Abstract: The invention is related to the sphere technologies for desulfurization and demercaptanization of gaseous hydrocarbons. It can be used for purification of any gaseous hydrocarbon medium. The device includes a catalytic reactor loaded with a catalyst solution in an organic solvent, a means of withdrawal sulfur solution from the reactor into the sulfur-separating unit, and a sulfur-separating unit. The sulfur-separation unit includes a means of sulfur extraction. The reactor design and the catalyst composition provide conversion of at least 99.99% of hydrogen sulfide and mercaptans into sulfur and disulfides. The catalyst is composed of mixed-ligand complexes of transition metals. The technical result achieved by use of claimed invention is effectively a single-stage purification of gaseous hydrocarbons from hydrogen sulfide and mercaptans with remaining concentration of —SH down to 0.001 ppm while leaving no toxic waste.
Abstract: A method of generating a refined sugar stream that comprises xylose from a biomass hydrolysis solution, including contacting a biomass hydrolysis solution that includes a population of mixed sugars comprising xylose, an acid, and impurities, with a thermally-phase separable solvent such as a glycol solvent to form an extraction mixture; and separating from said extraction mixture a first stream including the thermally-phase separable solvent, acid, and impurities and a second, refined sugar stream that comprises xylose. The thermally-phase separable solvent is an ethylene glycol or a propylene glycol ether, such as 2-butoxyethanol or 1-propoxy-propanol or any combination thereof.
Abstract: The present disclosure provides a process of clean production of electronic grade high-purity copper oxide. The process includes (1) preparing a carbon-ammonia system solution with a certain ratio of CO2, NH3 and H2O; (2) dissolving copper under a slightly negative pressure and at a system temperature less than or equal to 60° C.; the reaction ends until the concentration of copper in the carbon-ammonia system solution reaches 80 to 140 g/L; (3) adding sodium polyacrylate; the reaction solution is heated to 60-80° C. under a reduced pressure for deamination; (4) disposing basic copper carbonate to separate the solid from the liquid by a centrifuge to give an filter cake and copper-containing clear solution; (5) calcining the filter cake at 250-600° C.
Type:
Grant
Filed:
January 15, 2018
Date of Patent:
November 19, 2019
Inventors:
Ze Tan, Siping Huang, Yilang Zhou, Wei He, Chong Wang, Haiyan Lu
Abstract: Provided are porous titanate compound particles capable of giving excellent fade resistance and moisture-proof properties when used in a friction material, a friction material composition, a friction material, a friction member, and a method for producing the porous titanate compound particles. Porous titanate compound particles have a cumulative pore volume of 5% or more within a pore diameter range of 0.01 to 1.0 ?m, are each formed of titanate compound crystal grains bonded together, and each includes a treated layer formed on a surface thereof and made of a hydrophobic surface treatment agent.
Abstract: A porous catalyst for catalytic activating persulfates to decompose typical pollutants in papermaking wastewater is provided, and a synthesis method thereof and a method of degrading the typical pollutants in paper wastewater by using the porous catalyst are also provided. The porous catalyst MIL-88A@MIP is prepared by a molecular imprinting method comprising using metal organic framework MIL-88A as a precursor and using phthalates as templates.
Abstract: The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for: (i) reducing halogen levels necessary to affect gas-phase mercury control; (ii) reducing or preventing the poisoning and/or contamination of an SCR catalyst; and/or (iii) controlling various emissions. In still another embodiment, the present invention relates to a method and apparatus for: (A) simultaneously reducing halogen levels necessary to affect gas-phase mercury control while achieving a reduction in the emission of mercury; and/or (B) reducing the amount of selenium contained in and/or emitted by one or more pieces of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.).
