Patents Examined by Mark L. Bell
  • Patent number: 6875721
    Abstract: The invention relates to a complex comprising a magnesium dihalide and an electron donor. It is a complex of the magnesium dihalide and the electron donor and has the formula (I): MgX2·[R(OR?)n]m??(I) wherein MgX2 is the magnesium dihalide and R(OR?)n is the electron donor, X is a halogen, R is an n-valent C1-C20aliphatic group, an n-valent C7-C27 araliphatic group or an n-valent C2-C22 acylic group, R? is a C1-C20 alkyl group or a C7-C27 aralkyl group, n is a number from 1 to 6 and m is defined as a number 0.5?m?2.0. The invention also relates to the preparation process of such a complex, as well as the use thereof for the preparation of olefin polymerization catalyst components.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: April 5, 2005
    Assignee: Borealis Technology Oy
    Inventors: Thomas Garoff, Timo Leinonen, Sirpa Ala-Huikku
  • Patent number: 6872684
    Abstract: Catalysts for oxychlorination of ethylene to 1,2-dichloroethane, comprising compounds of copper and magnesium supported on alumina, in which the copper, expressed as metal, is present in an amount of 7 to 12% by weight and the Mg/Cu ratio is 0.05 to 1, and wherein the ratio between the concentration of copper provided by the Al/Cu ratio at the surface and that provided by the Al/Cu ratio in the entire particle of the catalyst is from 0.8 to 1.3.
    Type: Grant
    Filed: March 3, 2004
    Date of Patent: March 29, 2005
    Assignee: Sud Chemie MT S.R.I.
    Inventors: Francesco Casagrande, Carlo Orsenigo
  • Patent number: 6872682
    Abstract: A catalyst system for the polymerization of ?-olefins prepared by a process which includes catalyst activation whereby a solid transitional metal compound is contacted with an organoaluminum compound and catalyst prepolymerization whereby a premonomer is prepolymerized in the presence of the activated catalyst. High activity, low fines polymerization can be achieved if in the first step of catalyst activation a first reaction mixture is prepared by contacting the solid transitional metal compound with a first organoaluminum compound in the presence of an oil and in the second step, the first reaction mixture is contacted with a second organoaluminum compound to give a second reaction mixture, the second organoaluminum compound being the same as or different from the first organoaluminum compound.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: March 29, 2005
    Assignee: Borealis Technology Oy
    Inventors: Kauno Alastalo, Pauli Leskinen
  • Patent number: 6872243
    Abstract: Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state upon
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: March 29, 2005
    Assignee: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Donald R. Titterington, Jule W. Thomas, Jr., Jeffrey H. Banning, Christine E. Bedford, James D. Wuest
  • Patent number: 6869470
    Abstract: The invention relates to an ink set for ink jet recording comprising at least one “self-dispersion type pigment ink containing water and a pigment dispersible in water without a dispersing agent” and at least one “light-color resin-containing pigment ink containing water and a pigment made dispersible in water with a resin, wherein the concentration of the pigment is one-half or less the concentration of the pigment contained in the self-dispersion type pigment ink”. Also disclosed is an ink jet recording process for conducting ink jet recording using the ink set described above.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: March 22, 2005
    Assignee: Seiko Epson Corporation
    Inventor: Shinichi Kato
  • Patent number: 6867159
    Abstract: A disclosed method for coating a substrate with an ionomer, applies the ionomer as a component of a stable foam, then dries the applied foam layer. The substrate to be so coated, in particular embodiments, is an electrode substrate, with or without a catalyst layer applied thereon. In another embodiment, the substrate is an ion-exchange membrane. In yet more particular embodiments, the substrate is suitable for use in an electrochemical fuel cell. Also disclosed are products made by the disclosed methods, namely, ionomer-coated substrates, including ionomer-coated electrode substrates and electrodes. The foam layer may also comprise catalyst powder to form a catalyst layer. Membrane electrode assemblies, fuel cells, and fuel cell stacks that incorporate the substrates are also disclosed, as are motor vehicles, and stationary and portable electrical power-generating plants that incorporate the fuel cell stacks.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: March 15, 2005
    Assignee: Ballard Power Systems Inc.
