Abstract: Described are embodiments of a lithium metal phosphate production methods and systems. The systems and methods can include combining lithium extraction from spodumene, lithium recycling from lithium ion battery (“LIB”) black mass, and/or lithium metal phosphate synthesis from metal phosphates.

Abstract: This invention relates generally to a process for selective adsorption and recovery of lithium from natural and synthetic brines, and more particular to a process for recovering lithium from a natural or synthetic brine solution by passing the brine solution through a lithium selective adsorbent in a continuous countercurrent adsorption and desorption circuit.

Abstract: An object of the present disclosure is to provide a thin-film-like composite of nanocrystal, as a nanocrystalline material having excellent handling properties, which can overcome the above-mentioned problems of a nanocrystalline material having a powdery form while satisfactorily maintaining the properties of the nanocrystalline material (e.g., excellent catalytic activity). A thin-film-like composite of nanocrystal, characterized in that the thin-film-like composite of nanocrystal includes a thin-film-like connected assembly in which a plurality of nanocrystalline pieces each having a flake-like form and having a main surface and an end surface are connected to each other, the main surfaces of the plurality of nanocrystalline pieces exposed to the outside of the connected assembly are arranged so as to form gaps therebetween, and the connected assembly has a plan view area of 1 mm2 or more.

Abstract: The present disclosure concerns a process for the concentration of lithium in metallurgical fumes. The process comprises the steps of: —providing a metallurgical molten bath furnace; —preparing a metallurgical charge comprising lithium-bearing material, transition metals, and fluxing agents; —smelting the metallurgical charge and fluxing agents in reducing conditions in said furnace, thereby obtaining a molten bath with an alloy and a slag phase; and, —optionally separating the alloy and the slag phase; characterized in that a major part of the lithium is fumed as LiCl from the molten slag, by addition of alkali or earth alkali chloride to the process. Using a single smelting step, valuable transition metals such as cobalt and nickel also present in the charge are collected in an alloy phase, while the lithium reports to the fumes. The lithium in the fumes is available in concentrated form, suitable for subsequent hydrometallurgical processing.

Abstract: The present disclosure provides a method for fabricating a nickel-cerium dioxide-aluminum oxide hybrid nanoparticle cluster catalyst. The method includes a solution preparation step, an aerosolizing step, a drying step, a first calcining step, a reducing gas adding step, and a second calcining step. The solution preparation step is provided for preparing a precursor solution. The aerosolizing step is performed for obtaining an atomized droplet. The drying step is performed for converting to a precursor crystallite. The first calcining step is performed for obtaining an oxidation state catalyst. The reducing gas adding step is performed for adding hydrogen. The second calcining step is performed for obtaining the nickel-cerium dioxide-aluminum oxide hybrid nanoparticle cluster catalyst.

Abstract: An object of the present invention is to provide an electroless Pd plating solution which enables formation of a Pd plating film forming a plating film having excellent wire bondability even after a high-temperature thermal history. An electroless Pd plating solution of the present invention includes: a Palladium compound, a reducing agent, a complexing agent, and at least one selected from a group consisting of Ge and rare earth element.

Abstract: A method of recovering cobalt and nickel includes the steps of: adding alkaline to an acidic solution containing aluminum together with cobalt and nickel, adjusting pH of the acidic solution to 5 to 7, and converting the cobalt, the nickel and the aluminum into hydroxides thereof; recovering the hydroxides by solid-liquid separation, mixing the recovered hydroxides with an alkaline solution, and leaching aluminum contained in the hydroxides under a liquid condition of pH 8 or more; and recovering a cobalt hydroxide and a nickel hydroxide that aluminum is separated therefrom by solid-separation on a leachate.

Abstract: Various methods and systems are provided for facilitating the creation of a new and potentially thinner form of dielectric. Alternatively, for a given capacitance, a thicker layer can be created with lower risk of leakage. The present disclosure will enable the creation of physically smaller electronic components. Isotope-Modified Hafnium Dielectric is used to create a dielectric layer with a greater range of dielectric coefficients, which may enable the creation of smaller and/or more reliable electronic components.

Abstract: The present disclosure is an FCC additive composition comprising an acidity enhanced modified clay; an acidity enhanced modified alumina; a binder; a phosphorous oxide and a boron oxide, as well as a process for preparing the FCC additive composition. The FCC additive as disclosed is capable of cracking bottoms comprising large hydrocarbon molecules/heavy fuel oils, it enhances bottoms conversion and reduces formation of dry gas.

Abstract: This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

Abstract: Provided are a method of extracting lithium, which includes adding a phosphorus source material to a first solution containing a lithium cation (Li+) and an alkaline earth metal cation to produce a precipitate containing lithium, magnesium, calcium, strontium, and phosphorus, wherein the total concentration of the alkaline earth metal cations in the first solution is 100,000 mg/L or more, a method of preparing lithium carbonate using the same, and a method of preparing lithium hydroxide using the same.

