Abstract: Disclosed is a pigment dispersion containing at least a pigment, a liquid medium and a high-molecular dispersant. The high-molecular dispersant is a block polymer represented by A-B or A-B-C, in which A, B and C each represent a polymer block and the A and C blocks may be the same or different. The block polymer and its production process are also disclosed. The high-molecular dispersant is free of problems of a smell, coloration, a heavy metal and cost, and its use can provide a pigment dispersion excellent in the dispersion stability of a pigment.
Type:
Grant
Filed:
August 5, 2009
Date of Patent:
September 2, 2014
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Kyoto University
Abstract: The invention relates to water-in-water polymer dispersions containing a polymer A with a cationic monomer fraction of up to 60 wt. % and at least one polymer dispersant B, based on cationised dialkylaminoalkyl (meth)acrylamides with an average molecular weight of between 75,000 and 350,000 g/mol. The invention also relates to a method for producing said dispersions and to the use of the latter.
Type:
Grant
Filed:
November 30, 2005
Date of Patent:
September 2, 2014
Assignee:
Hercules Incorporated
Inventors:
Susanne Bellmann, Norbert Steiner, Joerg Issberner, Christian Boekelo
Abstract: This invention provides an effect pigment-containing, water-borne base coating composition comprising water-dispersible acrylic polymer particles (A) and effect pigment (B), the water-dispersible acrylic polymer particles (A) being obtained by emulsion polymerization of a radical-polymerizable unsaturated monomeric mixture including an amido-containing, radical-polymerizable unsaturated monomer having at least two radical-polymerizable unsaturated groups per molecule, and the effect pigment (B) being contained at a pigment weight concentration (PWC) within a range of 15-50%.
Abstract: The present invention provides a polyvinyl alcohol-based film for optical uses, which is excellent in stretching property and is used for producing a polarizing film excellent in polarization performance throughout the visible light wavelength range, particularly in the vicinity of the wavelength of 460 nm. The invention relates to a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin is composed of only a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and the amount of the 1,2-glycol bond at a side chain is from 0.01 to 6% by mol, or a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin includes a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and a polyvinyl alcohol-based resin (B) other than the polyvinyl alcohol-based resin (A) and satisfies the following expression (1): 0.
Type:
Grant
Filed:
July 27, 2006
Date of Patent:
July 8, 2014
Assignee:
The Nippon Synthetic Chemical Industry Co., Ltd.
Abstract: An ethylene-vinyl alcohol copolymer resin having low odor of acetic acid and good long-run workability is provided. The ethylene-vinyl alcohol copolymer resin which contains an alkali metal salt (A) and has a very low extractable carboxylate content is obtained by a method including contacting the ethylene-vinyl alcohol copolymer resin with an aqueous solution containing carbon dioxide gas.
Abstract: A molding composition is suitable for the production of pipes having improved resistance to thermooxidative degradation when these pipes are in long-term contact with liquids comprising disinfectants having an oxidizing effect. Such molding composition comprises, in addition to thermoplastic polyolefins, a polyoxy compound and/or a polyhydroxy compound as additive in an amount of from 0.01 to 1.0% by weight. In addition, the molding composition can further comprise an unsaturated aliphatic hydrocarbon in an amount of up to 5% by weight. The invention also relates to a process for improving the long-term resistance of water pipes to damage caused by oxidizing disinfectants from the water by use of this molding composition.
Abstract: Provided is a plant-derived resin composite material which has a sufficiently fast crystallization rate and excellent moldability and heat resistance by using a thermoplastic resin composition containing a plant-derived thermoplastic resin and an organic crystal nucleating agent which is composed of one or more low molecular weight compounds comprising at least two polar groups in the molecule, a spacing between any two of the polar groups being 34±4 angstroms.
Abstract: This invention provides a polyfunctional polymer having high stereoregularity, in particular, isotacticity, and provides a production process thereof. The present invention relates to a polymer having, in a molecule, a repeating unit represented by General Formula (2): wherein R1 and R2 are different, and each represents a hydrogen atom, an alkyl group and an aryl group; * represents an asymmetrical carbon, the polymer containing meso diad (m) and racemo diad (r) at a proportion of 60:40 to 100:0 (m:r). The invention also relates to chemical modifications and a production process of the polymer.
Abstract: This invention provides a chaff molding which is excellent in a compressive strength. Said chaff molding comprises a chaff and a polyvinyl alcohol-based resin having a 1,2-diol structure as a side chain.
Type:
Grant
Filed:
April 25, 2008
Date of Patent:
April 8, 2014
Assignee:
The Nippon Synthetic Chemical Industry Co., Ltd.
Abstract: The present invention relates to an aqueous dispersion primer, a coating produced therewith and a method for the production of a vapour barrier or of an intermediate layer. The aqueous dispersion primer based on a polymer for cement and/or other subfloors is characterised in that it contains in an aqueous dispersion the following materials: a) ?23% by weight of silanised styrene-acrylate copolymer and b) ?7.5% by weight of vinylidene chloride-acrylate copolymer and c) ?0.5% by weight of styrene-butadiene copolymer-paraffin wax mixture and d) ?0.5% by weight of additives, the percentage data relating to the mass of the dispersion primer, ready for handling.
Abstract: The present invention is to provide a solar cell sealing film which suppresses occurrence of rust on conducting wires or electrodes and which is improved in transparency and generating efficiency of the solar cell, and a solar cell having the sealing film. The solar cell sealing film comprises ethylene-vinyl acetate copolymer, a crosslinker and an adsorbent, which comprises, as the adsorbent, an inorganic fine particle having refractive index of not more than 1.54 in an amount of 0.1 to 1.5 part by weight based on 100 parts by weight of the ethylene-vinyl acetate copolymer.
