Abstract: Systems are provided for gel electrophoresis and electrotransfer that comprise one or more chambers that can removably and interchangeably receive either an electrophoresis cassette, or an electrotransfer cassette, and provide an electrical interface for both electrophoresis and electrotransfer of biomolecules. Electrophoresis devices including clamps and electrotransfer cassettes and related devices are provided. Methods for electrophoresis and electrotransfer using the systems and devices are also provided.

Abstract: Provided is a method for monitoring a change of ion strength in a sample solution by a closed-loop device that provides continuous cycling of electrochemical pH modulation between pre-defined pH values. In particular, the change of ion strength may be induced by a chemical reaction and may ultimately alter the electrical control parameters of the closed-loop device. By measuring such electrical control parameters, the degree and progress of the underlying chemical reaction may be monitored.

Abstract: Devices for detecting an analyte in a sample suspected of containing the analyte, are provided. The devices include bio-functional, nanostructured, isoporous membranes (BNIM) integrated organic electrochemical transistor (OECT), herein BNIM-OECT, for the rapid and sensitive detection of the presence of an analyte of interest, in a sample, for example, a biological sample. The membrane (i.e., BNIM) is physically separated from the OECT channel therefore the electronic device can be used multiple times. The isoporous membrane is functionalized to include a binding partner for the analyte being detected. The BNIM-OECT can be used for disease detection, by functionalizing the BNIM-OECT with a binding partner to an analyte associated with the disease, applying a collected biological sample to the BNIM-OECT. A decrease in channel current as a result of analyte binding to its binding partner on the isoporous membrane indicates the presence of the analyte in the sample.

Abstract: An embodiment provides a catalyst for water electrolysis which includes an iridium mixed phase formed by physical mixing of two or more selected from metal iridium (Ir), iridium(III) oxide (Ir2O3), or iridium(IV) oxide (IrO2) and has a structure in which nanosheets composed of the iridium mixed phase are stacked. The catalyst for water electrolysis may exhibit high activity and stability for the oxygen evolution reaction in water electrolysis.

Abstract: One object of this application is to provide an advanced substrate holder including a clamper. A substrate holder for holding a substrate by interposing the substrate between frames is disclosed. The substrate holder includes a front frame, a rear frame, and one or a plurality of clampers. Each of the clampers includes a hook portion including a hook base and a hook main body, and a plate including at least one claw. At least one of the clampers includes the plate including a first claw for a lock and a second claw for a semi-lock.

Abstract: A solar fuels generation system includes a first reactor that contains a first solution in which a charge carrier is reduced to a reduced charge carrier. The system also includes a second reactor that contains a second solution in which the reduced charge carrier reduces protons so as to generate hydrogen gas.

Abstract: An electrode includes an electrically conductive substrate and a layer of a molybdenum-doped zinc/cobalt oxide (ZnCo2-xMoxO4). The surface of the electrically conductive substrate is at least partially covered by the layer of ZnCo2-xMoxO4, where x is a positive number equal to or less than about 0.1, and the layer of the ZnCo2-xMoxO4 includes spherical-shaped particles. The electrode has a Tafel slope from 75 millivolts per second (mV/s) to 115 mV/s, and a potential of 0.27 to 0.30 volts relative to the reversible hydrogen electrode (VRHE) at a current density of about 50 mA/cm2 for a duration of at least 40 hours.

Abstract: The invention relates to an electrodialysis device for the desalination of water for oil and gas applications comprising: a membrane stack comprising alternating cation- and anion-exchange membranes (2.1, 2.3) and a plurality of spacers (2.2, 2.4), each spacer being arranged between two successive membranes; wherein at least one of the spacers (2.2, 2.4) comprises a recessed area (3.2) and a non-recessed area (3.3), a central opening (3.1) within the recessed area (3.2); the spacer (2.2, 2.4) is provided with at least four orifices (3.4, 3.5) within the non-recessed area (3.3); and with respective channels (3.6) which connect at least two of the orifices (3.4) with the central opening (3.1); and one membrane (2.1, 2.3) is accommodated in the recessed area (3.2). The invention also relates to a water desalination process using the electrodialysis device mentioned above.

Abstract: Integrations of carbon monoxide electrolyzers and chlor-alkali electrolyzers are disclosed herein. The disclosed integrations include novel process chains for the valorization of oxocarbons into hydrochloric acid, vinyl chloride, vinyl acetate, ethylene oxide, and other useful chemicals. The disclosed integrations further include novel ways to operate the electrolyzers in tandem to increase the efficiency of both reactors. This disclosure also includes novel ways to balance the operation of both electrolyzers to assure they are operating at an optimal level to take advantage of the benefits of the disclosed integrations.

Abstract: Embodiments of the invention are directed to a system for detecting neurotransmitters. A non-limiting example of the system includes a porous electrode. A system can also include a pH sensor attached to the porous electrode, wherein the pH sensor includes a sensing electrode and a reference electrode. The system can also include electronic circuitry in communication with the pH sensor.

Abstract: A sensor may include a sensing element retained within a storage compartment filled with a storage medium, which may also be used as a calibration medium. The sensing element can include a sensing surface located away from the distal end of the sensing element, such that an inactive section of the sensing element can cooperate with a sealing member such as an O-ring to form part of the seal retaining the storage/calibration medium. The sensing element can be extended and retracted from the storage compartment to expose the sensing surface to a process medium, while preserving the storage medium within the storage compartment for post-measurement validation.

