Patents Examined by Mark S Kaucher
  • Patent number: 11618817
    Abstract: It becomes possible to produce a thermoplastic resin composition having a sea-island structure by a kneading step of kneading a thermoplastic elastomer and/or rubber material having an alkoxysilyl group, in which the alkoxysilyl group is grafted to the thermoplastic elastomer and/or rubber material, and a thermoplastic resin in a melt state in a kneading machine and a dynamic crosslinking step of adding a water component into the kneading machine, forming a silanol group by a hydrolysis reaction of the alkoxysilyl group in the thermoplastic elastomer and/or rubber material having an alkoxysilyl group and the water component in the kneading machine, and subsequently forming a siloxane bond by a condensation reaction between the silanol groups.
    Type: Grant
    Filed: October 6, 2021
    Date of Patent: April 4, 2023
    Assignee: INOAC CORPORATION
    Inventors: Yoshihisa Takamori, Kentaro Iwanaga
  • Patent number: 11613635
    Abstract: The purpose of the present invention is to provide a resin composition for manufacturing a medical storage container that has improved oxygen permeability and that tends not to have excessively lower transparency. To this end, the present invention pertains to a resin composition for manufacturing a medical storage container, the composition including polyethylene (a) and polymethylpentene (b). The resin composition contains, as polyethylene (a), a first polyethylene (a-1), which is a main component of the polyethylene (a), and a second polyethylene (a-2) having a lower density than the first polyethylene.
    Type: Grant
    Filed: September 18, 2018
    Date of Patent: March 28, 2023
    Assignee: SB-KAWASUMI LABORATORIES, INC.
    Inventor: Noriaki Shirahama
  • Patent number: 11608597
    Abstract: The present invention relates to a complex of polymers and to the use thereof in a method of making paper, cardboard or the like. This complex of polymers is obtained by polymerizing water-soluble monomers: in the presence of a host polymer that comprises vinylamine functions and of a non-polymeric transfer agent, and in the absence of a branching or crosslinking agent of the ethylenic polyfunctional type. It is obtained as from a mass ratio of anionic monomer to water that is greater than 0.035.
    Type: Grant
    Filed: May 7, 2019
    Date of Patent: March 21, 2023
    Assignee: SPCM SA
    Inventors: Gatien Faucher, Damien Fougerouse, René Hund
  • Patent number: 11608402
    Abstract: A graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester onto a copolymer (A), the copolymer (A) being a copolymer of an alkyl (meth)acrylate ester (Aa) and a (meth)acrylate ester (Ab) including an aromatic hydrocarbon group. A thermoplastic resin composition including the graft copolymer (B), a copolymer (C) that is the product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester, and a molded article produced by molding the thermoplastic resin composition. Provided are the graft copolymer with which a thermoplastic resin composition excellent in terms of transparency, impact resistance, weather resistance, and flowability may be produced, a thermoplastic resin composition including the graft copolymer, and the molded article produced by molding the thermoplastic resin composition.
    Type: Grant
    Filed: October 11, 2019
    Date of Patent: March 21, 2023
    Assignee: TECHNO-UMG CO., LTD.
    Inventors: Kousaku Tao, Yoshitaka Naitoh, Yuuki Taguchi
  • Patent number: 11603465
    Abstract: A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan ? at 0° C. or greater.
    Type: Grant
    Filed: September 30, 2022
    Date of Patent: March 14, 2023
    Assignee: TECHNO-UMG CO., LTD.
    Inventors: Shinji Fujii, Naruki Tanaka
  • Patent number: 11603421
    Abstract: The present invention relates to a method for preparing a thermoplastic copolymer using monomer droplets, a thermoplastic copolymer prepared therefrom and a thermoplastic resin composition including the same. In the preparation method, monomer droplets including an aromatic vinyl-based monomer are injected after reaching a polymerization conversion ratio of 10% to participate in the reaction after initiating polymerization, and a thermoplastic copolymer having an increased average particle diameter may be prepared in high yield.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: March 14, 2023
    Assignee: LG CHEM, LTD.
