Abstract: A reductive system including a silane, preferably PMHS, and an active zinc compound, which is monomeric and not a hydride, wherein a reduction of a carbonyl substrate to a corresponding alcohol is achievable.
Abstract: This invention is directed to cationic polymerization of olefins using catalysts comprising a Group 6 or 10 neutral transition metal cation composition having a cyclopropenyl ring, a pi-bonded cyclopentadienyl ligand or cyclopentadienyl group-containing ligand and an amido or imido ligand. The precursor of the neutral transition metal composition is activated to a catalytic state by exposure to an activator composition that may be any of the heretofore known activator compositions such as an alumoxane or a compatible non-coordinating anion (NCA).
Abstract: A process to prepare an improved fluid rare earth phosphate catalyst composition useful in preparing alkylene oxide adducts of organic compounds having active hydrogen atoms is provided. The catalyst is prepared by dissolving a rare earth salt in a C9-C30 active hydrogen containing organic compound and then adding phosphoric acid to the organic compound rare earth mixture.
Abstract: Disclosed is a colorant composition of the formula
wherein R is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R can be joined to the phenyl moiety to form a ring, R′ is an aromatic- or heteroaromatic-containing group, each Ra, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, w is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, and x is an integer representing the number of repeat alkylene oxide units, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule.
Type:
Grant
Filed:
April 24, 2003
Date of Patent:
July 20, 2004
Assignee:
Xerox Corporation
Inventors:
Jeffery H. Banning, Donald R. Titterington, Clifford R. King
Abstract: An ink composition comprising water, a dye and at least one compound capable of including a dye therein, wherein the dye is dissolved or dispersed in an aqueous medium comprising the water.
Abstract: The present invention relates to a catalyst for polymerization and co-polymerization of ethylene. More particularly, the present invention relates to a solid titanium catalyst containing magnesium, wherein said catalyst is produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with alcohol; reacting said solution with an ester compound having at least one hydroxy group, or a phosphorous compound and a silicon compound having alkoxy groups; producing a solid component with an adjusted particle morphology by adding a mixture of a titanium compound and a silicon compound; reacting the same with an aluminum compound; and then reacting the same with a titanium compound, or a titanium compound and a vanadium compound. As a result, the catalyst of the present invention has high catalytic activity with excellent catalyst morphology.
Type:
Grant
Filed:
December 1, 2000
Date of Patent:
July 13, 2004
Assignee:
Samsung General Chemicals Co., Ltd.
Inventors:
Chun-Byung Yang, Weon Lee, Sang-Yull Kim
Abstract: A novel intercalation compound is provided, in which compound monohydric alcohol is intercalated between layers of a layered compound comprising vanadium, phosphorus and oxygen as primary components, characterized in that the monohydric alcohol is aliphatic secondary monohydric alcohol, alicyclic monohydric alcohol, or aromatic monohydric alcohol. By heating the intercalation compound, a vanadium-phosphorus mixed oxide having a BET specific surface area of at least 80 m2/g can be obtained.
Abstract: An ink for ink-recording is provided, which makes it possible to reduce color bleed while suppressing even when recording is performed on regular paper. The ink for ink-jet recording contains water, a coloring agent, a water-soluble organic solvent, and a compound represented by the following general formula (1):
wherein R represents a alkyl group having a number of carbons of 8 to 18, and x+y is not more than 10. A surface tension of the ink is controlled to 31 to 35 mN/m, which can reduce color bleed and feathering.
Abstract: A water-in-oil (W/O) emulsion ink for stencil printing is provided which is prevented from pigment aggregation and thus excellent in ink fixability, high in printing density and less declining in printing density even after printing many sheets. The emulsion ink has a ratio by volume of the water phase to liquid components of the oil phase (i.e., volume of water phase/volume of the liquid components of oil phase) in a range of 1.0 to 3.5, preferably 1.0 to 3.0 at 23° C. The liquid components of the oil phase may be composed of a resin, a solvent and a surfactant. The oil phase can contain a pigment at a ratio by volume of 0.19 or less to the total volume of the oil phase. The pigment preferably has an average particle size of 0.02 to 1.5 (&mgr;m). The water phase preferably has an average particle size of 0.1 to 1.0 (&mgr;m). The ink is suitable for containing particles of organic pigments with non-uniform shapes and a large average particle size like copper phthalocyanine blue and diaxazine violet.
Abstract: A process for making a solid composition comprising alkoxide groups, chloride groups, one or more metals, M, in the +2 oxidation state selected from Mg, Ca, Mn, Cu, Co or Zn, and one or more metals, T, in the +3, +4 or +5 oxidation state selected from Ti, Zr, V, Sm, Fe, Ni, Rh, Co, Cr, Mo, W or Hf, the molar ratio M/T of the composition being from 2.5 to 3.75, said process comprising contacting one or more alkoxide containing compounds of metal M, one or more alkoxide compounds of metal T, and a halide compound, the molar ratio M/T of the contacting compounds being from 2.5 to 3.5, and recovering the resulting solid.
Type:
Grant
Filed:
May 8, 2002
Date of Patent:
July 6, 2004
Assignee:
Union Carbide Chemicals & Plastics Technology
Corporation
Abstract: Single-site catalyst systems useful for polymerizing olefins are disclosed. The catalyst systems comprise an organometallic complex and an activator. The complex includes a Group 3-10 transition metal, M, and at least one indenoindolyl ligand that is pi-bonded to M. The activator is a reaction product of
an alkylaluminum compound and an organoboronic acid. Catalyst systems of the invention significantly outperform known catalyst systems that employ a metallocene complex and similar aluminoboronate activators.
