5656250
    Abstract: A three-dimensional network structure comprising three-dimensionally interconnected spherical silica particles, having specific physical characteristics including diameter, pores on the surfaces of the particles, cross-sectional areas of the bonds interconnecting the spherical silica particles, elasticity modulus, voids content, and silica content, the surfaces of the spherical silica particles being wholly or partly covered with a water-soluble polymer, the network structure being able to remain substantially intact when heat-treated and being able to undergo machining. There is also provided a method of making a three-dimensional network structure comprising spherical silica particles, comprising hydrolyzing and polymerizing a low polymer of an alkoxysilane in a mixed solution containing the alkoxysilane low polymer and a water-soluble polymer in a mixed solvent composed of water and an alcohol in the presence of an acid catalyst.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: August 12, 1997
    Assignee: Jiro Hiraishi, Director-General, Agency of Industrial Science and Technology
    Inventors: Yuko Tanaka, Muneaki Yamaguchi, Hiromasa Ogawa, Katsutoshi Tanaka
  • Patent number: 5653794
    Abstract: The present invention provides a process for the production of hydrophobic inorganic oxide products which comprises reacting the inorganic oxide particles with organohalosilanes, preferably organochlorosilanes, to produce hydrophobic organosilane coated inorganic oxides. It is preferred that the organohalosilane compounds be reacted with the inorganic oxide particles in an aqueous slurry. The inorganic oxide pigments prepared by the processes of this invention have essentially quantitative retention of the organosilanes and contain no adsorbed aldehydes on their surface. The by-products produced in the preferred embodiments of the invention are innocuous salts, which are environmentally safe and readily disposable.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: August 5, 1997
    Assignee: SCM Chemicals, Inc.
    Inventors: Leon Weber, Robert J. Kostelnik, Charles Wheddon
  • Patent number: 5651804
    Abstract: A novel copper activated thermoluminescence dosimeter comprising a glass composition having: about 94-97 weight percent SiO.sub.2 ; about 0.4 to 2 weight percent Al.sub.2 O.sub.3 ; about 0.02 to 1 weight percent M.sub.2 O, where M comprises Na.sup.+ or K.sup.+ ; about 2 to 6 weight percent B.sub.2 O.sub.3 ; and Cu(I), where Cu(I) is present at a level between about 10.sup.18 to 10.sup.19 ions/cm.sup.3 ; method of making the same.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: July 29, 1997
    Assignee: Council of Scientific & Industrial Research
    Inventor: Radhaballabh Debnath
  • Patent number: 5650367
    Abstract: A dielectric ceramic composition containing, per 100 parts by weight of BaTiO.sub.3, at least either one of Nb.sub.2 O.sub.5 or Ta.sub.2 O.sub.5 in an amount of from 0.8 to 3.5 parts by weight, MgO in an amount of from 0.06 to 0.7 parts by weight, oxides of rare earth elements in an amount of from 0.005 to 0.520 parts by weight, and MnO in an amount of from 0.01 to 0.30 parts by weight in the form of MnCO.sub.3, the molar ratio of MgO to either Nb.sub.2 O.sub.5 or Ta.sub.2 O.sub.5 being from 0.5 to 2.2. The dielectric ceramic composition has a dielectric constant of not smaller than 2500, is fired at a temperature of not higher than 1300.degree. C., exhibits a change of capacitance depending upon the temperature satisfying X7R of the IEA Standards, a dielectric loss of not larger than 2.5%, a small voltage dependence, and an insulation resistance of not smaller than 10.sup.4 M.OMEGA., and is suited as a material for producing ceramic capacitors and resonators.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: July 22, 1997
    Assignee: Kyocera Corporation
    Inventors: Nobuyoshi Fujikawa, Yoshihiro Fujioka, Yasushi Yamakuchi, Shin-ichi Osawa, Hiroshi Ojima
  • Patent number: 5648301
