Abstract: A catalyst which is able to express a high oligomerizing activity of ethylene and a method for the production of &agr;-olefin where ethylene is oligomerized using said catalyst are provided.
The present invention relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-1) a transition metal complex of Groups 4 to 6 of the Periodic Table and also relates to a method for the production of &agr;-olefin by oligomerization of ethylene using said catalyst.
The present invention further relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-2) a transition metal complex of Groups 8 to 10 of the Periodic Table and also relates to a method of the production of &agr;-olefin by oligomerization of ethylene using said catalyst.
Abstract: A process to produce high melt flow propylene polymer comprises polymerizing propylene in the presence of a titanium-containing, magnesium-containing, high activity catalyst and an aluminum alkyl cocatalyst in a gas phase system which uses condensed liquid to control temperature wherein the external catalyst modifier is a tetraalkylorthosilicate, preferably tetraethylorthosilicate, at process conditions of temperature, hydrogen concentration, and Si/Mg, Al/Mg and Al/Si atomic ratios, to produce a high melt flow propylene polymer at high yield.
Type:
Grant
Filed:
January 7, 1998
Date of Patent:
May 2, 2000
Assignee:
BP Amoco Corporation
Inventors:
Chi-Hung Lin, Dennis L. McGinn, Jerome A. Streeky, H. Dale Wilson, Jr., Kanokrot Ja Phalakornkul