    Inventors: Min Cheol Ju, Min Seung Shin, Sung Won Hong, In Soo Kim, Hyung Sub Lee
  • Patent number: 11597827
    Abstract: To provide a resin composition, a pellet, a composite molded article, a method for manufacturing a composite molded article and a tank, all capable of enabling tight joining and integration of the polyacetal resin molded article and the polyethylene resin molded article, and of suppressing formaldehyde emission and occurrence of mold deposit. The resin composition contains a resin ingredient and melamine, the resin ingredient containing a polyacetal resin and a maleic anhydride-modified polyethylene resin, the polyacetal resin and the maleic anhydride-modified polyethylene resin following a mass proportion of (20 to 49):(80 to 51), and molar concentration of the maleic anhydride group capable of reacting with amino group of melamine contained in the resin composition being 5 to 25 ?mol/g.
    Type: Grant
    Filed: August 28, 2019
    Date of Patent: March 7, 2023
    Assignees: MITSUBISHI ENGINEERING-PLASTICS CORPORATION, JAPAN POLYETHYLENE CORPORATION
    Inventors: Kunihiko Fujimoto, Kei Takahashi, Ritsuya Matsumoto
  • Patent number: 11578163
    Abstract: The invention relates to a block copolymer comprising at least one rigid polyamide block and at least one flexible block, characterized in that the flexible block has an NH2/OH ratio of concentrations of amine chain ends to alcohol chain ends which is within the range from 30 to 150, said concentrations being measured by 1H NMR (TFanh./CD2Cl23). The invention also relates to the use of a flexible block for manufacturing a copolymer containing polyamide blocks and flexible blocks that is both hydrolysis-resistant and CO2-permeable, with a permeability to CO2 of at least 10 000 cm3/m2/24 h/atm for a 25 ?m film of said copolymer, characterized in that said flexible block has a ratio of amine chain ends to acid chain ends which is within the range from 30 to 150.
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: February 14, 2023
    Assignee: ARKEMA FRANCE
    Inventors: Patrick Dang, Quentin Pineau, Inci Turan-Altuntas
  • Patent number: 11578199
    Abstract: Disclosed is a polyolefin-based resin composition for a vehicle interior material including heat-treated waste coffee grounds. The resin composition includes a polyolefin-based resin, waste coffee grounds including a volatile matter (VM) in an amount less than about 20 wt % of the waste coffee grounds, a modified polypropylene, an inorganic filler, and a thermoplastic elastomer.
    Type: Grant
    Filed: September 22, 2021
    Date of Patent: February 14, 2023
    Assignees: Hyundai Motor Company, Kia Corporation, 4EN Incorporation, GS Caltex Corporation
    Inventors: Han Ki Lee, A Rom Oh, Woo Ram Kim, Yeon Kyu Lee, Jung Woo Roh
  • Patent number: 11572464
    Abstract: An object of the present invention is to provide a medical rubber composition having excellent non-elution characteristic and gas permeability. The present invention provides a medical rubber composition containing: (a) a butyl rubber, (b) a diene-based rubber containing polybutadiene, (c) a peroxide-based crosslinking agent, and (d) a co-crosslinking agent, wherein an amount of (b) the diene-based rubber in 100 parts by mass of the rubber component composed of (a) the butyl rubber and (b) the diene-based rubber is 15 parts by mass or more and 90 parts by mass or less, and a mass ratio ((d)/(c)) of (d) the co-crosslinking agent to (c) the peroxide-based crosslinking agent is 1.2 or more and 25 or less.
    Type: Grant
    Filed: March 30, 2021
    Date of Patent: February 7, 2023
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventor: Yuichiro Matsutani
  • Patent number: 11566121
    Abstract: Provided is a thermoplastic elastomer composition for a weather strip material which is used for obtaining a molded product which has excellent adhesiveness to both a thermoplastic elastomer adherend and a crystalline ethylene resin adherend and also has excellent heat resistance at a fused portion. The thermoplastic elastomer composition for a weather strip material according to the disclosure contains: an ethylene-?-olefin copolymer rubber (A); an ?-olefin crystalline thermoplastic resin (B) having a melting point of 140° C. or higher; an olefin block copolymer (C) obtained by hydrogenating a block copolymer which has a conjugated diene polymer block with a 1,2-vinyl bond content of 25 mol % or less at both ends and also has a conjugated diene polymer block with a 1,2-vinyl bond content of more than 25 mol % in the middle; and a crystalline ethylene resin (D).