    Abstract: Novel non-crystalline, porous bioactive glass and ceramic materials that permit the in vitro formation of bone tissue when exposed to a tissue culture medium and inoculated with cells are disclosed. The present invention also discloses methods of treating bioactive glass materials to control pH so that when the glass is exposed to a tissue culture medium and then inoculated with cells, bone tissue growth occurs in vitro. The glass material disclosed is preferably formed from SiO.sub.2, CaO, Na.sub.2 O and P.sub.2 O.sub.5 and the porous, non-crystalline structure is most preferably created by melting the constituents, cooling and pulverizing the resulting glass, and then forming and hot pressing the powder. The glass of the present invention may be formed to produce templates that are useful for various indications, as well as granules that may be formed into a paste.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 15, 1997
    Assignee: Trustees of the University of Pennsylvania
    Inventors: Paul Ducheyne, Ahmed El-Ghannam, Irving Shapiro
  • Patent number: 5646078
    Abstract: An aluminum nitride powder comprising polycrystalline particles which have clearly observed grain boundaries, an agglomerated particle size of 0.1 to 100 .mu.m when measured by a particle size distribution analyzer, a tapped bulk density of 0.55 to 2.0 g/cm.sup.3, and a ratio of a number average particle size calculated from a SEM photograph image to a particle size calculated from a BET specific surface area of 1.1 to 3.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: July 8, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masahide Mohri, Shinichiro Tanaka, Takeshi Miyai
  • Patent number: 5643840
    Abstract: A low temperature sealing composition comprising PbO--B.sub.2 O.sub.3 --Bi.sub.2 O.sub.3 glass powder with a reduced amount of SiO.sub.2 content but with an addition of GeO.sub.2 so as to realize a lowered sealing temperature such as 400.degree.-310.degree. C. The glass powder consists essentially of 25-85 wt. % of PbO, 1-11.2 wt. % of B.sub.2 O.sub.3, 5.1-70 wt. % of Bi.sub.2 O.sub.3, 0.1-20 wt. % of GeO.sub.2, 0-5 wt. % of SiO.sub.2, 0-10 wt. % of Fe.sub.2 O.sub.3, 0-10 wt. % of CuO, 0-15 wt. % of ZnO, 0-5 wt. % of TiO.sub.2, and 0-9 wt. % of F.sub.2. The glass powder may be used by mixing with 15-55 vol. % of refractory filler powder of at least one element which is selected from the group consisting of lead titanate based ceramic powder, willemite based ceramic powder, cordierite ceramic powder, zircon based ceramic powder, tin oxide solid solution powder, and alumina powder.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: July 1, 1997
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hajime Hikata, Yoshitaka Jimura, Kumi Tanaka
  • Patent number: 5643841
    Abstract: A resistive paste comprising (a) a solid content comprising (al) a resistive material having a composition of Nb.sub.x La.sub.1-x B.sub.6-4x, wherein x is from 0.1 to 0.9 mol, and (a2) non-reducing glass frit, (b) from 1 to 10% by weight, based on the solid content, of TiO.sub.2 as a first additive, (c) from 1 to 10% by weight, based on the solid content, of at least one second additive selected from the group consisting of Co.sub.3 O.sub.4, CoO, and Fe.sub.2 O.sub.3, and (d) an organic vehicle.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: July 1, 1997
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Sachiko Yamaki, Keisuke Nagata, Hiroji Tani
  • Patent number: 5635433
    Abstract: A novel ceramic ferroelectric material having a high dielectric constant, a ow loss tangent, a low threshold voltage, a high nonlinear voltage exponent and a high tunability. The material is a composite comprising Barium Strontium Titanate (BSTO) and zinc oxide (ZnO). The preferred composite is represented by Ba.sub.1-x Sr.sub.x TiO.sub.3 --ZnO, wherein x is greater than 0.00, but less than or equal to 0.75, and wherein the percent weight ratio between BSTO and ZnO ranges from approximately 99%-50% and 1%-50% respectively. The novel materials possess superior electronic properties, and they may be employed in multilayer capacitors, capacitor-varistors, non-volatile computer memory or phased array antenna systems.