Abstract: An object of the present invention is to provide a new acetoacetic ester group-containing polyvinyl alcohol-based resin that contains less amount of water-insoluble matter and is excellent in transparency and viscosity stability when converted into an aqueous solution, and that realizes excellent water resistance by combined use of a crosslinking agent. The invention provides an acetoacetic ester group-containing polyvinyl alcohol-based resin containing a structural unit represented by the general formula (1): wherein at least one of R1 and R2 represents an acetoacetyl group, R3, R4, R5, R6, R7 and R8 each independently represents an arbitrary substituent, and X represents a single bond or an arbitrary bonding chain.
Type:
Grant
Filed:
August 18, 2006
Date of Patent:
March 4, 2014
Assignee:
The Nippon Synthetic Chemical Industry Co., Ltd.
Abstract: The present invention provides a method of producing, in an industrially advantageous manner, an ethylene/vinyl alcohol copolymer aqueous dispersion which has a high concentration and is excellent in long-term storage stability and in which the resin particles in the aqueous dispersion obtained are small in particle diameter.
Abstract: The present invention provides an ink jet recording medium having an ink receiving layer excellent in the coloration resistance and water resistance; and a coating solution for forming an ink receiving layer, which exhibits a large difference in the gelation rate between at ambient temperature and under heating, and is stable at ambient temperature and swiftly gelled when heated. The present invention relates to an ink jet recording medium comprising an ink receiving layer containing an acetoacetic ester group-containing polyvinyl alcohol resin crosslinked by a glyoxylate on a supporting base; and a coating solution for forming an ink receiving layer containing an acetoacetic ester group-containing polymer compound, a glyoxylate and water.
Type:
Grant
Filed:
December 24, 2009
Date of Patent:
February 18, 2014
Assignee:
The Nippon Synthetic Chemical Industry Co., Ltd.
Abstract: A non-aqueous pigment ink comprising a pigment, a pigment dispersant and a non-aqueous solvent, wherein the pigment dispersant is an acrylic polymer comprising, as constituent monomers, (M1) an alkyl(meth)acrylate having an alkyl group of 12 or more carbon atoms, (M2) a (meth)acrylic acid derivative having an amino group, and (M3) a (meth)acrylic acid derivative having a glycidyl group, in which the combination of all the constituent monomers comprises from 7 to 15 mol % of the monomer (M2) and from 0.5 to 3 mol % of the monomer (M3) and the molar ratio (M2)/(M3) between the monomer (M2) and the monomer (M3) is within a range from 4 to 20.
Abstract: Provided are a pressure-sensitive adhesive (PSA) sheet having excellent foam repulsion resistance and an aqueous PSA composition suitable for preparing this sheet. The composition primarily comprises an acrylic polymer obtained by polymerizing a starting monomer material containing an alkyl(meth)acrylate as a main monomer and both acrylic acid and methacrylic acid. The acrylic polymer preferably has a weight average molecular weight of 65×104 to 100×104. The starting monomer material is preferred to further contain a silanol-forming monomer and polymerized without the silanol-forming monomer to produce a polymer having a gel fraction of 7 to 17 mass %. The post-crosslink PSA preferably has a gel fraction of 20 to 55 mass %.
Abstract: The present invention relates to the use of surface-modified nanoparticles to alter the morphology and microstructure of polymer blends. The addition of surface modified nanoparticles to polymer blends comprised of immiscible polymers facilitates the uniform distribution of the dispersed phase of the polymer blend. In an embodiment, the present invention relates to a polymer blend comprising (1) a continuous phase comprising at least one polymer, monomer or oligomer, and a plurality of surface-modified nanoparticles, having a particle diameter of less than about 100 nanometers, distributed in the continuous polymer phase; and (2) a dispersed phase comprising at least one polymer, monomer or oligomer, wherein the continuous polymer phase and the dispersed polymer phase are immiscible.
Type:
Grant
Filed:
December 22, 2005
Date of Patent:
December 31, 2013
Assignee:
3M Innovative Properties Company
Inventors:
Jimmie R. Baran, Jr., Michael A. Johnson, James D. Laperre
Abstract: There is provided a method of producing a polyvinyl alcohol (PVA) film polarizer having an excellent durability, the method comprising dyeing, cross-linking, stretching, and drying, wherein additives containing phosphorus is inputted into one or more of the dyeing, the cross-linking, and the stretching. In this case, the additives containing phosphorus may be selected from a group consisting of a phosphoric acid, potassium phosphate monobasic, potassium phosphate dibasic, magnesium phosphate dibasic, sodium phosphate monobasic, and ammonium phosphate monobasic. An amount of the additives containing phosphorus in an added solution may be 0.01 to 15 wt %. As described above, when inputting the additives containing phosphorus while producing a polarizer, cross-linking between iodine and a polymer matrix becomes strong due to the phosphorus contained in the additives, thereby producing a polarizer having an excellent durability, and particularly, an excellent thermal stability.
Abstract: The present invention is directed toward water based play compositions including a crosslinkable network polymer and a crosslinking system effective to crosslink the polymer. The crosslinking system is a water-soluble salt complex including a primary crosslinking agent, a secondary crosslinking agent, and a tertiary crosslinking agent. The crosslinking system contains a diminished amount of boron compounds while remaining effective in crosslinking network polymers including polyvinyl alcohol (to form moldable dough compositions) and guar gum (to form hydrogels).