Abstract: Disclosed is an adhesive coating material for a hard tissue, which comprises (1) a polymer having an acid value of 30 to 700 and including a hydrophobic group and two carboxyl (--COOH) groups or one carboxylic anhydride ##STR1## group bonded to the polymer, said carboxyl groups or carboxylic anhydride group being bonded to adjacent carbon atoms, and (2) an organic titanate compound.

Abstract: Aromatic polyamines containing aromatic primary amino groups as well as urethane and polyester groups are made by hydrolyzing an isocyanate in the presence of a basic material and water to form a carbamate and then converting the carbamate groups to amino groups. The isocyanate starting material contains aromatic isocyanate groups (as well as urethane and polyester groups) and has an NCO content of from 0.5 to 11.5 wt %. The basic compound is selected from alkali metal hydroxides, alkaline earth metal hydroxides, alkali metal silicates, alkali metal sulfides, alkali metal cyanides, tetraalkylammonium hydroxides and mixtures thereof. Water is used in a quantity such that at least one mole of water is present for each equivalent of NCO groups. The carbamate groups may be converted to amino groups by treating the carbamate-containing mixture with a proton donor or with heat or with a solvent. The product polyamines are particularly useful in the production of polyurethanes.

Abstract: A thermosetting latex paint is disclosed which cures to provide better gloss and gloss retention of ultraviolet exposure. This latex paint comprises water having suspended therein copolymer particles of aqueous emulsion copolymerized monomers consisting essentially of monoethylenically unsaturated monomers including at least about 30% up to about 80% of vinyl acetate, the balance of the monomers in the copolymer including from 2% up to about 15% of monomers providing reactive hydrogen atoms, like hydroxyethyl methacrylate, to enable the copolymer to thermoset in the presence of a curing agent which reacts with the reactive hydrogen atoms of the copolymer, like hexamethoxymethyl melamine. The copolymer particles are suspended in the water by surfactant comprising at least 2% up to about 8%, based on total monomers, of an ethylene oxide adduct of an alkyl-substituted phenol having from 10-18 carbon atoms in the alkyl group with 5-14 moles of adducted ethylene oxide per mole of said substituted phenol.

Abstract: An acrylate or methacrylate functional copolymerizable monomer which serves as an adhesion for emulsion polymers is disclosed. This monomer is the adduct formed by reacting an aminoalkyl alkylene urea with about 0.9 up to about 1.5 molar proportions of a saturated monoepoxide to consume most or all of one of the two amino hydrogen atoms available, and then reacting with about 0.8 up to about 2.0 molar proportions of a monoisocyanate having a single acrylate or methacrylate group in the presence of at least 0.02%, based on the total weight of the reactants present, of an inhibitor which retards the free-radical polymerization of ethylenic unsaturation, such as hydroquinone, and phenothiazine.

Abstract: Homogenous liquid polyol blend compositions containing (a) certain aliphatic polyols, (b) phthalate diester polyols of said aliphatic polyols, and (c) trimellitate polyols of said aliphatic polyols. Such polyol blend compositions are useful in making homogenous liquid resin prepolymer blends compositions containing, in addition to such a polyol blend, fluorocarbon blowing agent, cell stabilizing surfactant, and urethane and/or isocyanurate catalyst. Such a resin prepolymer blend composition is suitable for reaction with organic isocyanates to produce cellular polyurethane and/or polyisocyanurate polymers.

Abstract: The subject invention relates to a process for preparing ferriferrocyanide pigments. The process comprises(a) forming an aqueous reaction mixture comprising(i) a ferrous salt,(ii) a compound selected from the group consisting of sulfuric acid, hydrochloric acid, an inorganic potassium salt, and mixtures thereof, and(iii) an alkali metal ferrocyanide such that the molar ratio of (i) to (ii) to (iii) is about 1:1 to 0.9:1.5 to 1:1;(b) oxidizing the acidic solution by aeration;(c) heating the aerated solution to from 10.degree. C. to 90.degree. C.; and(d) recovering the pigment.

Abstract: A composition for waterproofing and inhibiting corrosion of silicon dioxide containing substrates, such as masonry structures. The composition is from about 7% by weight to about 60% by weight of an alkylalkoxysilane, including oligomers and mixtures thereof, having a molecular weight of from about 100 to about 1000, and a solvent for the silane which can be an aromatic or aliphatic hydrocarbon solvent or mixtures thereof, with the solvent being free of alcohol groups.

Abstract: Novel solvent-based thermosetting composition comprising (a) hydroxy functional epoxy ester resin of number average molecular weight (Mn) between about 1,000 and about 5,000, comprising the reaction product of diepoxide with dicarboxylic acid and acid component comprising hydroxy functional acid and optionally further comprising fatty acid; and (b) polyfunctional, hydroxy-reactive crosslinking agent, for example, aminoplast crosslinking agent or blocked polyisocyanate crosslinking agent comprising isocyanate groups blocked by reaction with an active hydrogen bearing blocking agent. Coating composition may be formulated as primer sprayable with conventional spraying equipment.