    Inventors: Guy Ebbrell, John Gaffney
  • Patent number: 6866711
    Abstract: A composite pigment is provided with the composite pigment including a dense inorganic material and silica. The pigment composition is characterized by a CTAB surface area of greater than about 20 m2/g; a BET surface area of greater than about 15 m2/g; and a density of greater than about 2.5 g/cm3.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: March 15, 2005
    Inventors: Fitzgerald Alphanso Sinclair, Mark Edward Wozniak, Louis Frank Gatti, William C. Fultz
  • Patent number: 6866707
    Abstract: The invention relates to an ink set for ink jet recording comprising at least one “resin-containing pigment ink containing water and a pigment made dispersible in water with a resin” and at least one “self-dispersion type pigment ink containing water and a pigment dispersible in water without a dispersing agent”, wherein the ink set is constituted so that the at least one resin-containing pigment ink and the at least one self-dispersion type pigment ink correspond to each other in terms of hue. Also disclosed is an ink jet recording process for conducting ink jet recording using the ink set described above, wherein the resin-containing pigment ink contained in the ink set is used for paper exclusive to ink jet recording, and the self-dispersion type pigment ink contained in the ink set is used for plain paper.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: March 15, 2005
    Assignee: Seiko Epson Corporation
    Inventor: Shinichi Kato
  • Patent number: 6863737
    Abstract: A crystalline mixture solid containing maltitol having an oil absorptivity of 0.1 to 6.9 wt % and a bulk density of 0.60 to 0.75 g/cc when it is ground and classified to ensure that at least 70 wt % of the obtained particles should have a particle size of 16 to 50 mesh and a process for producing a crystalline mixture solid containing maltitol, comprising introducing air bubbles into a maltitol aqueous solution. According to this process, a crystalline mixture solid containing maltitol having high solubility and almost no moisture absorption is produced at a high work efficiency and a low cost in a short period of time.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: March 8, 2005
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyusho
    Inventors: Ryuzo Ueno, Akihiko Tabata, Junya Honda, Yojiro Furukawa
  • Patent number: 6864334
    Abstract: The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: March 8, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Lisa Saunders Baugh, Abhimanyu Onkar Patil, Donald Norman Schulz, Robert Timothy Stibrany, Joseph Anthony Sissano, Stephen Zushma
  • Patent number: 6864207
    Abstract: A process for making a polyolefin catalyst component, catalyst and polymer resin is disclosed. Controlling the viscosity of a catalyst synthesis solution with the addition of aluminum alkyl alters the precipitation of the catalyst component from a catalyst synthesis solution. The average particle size of the catalyst component increases with an increased concentration of aluminum alkyl in the synthesis solution. The catalyst component can be produced by a process comprising contacting a magnesium alkyl compound with an alcohol and an aluminum alkyl to form a magnesium dialkoxide. Catalyst components, catalysts, catalyst systems, polyolefin, products made therewith, and methods of forming each are disclosed. The reaction products can be washed with a hydrocarbon solvent to reduce titanium species [Ti] content to less than about 100 mmol/L.
    Type: Grant
    Filed: September 22, 2003
    Date of Patent: March 8, 2005
    Assignee: Fina Technology, Inc.
    Inventors: David W. Knoeppel, Tim J. Coffy, Henry Enriquez, Steven D. Gray
  • Patent number: 6864208
    Abstract: A catalyst solid for olefin polymerization comprising A) at least one magnesium halide, B) at least one metallocene complex and C) at least one compound capable of forming metallocenium ions, is prepared by i) firstly preparing finely divided support particles consisting of the magnesium halide A) and an C1-C8-alcohol having a mean particle diameter of from 1 to 200 ?m from an adduct of the magnesium halide A) and a C1-C8-alcohol, where the adduct contains from 1.5 to 5 mol of the C1-C8-alcohol per mole of magnesium halide, ii) then depositing the compound C) capable of forming metallocenium ions on the finely divided support particles and iii) subsequently bringing the reaction product hereby obtained into contact with the metallocene complex B). This catalyst solid can be used for the polymerization or copolymerization of olefins.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: March 8, 2005
    Assignee: Basell Polyolefine GmbH
    Inventors: Carsten Süling, Wolf Spaether, Nicola Paczkowski, Joachim Rösch, Joachim Wulff-Döring, Wolfgang Bidell
  • Patent number: 6864209
    Abstract: A catalytic composition for oligomerizing olefins, in particular ethylene, comprises mixing at least one nickel complex, prepared by reacting a nickel salt with a phosphonite ligapd, with at least one hydrocarbylaluminum compound in a molar proportion with respect to the nickel of not more than 8? and selected from the group formed by tris(hydrocarbyl)aluminum compounds, chlorinated or brominated hydrocarbylaluminum compounds and aluminoxanes.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: March 8, 2005
    Assignee: Institut Francais du Petrole
    Inventors: Fredy Speiser, Pierre Braunstein, Lucien Saussine
  • Patent number: 6863720
    Abstract: The problem is to provide a thermosensitive color-changing dry offset ink, having no problem in an ink transferability and an excellent printing characteristics. As a thermosensitive color-changing dry offset ink is used one composed of thermosensitive, color-changing microcapsules mixed in a vehicle the capsule having two particle size characteristics of (1) particle size distribution: particles of less than 0.5 ?m are contained in not less than 10 volume % and those not larger than 3.0 ?m are contained in not less than 90 volume % and (2) mean particle diameter: 0.2-1.5 ?m.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: March 8, 2005
    Assignee: Matsui Shikiso Chemical Co., Ltd.