Abstract: A porous substrate susceptible to one or both of hydroxylation and alkoxylation by a first protic solvent is exposed to a first relative pressure of the first protic solvent. The porous substrate includes a first plurality of pores having a first average pore diameter and a second plurality of pores having a second average pore diameter that is greater than the first average pore diameter. The first relative pressure is effective to one or both of hydroxylate or alkoxylate substantially only pores of the first average pore diameter to form a first modified porous substrate. The first modified porous substrate is reacted with a first functionalizing reagent that is effective to functionalize one or both of hydroxylated or alkoxylated surfaces, thereby functionalizing substantially only the first plurality of the pores, to form a first functionalized porous substrate.
Type:
Grant
Filed:
October 16, 2015
Date of Patent:
November 12, 2019
Assignee:
International Business Machines Corporation
Inventors:
Geraud J. Dubois, Bruno Michel, Patrick Ruch, Sarmenio Saliba, Willi Volksen
Abstract: A process for the vapour phase chemical dehydration of ethanol in a reactor in the presence of a supported heteropolyacid catalyst, said process comprising a step of contacting the ethanol with the heteropolyacid catalyst, wherein the heteropolyacid catalyst comprises a partially neutralised silicotungstic acid salt, wherein the partially neutralised silicotungstic acid salt has from 30% to 70% of the hydrogen atoms replaced with cations selected from the group consisting of alkali metal cations, alkaline earth metal cations, transition metal cations, ammonium cations, and mixtures thereof; but with the proviso that the alkali metal cation is not lithium; and wherein, after attaining steady-state performance of the catalyst, said process is operated continuously with the same supported heteropolyacid catalyst for at least 150 hours, without any regeneration of the catalyst.
Abstract: The present invention relates to a method of forming a particulate porous metal oxide or metalloid oxide, as well as uses of the obtained a particulate porous metal oxide or metalloid oxide. A solution of a non-ionic surfactant and either an ionic surfactant or an inorganic salt is formed in an acidic aqueous solution. A metal oxide precursor or a metalloid oxide precursor is added. The formed reaction mixture is heated under reflux upon agitation for a period sufficient to obtain a particulate porous metal oxide or metalloid oxide.
Abstract: Improved processes for extracting water soluble nutrients including sugars from plants and in particular sugar cane. The plants may be washed with a wash solution. After washing, water soluble nutrient containing liquid is extracted from the plants. A diluted wash solution may be added to the crushed plants to improve the extraction of the water soluble nutrients. The wash solution may be added to the liquid collected during the extraction to improve the separation of impurities from the nutrient containing liquid. The extracted liquid may demonstrate at least one of improved purity, improved clarity, improved filtration times, improved whiteness, and improved total recovered water soluble nutrients.
Abstract: The present disclosure provides a process for production of glucose having purity greater than 98% from pretreated cellulosic biomass comprising 50-95% cellulose, using thermo-chemical and enzymatic treatments. The process of the disclosure involves mild acid and/or alkali treatment of the pretreated cellulosic biomass for production of treated cellulosic biomass residue comprising polysaccharides containing greater than 98% glucose. The treatment results in high purity cellulose that is highly amenable to enzymatic hydrolysis and yields glucose having purity greater than 98%. The process of the disclosure also involves membrane separation of enzymes and oligosaccharides for recycling and separation of glucose to avoid product feedback inhibition.
Type:
Grant
Filed:
July 22, 2016
Date of Patent:
November 5, 2019
Assignees:
Institute of Chemical Technology, The Coca-Cola Company
Abstract: The present invention relates to formulations comprising at least one hydridosilane of the generic formula SinH2n+2 with n=3-6 and at least one hydridosilane oligomer, to processes for preparation thereof and to the use thereof.