Type:
Grant
Filed:
June 4, 2001
Date of Patent:
July 6, 2004
Assignee:
Equistar Chemicals, LP
Inventors:
Michael W. Lynch, Craig C. Meverden, Sandor Nagy, Karen L. Neal-Hawkins
Abstract: A carbon-containing material with organic groups, which is obtainable by reaction of the carbon-containing material with organic compounds of the general formula 1
A process for preparing the carbon-containing material according to the invention is also described. The carbon-containing materials according to the invention can be used as fillers, reinforcing fillers, UV stabilizers, conductivity carbon blacks or pigments.
Type:
Grant
Filed:
October 1, 2002
Date of Patent:
July 6, 2004
Assignee:
Degussa AG
Inventors:
Klaus Bergemann, Egon Fanghaenel, Bernd Knackfuss, Thomas Luethge
Abstract: An electrophoresis device is disclosed which separates cells, particles, proteins and other separands by collecting samples of decreasing electrophoretic mobility in a train of inverted cavities while an electric field is applied between said inverted cavities and one or more sample cuvettes containing a mixture of cells, particles, proteins or other separands. One circular plate is provided for the one or more sample cuvettes, and one circular plate is provided for the multiple collection cavities. The invention utilizes an innovative purification method that combines free electrophoresis and multistage extraction in an instrument capable of separating living cells, particles, and proteins in useful quantities at high concentrations. The purification method includes a method for dealing with electrolysis products, a technique for controlling the electrical energy input, and an approach for keeping the process isothermal.
Type:
Grant
Filed:
April 29, 2002
Date of Patent:
July 6, 2004
Inventors:
Nathan A. Thomas, John C. Vellinger, Paul W. Todd, Shramik Sengupta
Abstract: A crystalline mixture solid composition comprising &agr;-D-glucopyranosyl-1,1-mannitol (GPM), &agr;-D-glucopyranosyl-1,6-sorbitol (GPS-6) and a small amount of &agr;-D-glucopyranosyl-1,1-sorbitol (GPS-1) and a production process therefor. The above crystalline mixture solid composition is produced by mixing a hydrophilic solvent with a solid composition or aqueous solution comprising 50 to 80 wt % of GPM, 1 to 50 wt % of GPS-6 and 0.01 to 20 wt % of GPS-1, separating solid matter from a liquid, and removing water and the solvent from the solid matter and can be obtained as a thin scale crystal.
Abstract: A method for the preparation of starch particles in a two-phase system comprises at least the following steps: a) a preparation of a first phase comprising a dispersion of starch in water; b) preparation of a dispersion or emulsion of the first phase in a second liquid phase, with the proviso that the second phase is not water; c) cross-linking of the starch present in the first phase; d) separating the starch particles thus formed. According to a first aspect of the invention the second phase consists of a hydrophobic liquid and step b) consists in forming an oil-in-water emulsion, which is then inverted to a water-in-oil emulsion. According to a second aspect of the invention, the second phase consists of a water-miscible non-solvent for starch. Starch particles of very small particles size can be produced in a controlled manner by means of this method.
Abstract: This invention provides a process for hydrotreating hydrocarbon resins, which process comprises contacting a feedstock comprising a hydrocarbon resin or rosin, under suitable hydrotreating conditions, with a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals and wherein the ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10. The process according to the invention can achieve increased hydrocarbon resin productivity through increase in throughput volumes and effective catalyst lifetimes. The process of the invention is desirably practiced with a bulk catalyst consisting of only the combination of the metal species with the active metal components. The absence of carrier substrates largely removes the possibility of halogen accumulation on substrate surfaces that, in turn, can acidify metal catalysts such that additional, progressive cracking of the hydrocarbon resin molecules occurs.
Abstract: A silica-based photocatalyst fiber having visible-light activity, which fiber comprises a composite oxide phase comprising an oxide phase (first phase) mainly made of a silica component and a titania phase (second phase), wherein the second phase contains a metal element other than titanium and the existent ratio of the second phase slopingly increases towards the surface of the fiber, and a process for the production thereof.
Abstract: Organolead compounds such as tetraethyllead are useful in catalyst compositions for the oxidative carbonylation of hydroxyaromatic compounds to diaryl carbonates. They are employed in combination with a Group 8, 9, or 10 metal such as palladium, or a compound thereof, and a bromide or chloride such as tetraethylammonium bromide.
Type:
Grant
Filed:
June 6, 2002
Date of Patent:
June 22, 2004
Assignee:
General Electric Company
Inventors:
Kirill Vladimirovich Shalyaev, Bruce Fletcher Johnson
Abstract: The present invention relates to catalyst compositions for purifying terephthalic acid from p-carboxybenzaldehyde, based on Group VIII metals, comprising crystallites of catalytically active palladium or of palladium and at least one metal of Group VIII of the Periodic Table of Elements, applied to the surface of a carbon material, wherein a mesoporous graphite-like material with the average mesopore size in the range of from 40 to 400 Å, the proportion of the mesopores in the total pore volume of at least 0.5, and the degree of graphite-similarity of at least 20% is used as the carbon material, in which metal crystallites are distributed in the volume of the carbon material granules in such a manner that the distribution peaks of these crystallites should be at a distance from the outer surface of the granule corresponding to 1-30% of its radius.
Type:
Grant
Filed:
May 6, 2002
Date of Patent:
June 22, 2004
Assignees:
Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdelenia
Rossiiskoi Akademii Nauk, Samsung General Chemicals Co., Ltd.
Inventors:
Anatoly Vladimirovich Romanenko, Vladimir Alexandrovich Likholobov, Maria Nikolaevna Timofeeva, Jhung Sung Hva, Park Jun Seok