Abstract: Nonlinear optical composites with large third-order optical response compd of metal clusters uniformly dispersed in polymers are prepared by vapor deposition of a metal onto a cold support while simultaneously cocondensing a vapor of an organic material. Where the organic material is a monomer, it polymerizes either when it comes in contact of the metal and/or when the cold surface is warmed. The unpolymerized monomer is removed to yield a processable composite. When the organic material is a diluent, it deposits as a solid on the cold surface forming a dispersion of the solid metal clusters in the liquid diluent. A polymer solution is then mixed with the dispersion and the composite is formed after removal of the diluent and the solvent for the polymer.

Abstract: A laminated material having a latent inherent delamination potential which contains at least one layer comprising a thermoplastic, wherein the thermoplastic carries, at least on one side, a release layer of water-soluble or water-dispersible organic material. The material can be delaminated by a process of chopping the material and treating the material with water or steam. The laminated material is useful as, for example, a packaging material. The material can easily be delaminated into its individual layers, thus facilitating recycling of the materials.

Abstract: This invention embodies an optical medium which consists of polar, multi-monomolecular layers of organic dye molecules with a net polar orientation, considerable second order optical nonlinearity, and excellent thermal stability. The medium is prepared by repeated sequential depositions on a surface of multivalent metal ions, e.g. Zr.sup.4+, and organic dyes terminated with an acidic functionality, e.g. a phosphonic acid, followed by activation of the surface for the next deposition sequence. The monolayers are deposited in the form of a multilayer film containing up to 1000 or more monolayers. The monolayers are deposited from liquid solutions; therefore they may be deposited on substrates having diverse topography and configurations. Second harmonic generation (SHG) analysis establishes that the multilayers have uniform polar order which does not decrease with increasing numbers of monolayers in the film.

Abstract: An optical recording medium capable of reproduction in accordance with the CD standard is provided. The medium includes a reflective thin film of Ag or similar element, an intermediate thin film of Zn or similar element, and a low-melting thin film of Te or similar element wherein light irradiation causes the reflective thin film element and the low-melting thin film element to diffuse into each other to form an alloy or compound of reduced reflectivity. It is possible to determine through simulation a combination of atoms of the respective thin films which form a cluster having HOMO where electrons in the reflective thin film atoms and electrons in the low-melting thin film atoms do not form a hybrid orbital and LUMO where electrons in the reflective thin film atoms and electrons in the low-melting thin film atoms form a hybrid orbital.