    Type: Grant
    Filed: September 11, 1995
    Date of Patent: June 3, 1997
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Louise Sengupta
  • Patent number: 5635250
    Abstract: A method is provided for preparing ceramic precursors from hydridosiloxane starting materials and then pyrolyzing these precursors to give rise to silicious ceramic materials. Si--H bonds present in the hydridosiloxane starting materials are catalytically activated, and the activated hydrogen atoms may then be replaced with nonhydrogen substituents. These preceramic materials are pyrolyzed in a selected atmosphere to give the desired ceramic product. Ceramic products which may be prepared by this technique include silica, silicon oxynitride, silicon carbide, metal silicates, and mullite.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: June 3, 1997
    Assignee: SRI International
    Inventors: Yigal D. Blum, Sylvia M. Johnson, Michael I. Gusman
  • Patent number: 5631195
    Abstract: A glass composition comprising from 45 to 66 wt % of SiO.sub.2, from 0 to 15 wt % of Al.sub.2 O.sub.3, from 10 to 24 wt % of Li.sub.2 O+Na.sub.2 O+K.sub.2 O, from 14 to 26 wt % of CaO+MgO+SrO+BaO+ZnO, and from 0 to 1 wt % of SO.sub.3 +Sb.sub.2 O.sub.3, said glass composition containing substantially no zirconia and having a strain point of at least 560.degree. C. and a linear thermal expansion coefficient of at least 80.times.10.sup.-7 /.degree.C. within a temperature range of from 50.degree. to 350.degree. C.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: May 20, 1997
    Assignee: Asahi Glass Company Ltd.
    Inventors: Osamu Yanagisawa, Kenji Oda, Naoki Sugimoto, Yoshio Takegawa, Akira Takada, Hideyo Osada, Haruo Aizawa, Koji Miura
  • Patent number: 5629248
    Abstract: A preferred embodiment of a sulfide glass with improved mechanical and optical properties such as extended transmission in the infrared region of radiation having wavelengths of up to about 15 microns, Tg in the range of 370.degree.-550.degree. C., and thermal stability of 100.degree.-300.degree. C., containing, on mol basis, 36-72% germanium sulfide, 2-38% gallium sulfide and/or indium sulfide, and 26-62% of at least one modifier containing an alkaline earth sulfide. A process for making glass of improved mechanical and optical properties comprises the steps of mixing glass components, including an alkaline earth modifier in elemental or sulfide form; melting the glass components in an inert vessel contained in a sealed ampoule to form a molten mixture; cooling the molten glass mixture to a solid state; annealing the solid glass; and cooling the annealed glass to about room temperature.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: May 13, 1997
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Ishwar D. Aggarwal, Celia I. Merzbacher, Barry B. Harbison, John M. Jewell
  • Patent number: 5627113
    Abstract: A novel copper activated thermoluminescence dosimeter comprising a glass composition having: about 94-97 weight percent SiO.sub.2 ; about 0.4 to 2 weight percent Al.sub.2 O.sub.3 ; about 0.02 to 1 weight percent M.sub.2 O, where M comprises Na.sup.+ or K.sup.+ ; about 2 to 6 weight percent B.sub.2 O.sub.3 ; and Cu(I), where Cu(I) is present at a level between about 10.sup.18 to 10.sup.19 ions/cm.sup.3 ; method of making the same.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: May 6, 1997
    Assignee: Council of Scientific & Industrial Research
    Inventor: Radhaballabh Debnath
  • Patent number: 5627114
    Abstract: This invention is directed to the production of glass articles transparent to visible radiation, but opaque to ultraviolet radiation, rendering them particularly suitable for protecting the wearer of such lenses from exposure to laser radiation in the ultraviolet regions of the electromagnetic spectrum. The method involves exposing silver halide-containing glass articles to flowing hydrogen in a heat chamber operating at 375.degree.-500.degree. C. for at least four hours to produce an integral reduced layer in at least one surface of the articles of sufficient depth to prevent the transmission of ultraviolet radiation through the articles.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: May 6, 1997
    Assignee: Corning Incorporated
    Inventors: Thomas G. Havens, David J. Kerko, JoAnn Morrell
  • Patent number: 5627115
    Abstract: The invention relates to brownish, brown to black colored borosilicate glasses which have stepped grades of transmission in the NIR range or are fully non-transmitting. The borosilicate glass, primarily the borosilicate glass 3.3, is melted with defined additives of titanium carbide and/or metallic silicon. The glasses produced in accordance with the invention are to be used as filters, glass vessels and/or decorative colored glass in construction and for decorating because of their absorption/transmission characteristics. On the other hand, the glasses produced in accordance with the invention can also be used as absorbers in solar technology when the light transmissibility in the NIR/IR range is sufficiently low.
