Abstract: In subjecting a steel workpiece to nitriding by glow discharge, formation of brittle nitrogen compound is restrained and the surface hardened layer with a nitrogen diffusion layer of high toughness is obtained by making the gas atmospheric condition the gas mixing ratio of N.sub.2 :H.sub.2 =1:2-40. By mixing Ar gas in the above gas atmospheric condition additionally, glow width is adjusted and glow discharge is allowed to enter into narrow concaves at the surface of a workpiece.
Abstract: Nickel aluminide single crystal alloys having improved strength and ductility at elevated temperatures, produced by major elemental additions to strengthen the Ni.sub.3 Al phase by solid solutioning and/or secondary phase formation. The major elemental additions comprise (by weight) 7-20% Al, 0.5-9% molybedenum, 0.5-10% tungsten and 2-15% titanium. Optional minor elemental additions of boron, manganese, silcon and/or hafnium are preferred.