Type:
Grant
Filed:
June 12, 2014
Date of Patent:
October 29, 2019
Assignee:
EVONIK DEGUSSA GMBH
Inventors:
Paul Henrich Woebkenberg, Matthias Patz, Stephan Traut, Jutta Hessing, Miriam Deborah Malsch
Abstract: A liquid composition for forming a silica porous film of the invention is prepared by mixing a hydrolyzate of tetramethoxysilane or tetraethoxysilane as a silicon alkoxide with a silica sol in which fumed silica particles having primary particles having a mean particle diameter of 40 nm or less and secondary particles having a mean particle diameter of 20 nm to 400 nm, that is greater than the mean particle diameter of the primary particles, are dispersed in a liquid medium, in which the mass ratio (A/B) of the SiO2 content (B) of the silica sol to the SiO2 content (A) in the hydrolyzate is in a range of 1/99 to 60/40.
Abstract: The present invention is directed to a process for obtaining a nanostructured titania catalyst with stabilized acidity through the sol-gel method and hydrotreatment and thermal activation; constituted basically by titanium oxide, specially characterized of being as nanostructures in its evolution nanocrystals-nanotubes-nanocrystals, that gives special physicochemical properties such as high specific area, purity and phases stability, acidity stability and different types of active acid sites, such as a capacity to disperse and stabilize metallic particles with high activity mainly in catalytic processes.
Type:
Grant
Filed:
September 25, 2014
Date of Patent:
October 29, 2019
Assignee:
INSTITUTO MEXICANO DEL PELTROLEO
Inventors:
Salvador Castillo Cervantes, Isidro Mejia Centeno, Jesus Marin Cruz, Policarpo Galicia Gómez, Roberto Camposeco Solis
Abstract: A process for producing an aqueous composition comprising a dispersed esterified cellulose ether comprises the steps of grinding, in the presence of an aqueous diluent an esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a N divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation, blending a salt of a fatty acid with the esterified cellulose ether and choosing the amounts of aqueous diluent, esterified cellulose ether and salt of a fatty acid that the produced aqueous composition comprises at least 20 percent of the dispersed esterified cellulose ether and heating the aqueous composition to a temperature of from 37 to 80 C during or after the grinding step.
Type:
Grant
Filed:
July 8, 2016
Date of Patent:
October 22, 2019
Inventors:
Meinolf Brackhagen, Neal J. Fetner, Matthias Knarr, Jin Zhao
Abstract: The present subject matter relates generally to a method for the removal of oxygen from hydrogen using a manganese, iron, nickel or cobalt based adsorbent. More specifically, the present subject matter relates to the methods for the removal of oxygen from hydrogen using a manganese based adsorbent without the generation of water or other oxides.
Type:
Grant
Filed:
November 3, 2016
Date of Patent:
October 22, 2019
Assignee:
UOP LLC
Inventors:
Stephen Caskey, Vladislav I. Kanazirev, Thomas Traynor
Abstract: A process for forming a fingerprint-resistant coating on a substrate comprising activating the substrate by exposure to a plasma, and then depositing on the activated substrate at least one alkyl backbone monolayer, and hydroxyl-polyhedral oligomeric silsesquioxane (OH—POSS) nanoparticles.
Type:
Grant
Filed:
June 6, 2017
Date of Patent:
October 22, 2019
Assignee:
NBD NANOTECHNOLOGIES, INC.
Inventors:
Miguel Galvez, Bong June Zhang, Esra Altinok
Abstract: Pulverulent alkali metal alkyl siliconates having lesser hydroscopicity and improved hydrophobicity in construction materials are produced by spray drying an aqueous solution of an alkali metal alkylsiliconate having a defined range of alkali metal content, a low alcohol content, and a low chlorine content.
Abstract: Processes for producing polycrystalline silicon by thermal decomposition of silane are disclosed. The processes generally involve thermal decomposition of silane in a fluidized bed reactor operated at reaction conditions that result in a high rate of productivity relative to conventional production processes.
Abstract: Processes for producing polycrystalline silicon by thermal decomposition of silane are disclosed. The processes generally involve thermal decomposition of silane in a fluidized bed reactor operated at reaction conditions that result in a high rate of productivity relative to conventional production processes.