Abstract: A novel copolymer having excellent pigment dispersion performance, and more particularly, a novel copolymer usable as a pigment dispersing agent that can attain high luminance and high contrast of a green picture element in a color filter. The novel copolymer contains: a block chain (A) including a repeating unit having a tertiary amino group; and a block chain (B) including a repeating unit represented by the following formula (I) (wherein R1 represents a hydrogen atom or a C1-C3 alkyl group, R2 and R3 each independently represent a hydrogen atom or a C1-C6 alkyl group, Q represents an oxygen-containing saturated hetero ring group optionally having an alkyl group as a substituent or a C2-C20 alkenyl group, and n represents an integer of 0 to 6), and has an amine value of 80 mgKOH/g or more and 250 mgKOH/g or less.
Abstract: The present disclosure relates to a curable system comprising at least two compositions (A) and (B) where composition (A) comprises an epoxy resin, an inorganic thixotropic agent, an organic gelling agent and a filler and composition (B) comprises a hardener, an inorganic thixotropic agent, an organic thixotropic agent and filler. The curable system may be used in the manufacture of components or parts of electrical equipment.
Type:
Grant
Filed:
March 25, 2010
Date of Patent:
January 17, 2017
Assignee:
Huntsman International LLC
Inventors:
Josef Grindling, Christian Beisele, Astrid Beigel, Cliff Beard, Ann Beard
Abstract: An object of the present invention is to provide a methacrylic resin composition which exhibits excellent flexibility, elasticity, impact resistance, and plasticity and moldability while transparency inherent to methacrylic resins is maintained. A methacrylic resin composition to be produced is composed of 10 to 99 parts by mass of a methacrylic resin (A) containing not less than 80 mass % of a methyl methacrylate unit and 90 to 1 part by mass of a block copolymer (B) containing 10 to 60 mass % of a methyl methacrylate polymer block (b1) and 90 to 40 mass % of an acrylate polymer block (b2) and having a refractive index of 1.485 to 1.495 (the total of (A) and (B) is 100 parts by mass).
Abstract: Polymer latex binders useful for preparing coating compositions containing low levels of, or which are substantially free of, volatile organic compounds (VOCs) such as volatile freeze-thaw additives are prepared by multistage emulsion polymerization, wherein one stage provides a copolymer having a relatively high glass transition temperature and containing an oxyalkylene-containing (meth)acrylate comonomer.
Type:
Grant
Filed:
February 5, 2013
Date of Patent:
December 27, 2016
Assignee:
Arkema Inc.
Inventors:
Wenjun Wu, Jihui Guo, Jeffrey A. Schneider
Abstract: Geomembrane liners suitable for use at elevated temperatures up to 100° C., as well as master batch compositions suitable for preparing such geomembrane liners.
Abstract: Provided is a process for the production of a fluorine-containing block copolymer, which suppresses the formation of a homopolymer as a by-product and which, regardless of whether the chain transfer constant of the iodine end is large or small, achieves nearly 100% conversion into a block copolymer. The process is characterized by reacting (A) a fluorine-containing polymer which has an iodine atom or a bromine atom at either or both terminals of the backbone chain and/or at a side-chain terminal with (M) a radical-polymerizable monomer in the presence of (C) a sulfur compound represented by general formula (2): (Y1)nH2-nS2O4 (wherein Y1 is a mono- or divalent metal ion or an ammonium ion; and n is an integer of 0 to 2).
Abstract: To provide a chloroprene rubber composition providing good permanent compression set and excellent mechanical strength, a vulcanizate of the composition, and a molded article of the composition. A chloroprene rubber composition including a chloroprene rubber and a natural rubber in a total amount of 100 parts by mass, a copolymer of styrene and butadiene in an amount of 0.1 to 10 parts by mass, ethylene thiourea in an amount of 0.1 to 3.0 parts by mass, and dipentamethylenethiuram tetrasulfide in an amount of 0.1 to 3.0 parts by mass is vulcanized after or during molding of the composition to yield a vulcanized molding.