Abstract: A method for preparing potassium chloride from carnallite includes: carrying out high-temperature water solution mining treatment on carnallite with fresh water to obtain potassium-rich saturated brine; mixing the potassium-rich saturated brine, a sylvine saturated solution, and bittern for mixing brine, evaporation and decomposition to obtain artificial sylvine; and carrying out low-temperature selective dissolution treatment on the artificial sylvine with fresh water to prepare potassium chloride. The carnallite is mined by using hot water, which reduces the content of sodium chloride in the potassium-rich saturated brine; artificial sylvine is only subjected to low-temperature selective dissolution once, which avoids unnecessary energy consumption and impurity accumulation unnecessary for multifold cycles of thermal dissolution-cold crystallization treatment of sylvine while guaranteeing the high yield and high quality of potassium chloride.

Abstract: The invention relates to a method and system for phosphate recovery from a stream such as waste flow, sewage or another sludge stream. The method comprises the steps of: providing an incoming stream comprising an initial amount of phosphate; dosing/controlling iron salt to the stream such that precipitates are formed in the stream, wherein the precipitates comprise vivianite like structures comprising more than 60% of the initial amount of phosphate in the incoming stream, and preferably also the steps of: separating the vivianite like structures from the stream; and recovering the phosphates from the separated vivianite like structures.

Abstract: The present invention relates to the methods of recycling electrochromic devices and also designing such devices while keeping recyclability in perspective. Recyclability includes recovering of certain materials for re-use within the same application or other applications. Using recycling reduces or eliminates waste stream quantities to be disposed of and/or reduces toxicity of these waste streams.

Abstract: Provided are a selective recovery method of vanadium and cesium from a waste sulfuric acid vanadium catalyst by a hydrometallurgical method including water leaching, solid-liquid separation, vanadium solvent extraction, vanadium selective stripping, and cesium alum production, and a high-quality vanadium aqueous solution and cesium alum produced thereby.

Abstract: The gemini surfactant for use in recycling lithium batteries is an anionic surfactant having the generic formula CxH2x+1(CyH2y+1) PO4CzH2zPO4CxH2x+1(CyH2y+1). An example of the surfactant is shown as compound 1 below where (x=5, y=2, z=4). Current solvents used to remove polymer binders include Nmethyl-2-pyrrolidone (NMP), N—N-dimethylformamide (DMF), N—N-dimethylacetamide (DMAC), N—N-dimethylsulfoxide (DMSA), and ethanol. The benchmark solvent often used to dissolve polymer binders is NMP. However, the present surfactants are phosphate-based surfactants and are used with a phosphate-based solvent, namely, triethyl phosphate (TEP), which is cheaper and more environmentally friendly than NMP. However, TEP has weaker binder solubility than NMP. Thus, the present surfactants are used with sonication to remove polymer binders.

Abstract: The invention relates to a method of separating and extracting rare-earths from rare-earth polishing powder waste and regenerating rare-earth polishing powder, which is characterized by: firstly, process the waste powder with first acid leaching, alkali roasting, and second acid leaching to separate and extract rare-earths from rare-earth polishing powder waste to obtain the leaching solution of rare-earth chloride; secondly, precipitate from the leaching solution with ammonia to remove impurities and hydrochloric acid solution to obtain the purified solution of rare-earth chloride; thirdly, co-precipitate from the solution acquired in the second step with hydrofluoric acid, ammonium bicarbonate, and dispersant to obtain the lanthanum cerium fluoro-carbonate; and finally, after drying, two-stage high-temperature calcination, and ball milling, the regenerated rare-earth polishing powder with decent polishing performance can be obtained.

Abstract: A cost-effective method for recovering precious metals in circuit board components utilizes the basic principle of oxidation-reduction reaction, adopts a mixed solution of sulfuric acid and hydrogen peroxide and a mixed solution of hydrochloric acid, sodium chloride and sodium chlorate, and also adopts ammonia water and formaldehyde to reduce silver. According to the characteristic that the redox potential of gold and palladium ions is higher, the gold and palladium ions in the chlorination leaching solution are selectively reduced into elements by using a reducing agent which is low in price and moderate in reducibility, then the elements are separated through filtration to realize resource recycling.

Abstract: An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

Abstract: The present invention provides a process of preparing a high coordination sulfated mixed metal oxide catalyst. The process comprises mixing specific ratios of alumina and zirconia mixtures at specific particle size limits which do not exceed 37 ?m, in the presence of a combination of ?-amino acids, i.e., non-polar side chains and basic side chains having molecular weight less than 250, nitric acid (HNO3) and sulfuric acid (H2SO4) at a pH range of 1.5 to 3.8 at temperatures below 30° C. The catalysts have a high conversion towards hydrocarbon isomerization reaction while concurrently having crushing strength in range of 2.0 daN and 5.0 daN, allowing for efficient commercial application.