Abstract: This invention relates to esters of alkyl diglycol ethers with mono- and dicarboxylic acids and the use thereof as coalescing agents in polymer latices employed in paint formulations. A particularly preferred ester is ethyldiglycol propionate. The esters claimed are effective in lowering the minimum film forming temperature of various emulsion polymers, are stable in the presence of water and are compatible with pigments and fillers normally used in paint formulations.

Abstract: A particulate or granular oxygen absorbent comprising at least one ascorbic compound selected from ascorbic acid, ascorbic acid salts or mixtures thereof, an alkali metal carbonate, an iron compound, carbon black and water and the absorbent coated with a finely divided powder are disclosed.

Abstract: Readily dispersible formulations comprising (a) finely divided copper phthalocyanine and (b) an iron hexacyanoferrate-III pigment are obtained by thoroughly milling a mixture of (a) and (b).The performance characteristics and tinctorial properties of the formulations comprising (a) and (b) can be improved by incorporating (c) a Mannich condensate obtained from 2-hydroxynaphthalene which may or may not possess 1 or 2 further .beta.-OH groups, formaldehyde and a primary or secondary amine, (d) a compound of the formula K(-NH-CONH-R).sub.2, where K is 1,5-naphthylene or 4,4'-diphenylenemethane and R is C.sub.12 -C.sub.18 -alkyl, C.sub.12 -C.sub.18 -alkenyl, C.sub.8 -C.sub.18 -alkoxypropyl or C.sub.2 -C.sub.8 -alkoxyethyleneoxypropyl, (e) a C.sub.6 -C.sub.18 -alkylbenzenesulfonic acid and (f) a mixture of (e) with a basic copper phthalocyanine and/or a salt obtained by reacting (e) with the basic copper phthalocyanine.

Abstract: A continuous method for producing a dispersion of phthalocyanine blue pigment in an organic solvent is disclosed. The method involves the following two steps:(A) mixing a phthalocyanine crude pigment at about 10 to 50% by weight with from about 5 to 20% by weight of surfactant in a binder containing an organic solvent, and(B) continuously pumping the blend of (A) through at least two shot mills in series in which the shot grinding media range in size from 0.1 to 2.5 mm. diameter and grinding the blend until the particle size of the crude is reduced to where the solvent dispersion has suitable pigment tinctorial strength for use in inks and coatings.The dispersion of blue pigment produced by this method is especially useful in paste inks and organic solvent-based coatings.

Abstract: In the production of polyether polyols, the neutralization of alkaline catalysts using formic acid such that no precipitate forms.

Abstract: A paint is formulated by combining fine boron nitride powder with a polymeric dispersion and a volatile liquid carrier, which paint is coated on ceramic preforms and subjected to hot pressing. The paint eliminates the formation of undesirable carbides on the surface of the pressed ceramic.

Abstract: An improved process for making glycidyl ethers of novolac resins, particularly cresol and phenol novolacs, by reaction of the novolac with a solid alkali metal hydroxide in excess epichlorohydrin and in the presence of an alcohol cosolvent where the reaction mixture contains a small amount of water, wherein the improvement comprises carrying out the etherification and dehydrochlorination in a combined one step process, in the absence of a catalyst specific for chlorohydrin formation, and using the solid alkali metal hydroxide in the form of tiny beads.

Abstract: A heat-curable polyurethane composition, comprising:(a) a secondary or tertiary aliphatic diisocyanate prepolymer;(b) a polyol compound;(c) a chain extender selected from the group consisting of sucrose and sorbitol; and(d) a curingly effective amount of a catalyst selected from the group consisting of magnesium acetylacetonate, nickel acetylacetonate, magnesium stearate, cadmium stearate, and organic acid salts of 1,8-diazabicyclo [5.4.0]undec-7-ene.

Abstract: Disclosed herein is an emulsifier or emulsifying composition which comprises one or more of the hydroxyalkyl or hydroxyalkenyl phosphates represented by the general formula (I) and/or (II): ##STR1## in which R represents an alkyl or alkenyl group of 5-21 carbon atoms, X.sub.1 and X.sub.2 independently represent a pair ion selected from the group consisting of hydrogen, alkali metal, ammonium, etc.The emulsifying composition according to the invention is highly safe to skin and widely usable in the emulsification of either W/O or O/W type.

Abstract: Improved aqueous based pressure sensitive adhesive compositions are disclosed comprising a latex of a carboxylated butadiene-styrene polymer and a tackifier resin.

Abstract: Water-containing peroxydisulfate suspensions containing potassium peroxydisulfate, a water-soluble polymer or copolymer of acrylic acid and/or maleic acid, with or without an anionic surfactant, where appropriate mixed with a non-ionic surfactant, and water, in which the aqueous phase contains from 12 to 65% by weight of not less than one other dissolved compound which keeps the system at a pH of not less than 5 and is a source of potassium ions.

Abstract: A method of producing surface-treated barium sulfate is disclosed which has an improved dispersibility in resins and coating compositions. The method comprises adding an aqueous solution of an alkali silicate to an aqueous slurry of barium sulfate which contains barium ion in excess to deposit barium silicate on the surface of barium sulfate, and then adding to the slurry a mineral acid to decompose the barium silicate to hydrous silica. The thus surface-treated barium sulfate may be further coated with hydrous metal oxides such as alumina or with a silane coupling agent so as to have a more improved dispersibility.