    Type: Grant
    Filed: February 4, 2021
    Date of Patent: January 31, 2023
    Assignee: ENEOS Materials Corporation
    Inventors: Masato Kobayashi, Kodai Ozaki
  • Patent number: 11566128
    Abstract: A soft polyolefin resin composition and an article molded therefrom are provided. The polyolefin resin includes: (A) 50 to 95% by weight of an ethylene-propylene block copolymer obtained by polymerization of a propylene homopolymer or an ethylene-propylene random copolymer with an ethylene-propylene rubber copolymer in stages in reactors; (B) 4.8 to 40% by weight of an ethylene-?-olefin rubber copolymer; and (C) 0.2 to 10% by weight of a copolymer of ethylene and a polar monomer, based on the total weight of components (A) to (C). The glass transition temperature of the rubber component in the ethylene-propylene block copolymer appears at ?60 to ?40° C. when measured by a dynamic mechanical analyzer, the melt index of the polyolefin resin composition measured at 230° C. under a load of 2.16 kg is 0.5 to 20 g/10 minutes, and the glass transition temperature of the rubber component in the polyolefin resin composition appears at ?60 to ?40° C. when measured by a dynamic mechanical analyzer.
    Type: Grant
    Filed: November 3, 2020
    Date of Patent: January 31, 2023
    Inventors: Eunwoong Lee, BongSeock Kim, YongSung Chun
  • Patent number: 11560475
    Abstract: An object of the present invention is to provide a photocurable resin composition capable of obtaining a cured product having excellent quick curability by irradiation with a low integrated light intensity and flexibility. A photocurable resin composition containing the following components (A) to (E): component (A): a monofunctional urethane (meth)acrylate having a polyether skeleton; component (B): a monofunctional (meth)acrylic monomer having a polyether skeleton and having no urethane skeleton; component (C): a photoradical polymerization initiator; component (D): a polyfunctional (meth)acrylic monomer having 4 or more functionalities; and component (E): a polyester-based plasticizer having no (meth)acryloyl group.
    Type: Grant
    Filed: April 26, 2021
    Date of Patent: January 24, 2023
    Assignee: THREEBOND CO., LTD.
    Inventor: Yusuke Kuwahara
  • Patent number: 11560443
    Abstract: A grafted polyvinyl alcohol polymer includes a polyvinyl alcohol main chain and a plurality of side chains grafted to the polyvinyl alcohol main chain. One or more of the side chains from the plurality of side chains include one or more units selected from: an aliphatic carboxylic acid, an aliphatic amide, an amino alkyl (meth)acrylate, a hydroxylated alkyl (meth)acrylate, or any combinations thereof. The grafted polyvinyl alcohol polymer can be included in a formulation that also includes water, and the formulation can be used as an adhesive in a creping process.
    Type: Grant
    Filed: September 3, 2020
    Date of Patent: January 24, 2023
    Assignee: BUCKMAN LABORATORIES INTERNATIONAL, INC.
    Inventors: Ahmed Moustafa, Daniel Glover
  • Patent number: 11560470
    Abstract: Provided is a thermoplastic elastomer composition capable of producing a molded article having a good appearance such as surface smoothness and excellent bondability to another member, the thermoplastic elastomer composition comprising: an ethylene-based polymer (A); and a propylene-based polymer (B), wherein a melt viscosity of the thermoplastic elastomer composition measured at a temperature of 220° C. and a shear rate of 12 sec?1 is 2,500 Pa·sec or less; the thermoplastic elastomer composition has a sea-island structure; and an island portion has a volume average particle diameter of 2.1 ?m or more and a particle diameter dispersion D of 7.0 or less.