    Type: Grant
    Filed: August 7, 1995
    Date of Patent: May 6, 1997
    Assignee: JENAer Glaswerk GmbH
    Inventors: Eckhart Watzke, Andrea Kampfer, Thomas Kloss, Gerhard Kemmler
  • Patent number: 5626923
    Abstract: A method for providing a ceramic coating on a ceramic or metallic substrate and the ceramic coating composition useful therein. The coating composition comprises a putty-like material comprising a colloidal silica, a base for gelling the silica, a filler, and no more than 50 wt. % of a volatile solvent or solvents. The putty-like material is rolled onto the desired substrate and cured to form a protective ceramic coating of any desired thickness. The cured coating may be fired, if desired.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: May 6, 1997
    Assignee: McDonnell Douglas Corporation
    Inventors: Jerry M. Fitzgibbons, James E. French
  • Patent number: 5624652
    Abstract: Amorphous silicas suitable for use as abrasives in transparent toothpastes can be prepared by a precipitation route. These silicas are distinguished by having a BET surface area of 10 to 90 M.sup.2 /g, a weight mean particle size of 5 to 15 micron, and a plastics abrasion value of 16 to 20, a transmission of at least 70% in the RI range from 1,430 to 1,443 and an oil absorbtion in the range from about 70 to about 150 cm.sup.3 /100 g.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: April 29, 1997
    Assignee: Crosfield Limited
    Inventors: Derek Aldcroft, Peter W. Stanier
  • Patent number: 5622903
    Abstract: Irregularly shaped glass fibers and insulation therefrom comprise two different glasses having differing coefficients of thermal expansion. These glasses also have physical properties which allow current processes to fabricate them into insulation. The glasses also meet German recommendations regarding a KI value of 40 or above.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: April 22, 1997
    Assignee: Owens-Corning Fiberglas Technology, Inc.
    Inventors: Charles F. Rapp, Russell M. Potter
  • Patent number: 5622553
    Abstract: A substance for increasing friction between two surfaces such as two metallic surfaces has a gel base material determining the viscosity of the substance and contains hard crystals mixed into the gel based material. A plurality of the hard crystals is comprised of a first particles of the first substantially identical particle size and second particles of the second substantially identical particle size. The first and second particle sizes have a fixed ratio relative to one another.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: April 22, 1997
    Inventors: Bernhard Jakob, Michael Klemm
  • Patent number: 5618764
    Abstract: A colored ceramic composition comprising, as inorganic components, from 5 to 40 wt % of a colored heat resistance pigment powder, from 60 to 95 wt % of a zinc-containing glass powder and from 0 to 10 wt % of a refractory filler powder, wherein said glass powder consists essentially of the following components:______________________________________ SiO.sub.2 27 to 40 wt % B.sub.2 O.sub.3 10 to 20 wt % ZnO 35 to 45 wt % Li.sub.2 O 0 to 5 wt % Na.sub.2 O 0 to 10 wt % K.sub.2 O 0 to 5 wt % Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0 to 15 wt %.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: April 8, 1997
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroshi Usui, Hitoshi Onoda, Tsuneo Manabe