Abstract: A bipolar electrodialysis (BPED) cell is able to bipolar convert salt solutions into acid and base solutions. However, protons migrate through the anion exchange membranes and tend to neutralize the base solution. In a bipolar electrodialysis system described herein, multiple BPED cells are arranged to provide a multi-stage treatment system. Up to half, or up to one third, of the stages have cells with acid block anion membranes. The one or more stages with acid block anion membranes are located at the acid product output end of the system, where the acid concentration in the system is the highest. Replacing the traditional anion membranes in some of the stages with acid block anion membranes allows higher concentration products to be produced with moderate increase in energy consumption.

Abstract: The design of bifunctional catalysts for water splitting by modifying the electronic structure of the catalyst. That bifunctional catalyst that is synthesized is a quaternary FeNi—PSe nanoporous film (FeNi—PSe NF). A self-supported FeNi—PSE NF is synthesized and used as an anode and a cathode in a two-electrode electrolytic cell. The cell is subjected to a water source, and the FeNi—PSe NFs split the water molecules to produce hydrogen fuel. The slightly oxidized FeNi—PSe surface serves as an active site for oxygen evolution reactions, making hydrogen evolution reactions and oxygen evolution reactions well-balanced, thereby improving electrolysis efficiency.

Abstract: The disclosure provides for a device and method for initiating an electrocoagulation reaction. The device may include one or more electrodes, conductive rods, conductive pipe, non-conductive pipe, and an adjustable power source wherein the electrodes have cutouts through each to allow for concentrated magnetic and electrical fields to form increasing the efficiency of the electrocoagulation reaction. The adjustable power source may be connected to the electrodes, conductive rods, and conductive pipe. The electrocoagulation device may be combined with another electrocoagulation device wherein each electrocoagulation device comprises electrocoagulation electrodes different than that of the electrocoagulation electrodes of the other electrocoagulation device. The present invention provides for contaminant removal from fluids such as wastewater including such wastewaters as fracking water, plating waste water, septic waste water and the like, potable water, pond water, hot tub water, and the like.

Abstract: A glucose sensor includes an insulating metal oxide layer and at least one pair of metallic electrodes arranged on the insulating metal oxide layer and separated by a gap containing the metal oxide layer. In operation, a probe including a voltage supply and current sensor can provide a voltage difference across the first and second metallic electrodes while a sample is present across the gap between the electrodes. A measured current between the first and second metallic electrodes when the voltage difference is provided can be correlated to a glucose level of the sample.

Abstract: An electrolytic eluent generator includes an electrolyte reservoir and at least one eluent generation cartridge. The electrolyte reservoir includes a chamber containing an aqueous electrolyte solution; and a first electrode. The at least one eluent generation cartridge includes a platinum mesh electrode; a polymer screen; a plurality of reinforced membranes; a membrane washer; and a spacer including a central post and an annular projection.

Abstract: Provided is a sensor including a substrate that includes a major surface, a sensor part that includes a gas flow path formed of a porous material, and at least one of a heater or a temperature sensor. The heater is capable of heating the sensor part, the temperature sensor is capable of measuring temperature of the sensor part, the sensor part and the at least one of the heater or the temperature sensor are stacked over the major surface, the at least one of the heater or the temperature sensor is an interconnect having forward tapered side surfaces, and the at least one of the heater or the temperature sensor includes a metal interconnect layer, and the forward tapered side surfaces of the interconnect overlap with the gas flow path in plan view of the major surface.

Abstract: A potentiometric oxygen sensor for measuring an oxygen concentration of a liquid metal, which includes a metal tube forming at least one sensor body part, an electrochemical subassembly, and an insert made of a transition metal from group 4 of the Periodic Table or its alloy. The electrochemical subassembly contains an electrolyte, intended to be in contact with the liquid metal, and a reference electrode contained in the electrolyte, the electrolyte being made of yttrium-doped or calcium-doped hafnia (HfO2), or of thoria (ThO2), which is optionally yttrium-doped or calcium-doped, or of yttrium-doped or calcium-doped zirconia (ZrO2). The reference electrode contains at least one metal and its oxide form at the operating temperature of the potentiometric oxygen sensor. The insert is arranged between the sensor body part and the electrolyte, and is attached to the sensor body part and brazed onto the electrolyte by a brazing joint.

Abstract: In the examples provided herein, a system includes an electrochemical sensor having two electrodes inserted in a fluid to be tested, where an alternative current (AC) voltage is applied across the two electrodes; an electrochemical sensor having two electrodes inserted in a fluid to be tested, wherein an alternative current (AC) voltage across the two electrodes; and a frequency response analyzer to analyze the measured the electrical response across multiple frequencies. The system also includes a memory to store a baseline of the electrical response across multiple frequencies, and a processor to determine from the stored baseline and the measured electrical response whether the electrical response is outside a predetermined range.

Abstract: A method of analyzing a molecule is disclosed. A voltage source is selectively connected to or disconnected from a capacitor using a switch controlled by a reset signal. A charge is stored in a capacitor when the voltage source is connected to the capacitor. The capacitor is discharged through a nanopore in a membrane when the voltage source is disconnected from the capacitor. A duty cycle of the reset signal is determined such that the voltage source and the capacitor is connected for at least a one tenth portion of a reset signal period and disconnected for a remaining portion of the reset signal period, such that a voltage across the nanopore is maintained at a higher level during the portion of the reset signal period in which the connection is maintained than during the remaining portion of the reset signal period in which the connection is not maintained.