    Type: Grant
    Filed: July 27, 2021
    Date of Patent: January 24, 2023
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Takahiro Konishi
  • Patent number: 11555104
    Abstract: The present disclosure relates to polymer compositions, articles formed from polymer compositions, methods of making polymer compositions, and methods of making articles including polymer compositions. In at least one embodiment, a composition includes: (1) an ethylene polymer, (2) a vinyl alcohol polymer or a polyamide, and (3) a polar polymer or a grafted polyolefin. A composition of the present disclosure may further include a polypropylene polymer. A polar polymer may be an ethylene-acrylic-acid-copolymer, ethylene acrylate copolymer, a polyvinyl acetate, or combination(s) thereof. In at least one embodiment, a film includes a composition having: (1) an ethylene polymer, (2) a vinyl alcohol polymer or a polyamide, and (3) a polar polymer or a grafted polyolefin.
    Type: Grant
    Filed: March 25, 2020
    Date of Patent: January 17, 2023
    Assignee: EXXONMOBIL CHEMICALS PATENTS INC.
    Inventors: Caroline N. Szala, Martin Machado, Michael Martin-Gatius, Joachim F. Laun, Linda M. van den Bossche
  • Patent number: 11542355
    Abstract: Polar modifier systems based on a blend of DTHFP, ETE, TMEDA, DMTHFMA and/or functionally similar compounds with BDMAEE and SMT are used to make block copolymers having high levels of pendant vinyl double bond repeat units, which is through highly selective 1,2-bond butadiene addition, low vinylcyclopentane formation, unimodal narrow molecular weight distribution, and a low level of randomized co-monomer repeat units. The block copolymers have very high levels of 1,2-vinyl content and high 3,4-vinyl bond addition of the conjugated diene monomer and low vinylcyclopentane content. The polar modifier systems provide a fast polymerization rate, with a unimodal narrow molecular weight distribution. The polar modifier systems allow operation at a higher temperature than in prior art systems, which reduces cooling requirements.
    Type: Grant
    Filed: January 13, 2021
    Date of Patent: January 3, 2023
    Inventors: Daniel Abraham Elizarrarás Maya, Christopher J. Hardiman, Sergio Corona Galván, Sergio Alberto Moctezuma Espiricueto, Luis Antonio Rodríguez Guadarrama
  • Patent number: 11535741
    Abstract: A block copolymer composition is disclosed herein. In some embodiments, a block copolymer composition has a weight average molecular weight (Mw) of 70,000 g/mol to 120,000 g/mol, a polydispersity index (PDI) of 1.0 to 2.0, a glass transition temperature (Tg) of ?55° C. to ?30° C., and a melt index (MI), measured at 230° C. and a loading condition of 5 kg, of 0.2 g/10 minutes to 3.0 g/10 minutes. The block copolymer composition has excellent processability.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: December 27, 2022
    Inventors: Yoon Ki Hong, Seok Pil Sa, Hyun Mo Lee, Eun Ji Shin, Ki Soo Lee, Bun Yeoul Lee
  • Patent number: 11535743
    Abstract: Thermoplastic compounds include elastomer, modified polyolefin polymer including a polar functional group, and unmodified polyolefin polymer. The melt flow rate of the modified polyolefin polymer is greater than the melt flow rate of the unmodified polyolefin polymer. The thermoplastic compounds exhibit excellent bonding when overmolded onto rigid substrates such as metals, while also providing desirable aesthetic properties and good processability.
    Type: Grant
    Filed: March 5, 2019
    Date of Patent: December 27, 2022
    Assignee: Avient Corporation
    Inventors: Haiping Zhang, Dirk Von Falkenhayn
  • Patent number: 11524150
    Abstract: Disclosed herein in is a medical tube comprising a hydrogenated styrenic block copolymer having a formula A-B-A, (A-B-A)nX or (A-B)nX is disclosed, where n is an integer from 2 to 30, and X is residue of a coupling agent. Prior to hydrogenation, each A block is a monoalkenyl arene homopolymer block having a true peak molecular weight of 5 kg/mol to 15 kg/mol. Each B block is a controlled distribution copolymer block having a true peak molecular weight of 30 kg/mol to 200 kg/mol. The hydrogenated styrenic block copolymer has a midblock poly(monoalkenyl arene) content of 35 wt. % to 50 wt. % based on the total weight of the midblock, and physical properties that makes it useful for producing medical tubes having kink resistance.
    Type: Grant
    Filed: August 27, 2019
    Date of Patent: December 13, 2022
    Assignee: KRATON POLYMERS LLC
    Inventors: Donn Dubois, Aparajita Bhattacharya