Abstract: The present invention relates to self-coalescing latexes that incorporate film fat ing polymers that are low molecular weight polymers that are compatible with the latex and act as thin plasticizers penetrating through the remainder of the latex particle and aiding in the coalescence of the remaining polymers. In a preferred embodiment, the self-coalescing latex is a sequentially polymerized polymer having at least a core, a shell and a skin. The film forming polymers are formed of monomers substantially the same as the monomers of the shell but having average weighted molecular weights substantially less than the polymers of the shell. The present invention also relates to the method of polymerizing the self-coalescing latex of the current invention, which largely results from the addition of a substantial amount of chain transfer agent to a remaining portion, about 15% or less, of the monomer pre-emulsion prior to polymerization.
Type:
Grant
Filed:
May 15, 2012
Date of Patent:
November 29, 2016
Assignee:
Columbia Insurance Company
Inventors:
Hrire Gharapetian, Navin Tilara, Robert Sheerin
Abstract: An acrylic rubber graft copolymer is obtained by graft polymerizing a vinyl monomer in the presence of a rubbery polymer including acrylate ester monomer units and polyfunctional monomer units, wherein the total amount of the polyfunctional monomer units in the rubbery polymer is 0.3 to 3 parts by mass with respect to 100 parts by mass of the acrylate ester monomer units, and the polyfunctional monomer units include 30 to 95 mass % of polyfunctional monomer units having two unsaturated bonds and 5 to 70 mass % of polyfunctional monomer units having three unsaturated bonds with respect to 100 mass % of the total of the polyfunctional monomer units. A thermoplastic resin composition includes the acrylic rubber graft copolymer.
Abstract: A process for preparing a copolymer including one or more phosphorus-containing mer units, the process comprising anionically polymerizing conjugated diene monomer, vinyl organophosphine monomer, and optionally monomer copolymerizable therewith.
Type:
Grant
Filed:
March 12, 2014
Date of Patent:
November 22, 2016
Assignee:
Bridgestone Corporation
Inventors:
Terrence E. Hogan, William L. Hergenrother
Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH?CH—R? (I) or —X—C?C—R? (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH?CH—R? or with the acetylenic unsaturation of —X—C?C—R? and R? represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH?CH— or —C?C— bond.
Type:
Grant
Filed:
December 22, 2010
Date of Patent:
November 15, 2016
Assignee:
Dow Corning Corporation
Inventors:
Michael Backer, Francois De Buyl, Damien Deheunynck, Valerie Smits
Abstract: The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.
Type:
Grant
Filed:
October 26, 2011
Date of Patent:
November 15, 2016
Assignee:
Rohm and Haas Company
Inventors:
Yannick Saint-Gerard, Veera Nelliappan, Yannick Chiquet, Eric G. Lundquist
Abstract: A method of preparing tunable inorganic patterned nanofeatures by infiltration of a block copolymer scaffold having a plurality of self-assembled periodic polymer microdomains. The method may be used sequential infiltration synthesis (SIS), related to atomic layer deposition (ALD). The method includes selecting a metal precursor that is configured to selectively react with the copolymer unit defining the microdomain but is substantially non-reactive with another polymer unit of the copolymer. A tunable inorganic features is selectively formed on the microdomain to form a hybrid organic/inorganic composite material of the metal precursor and a co-reactant. The organic component may be optionally removed to obtain an inorganic features with patterned nanostructures defined by the configuration of the microdomain.
Type:
Grant
Filed:
August 12, 2011
Date of Patent:
November 8, 2016
Assignee:
UChicago Argonne, LLC
Inventors:
Seth B. Darling, Jeffrey Elam, Yu-Chih Tseng, Qing Peng
Abstract: Disclosed are a water-dispersible halogen-capping polyalkylacrylate, a vinyl chloride-based block copolymer and a method for preparing the same. By using the water-dispersible halogen-capping polyalkylacrylate derivative as a chain transfer agent for polymerization of a vinyl chloride-based monomer, it is possible to obtain effects such as reduction of coagulation of particles and adhesion of particles to a reactor wall, improvement in reaction efficiency and polydispersity index, and prevention of yellowing.