    Inventors: Yosuke Kitagawa, Shozo Suefuku, Masaki Kariya
  • Patent number: 6864212
    Abstract: Bismuth- and phosphorus-containing naphtha reforming catalysts, methods of making such catalysts, and a naphtha reforming process using such catalysts.
    Type: Grant
    Filed: August 8, 2002
    Date of Patent: March 8, 2005
    Assignee: Shell Oil Company
    Inventor: Peter Tanev
  • Patent number: 6864210
    Abstract: A catalyst system useful for polymerizing olefins is disclosed. The catalyst system comprises an activator and a bimetallic complex that incorporates two Group 3 to 10 transition metal atoms, which may be the same or different, and a neutral or anionic indigoid ligand. By proper selection of the indigoid skeleton and by modifying its substituents and transition metal centers, polyolefin makers can fine-tune the bimetallic complexes to control activity, enhance comonomer incorporation, and optimize polymer properties.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: March 8, 2005
    Assignee: Equistar Chemicals, LP
    Inventors: Gregory G. Hlatky, Jonathan L. Schuchardt
  • Patent number: 6863721
    Abstract: A color decorating spray composition comprises a color lake dispersion, an oil, a humectant, an alcohol, a color carrier and drying agent, a color suspending agent, an antifoaming agent, an emulsifier and a propellant. An apparatus for dispensing the composition includes a lined aerosol container filled with the composition, and an aerosol valve assembly including a mounting cup crimped to a formed collar on the container. The valve assembly further includes a valve body fixed in a central aperture of the mounting cup, a valve stem concentrically located in the valve body and loaded against a vapor orifice thereof by a coil spring, and an actuator fitted to the top of the stem. The valve stem has a powder-capable orifice provided with a bead which causes powder to be blown away when the actuator is depressed and composition is expelled through a space between the stem and the valve body.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: March 8, 2005
    Assignee: Signature Brands LLC
    Inventors: Jack C. Grosskopf, Mary C. Thomson
  • Patent number: 6864205
    Abstract: A family of novel hetrocyclic-amide type catalyst precursors useful for the polymerization of olefins, such as ethylene, higher alpha-olefins, dienes, and mixtures thereof.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: March 8, 2005
    Assignee: Univation Technologies, LLC
    Inventor: Rex Eugene Murray
  • Patent number: 6860930
    Abstract: Disclosed is a phase change ink composition comprising (a) a colorant and (b) a carrier comprising a polyamide, wherein the polyamide component of the carrier contains at least about 10 percent by weight of a branched triamide.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: March 1, 2005
    Assignee: Xerox Corporation
    Inventors: Bo Wu, Jeffery H. Banning, Donald R. Titterington, C. Wayne Jaeger
  • Patent number: 6861386
    Abstract: A polymerizable composition including a resin system comprising oligomers or polymers functionalized with groups curable by ring opening metathesis polymerization, a metathesis catalyst, and a catalyst accelerator. In examples of the present invention, the composition includes a ruthenium carbene complex catalyst capable of initiating ring-opening metathesis polymerization of the composition and a silicone-based sulfosuccinate salt capable of accelerating the polymerization initiated by the catalyst. In another example, the invention includes a paste/paste system in which a base paste includes the polymerizable oligomer or polymer and the catalyst accelerator and in which a catalyst paste includes the catalyst dissolved in an inert solvent.
    Type: Grant
    Filed: December 6, 2002
    Date of Patent: March 1, 2005
    Assignee: Kerr Corporation
    Inventors: Christos Angeletakis, Mingfei Chen