Type:
Grant
Filed:
June 3, 2013
Date of Patent:
October 25, 2016
Assignee:
LG Chem, Ltd.
Inventors:
Kyoung Shil Oh, Bo Hee Park, Kyung Hyun Kim
Abstract: The present invention relates to a composition comprising a stable aqueous dispersion of large acrylic based polymer particles and small acrylic based polymer particles wherein the large polymer particles comprise structural units of a phosphorus acid monomer or a salt thereof; and wherein the small polymer particles comprise a substantial absence of structural units of any phosphorus acid monomer and salts thereof. The bimodal dispersion of the present invention provides a way of making a high solids adsorbing latex with high hiding efficiency.
Type:
Grant
Filed:
July 2, 2014
Date of Patent:
October 18, 2016
Assignees:
Rohn and Haas Company, Dow Global Technologies LLC
Inventors:
James C. Bohling, Beth Cooper, Melinda H. Keefe, Margo Schaefer
Abstract: The invention provides lactamic polymers comprising an acetoacetate moiety. The lactamic polymers may be readily functionalized and the functionalized lactamic polymers may be further derivatized to provide a wide variety of useful polymers having desirable chemical and physical properties. The lactamic polymers of the invention may be employed in a wide variety of compositions. (A); (B) wherein R1-R6, w, x, y, z, and n are described herein.
Type:
Grant
Filed:
February 23, 2012
Date of Patent:
October 11, 2016
Assignee:
ISP Investments LLC
Inventors:
David K. Hood, Karyn B. Visscher, Surya Kamln, Sounak Sarkar
Abstract: A bonding base for electronic components, and a method. The bonding base comprises: a dielectric basic layer formed of a mixture comprising thermoplastic polymer, the polymer part of which mixture comprises 75 to 95% by weight of thermoplastic PPO, the polymer part further comprising 5 to 20% by weight of elastomer which is incompatible with PPO.
Abstract: The invention relates to the use of 1,5-enediyne compounds of formula (I) as curing agents in polymeric systems. In particular the invention relates to a curable composition comprising a curing agent of formula (I) and a polymer suitable to be cross-linked and to the cured article obtained therefrom.
Type:
Grant
Filed:
December 16, 2010
Date of Patent:
October 4, 2016
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Enzo Giannetti, Aldo Sanguineti, Ivan Wlassics, Giuseppe Marchionni
Abstract: Disclosed is a method for producing a plastisol acrylic polymer which can have a satisfactory adhesion property even when the heating time is short and the heating temperature is low, and which has excellent storage stability. The method comprises (1) a step of polymerizing an acrylic monomer mixture (a) to produce a polymer (A) and (2) a step of polymerizing an acrylic monomer mixture (b) in a dispersion containing the polymer (A), wherein a monomer having a hydroxy group is contained in the acrylic monomer mixture (a), a monomer having an acetoacetyl group or a block isocyanate group is contained in the acrylic monomer mixture (b), and the dissolution parameter (SA) for the polymer (A) and the dissolution parameter (SB) for a polymer (B) produced by the polymerization of the acrylic monomer mixture (b) are different from each other.
Abstract: A cover tape having at least a base material layer, and an adhesive layer that is heat sealed by a resin carrier tape, the cover tape wherein the base material layer has an antistatic layer on a surface thereof that is on the reverse side to the adhesive layer; the antistatic layer contains at least an inorganic antistatic agent and a wax having a particle diameter of 0.2-3.0 ?m; the inorganic antistatic agent is 40%-80% by mass and the wax content is 10%-50% by mass, relative to the total components forming the antistatic layer; and the surface resistivity of the base material layer side is no more than 1013?/? in a 23° C.×30% RH atmosphere.