Patents Examined by Melvyn I. Marquis
  • Patent number: 5945497
    Abstract: A process for treating a plurality of by-product streams containing chlorosilicon compounds. The process comprises the steps of determining the average SiCl functionality of a plurality of by-product streams comprising chlorosilicon compounds, blending at least two of the by-product streams to form a blended by-product stream having an average SiCl functionality greater than or equal to 2.8, adding to the blended by-product stream a surfactant having a HLB number within range of about 3 to 28, and contacting the blended by-product stream with an aqueous medium at a temperature within a range of about 50.degree. C. to 120.degree. C. to form a granular siloxane gel.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: August 31, 1999
    Assignee: Dow Corning Corporation
    Inventors: Ollie William Marko, Denise Lynne McClure
  • Patent number: 5945469
    Abstract: This invention relates to novel nylon compositions that maintain their appearance on weathering in the presence of U.V. light and a process of their manufacture. These composition are useful in a variety of applications including fibers, molded plastic parts, films and coatings.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: August 31, 1999
    Assignee: AlliedSignal Inc.
    Inventors: Richard Bidwell Heath, Keith Alan Horn, Allen Franklin Chambers, Jr., Lutz Stoeber
  • Patent number: 5945502
    Abstract: A polymer including mers of the formulas: ##STR1## and copolymers or mixtures thereof.
    Type: Grant
    Filed: November 13, 1997
    Date of Patent: August 31, 1999
    Assignee: Xerox Corporation
    Inventors: Bing R. Hsieh, Yuan Yu
  • Patent number: 5945172
    Abstract: A coating agent composition comprising an organopolysiloxane resin: with the organopolysiloxane resin having a number average molecular weight of at least 500 and acrylic or methacrylic functional group-attached silicon atoms in a proportion of 5 to 100 mole % to the total silicon atoms; and with the resin comprising units represented by formula R.sup.1 LSiX.sub.3 in a proportion of 30 to 100 mole %, wherein R.sup.1 is a hydrogen atom or a substituted or unsubstituted organic group having 1 to 18 carbon atoms and X is a hydroxyl group, a hydrolyzable group or a siloxane residue, provided that at least one X is a siloxane residue; wherein from 30 to 80 mole % of the R.sup.1 SiX.sub.3 units are one silanol group-containing units represented by formula R.sup.1 Si(OH)Y.sub.2 wherein Y is a siloxane residue.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: August 31, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaaki Yamaya, Kazuharu Sato, Hiroaki Kizaki, Masahiro Furuya
  • Patent number: 5942571
    Abstract: A liquid silicone rubber composition for use in high-voltage eletrical insulating parts comprising (A) a polyorganosiloxane containing alkenyl groups, (B) fumed silica, (C) a polyorganohydridosiloxane, (D) a platinum type catalyst, (E) finely powdered aluminum hydroxide, and (F) a powdered metal compound selected from the group consisting of powdered zinc oxidc, powdered zinc borate, and powdered magnesium hydroxide and a method for manufacturing such a composition.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: August 24, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akito Nakamura, Yasumichi Shigehisa, Yuichi Tsuji
  • Patent number: 5942591
    Abstract: A solventless curable silicone release composition contains (A) a branched organopolysiloxane having a vinyl group attached to a silicon atom at an end of its molecular chain, (B) an organohydrogenpolysiloxane having at least three SiH groups in a molecule, and (C) a platinum group metal catalyst. The composition is easily applicable to a thin gage and cures into a releasable silicone coating ensuring light release at high speeds. A release sheet having the cured coating formed thereon has improved release characteristics.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: August 24, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hideyuki Itoh, Toshio Ohba, Kenichi Isobe, Shinji Irifune, Takamasa Toyoda
  • Patent number: 5942583
    Abstract: A primer composition contains (A) an organic silicon compound having a group of the formula: --CR.sup.2 R.sup.3 (CH.sub.2).sub.m COOR.sup.1, (B) an organic silane compound of the average compositional formula: R.sup.7.sub.b R.sup.8.sub.c (OR.sup.9).sub.d SiO.sub.(4-b-c-d)/2, (C) an organic silicon compound containing a SiH group, represented by the average compositional formula: R.sup.10.sub.e H.sub.f SiO.sub.(4-e-f)/2 and/or an organic silicon compound containing a SiH group and 1-4 divalent or trivalent aromatic rings or a C.sub.2 -C.sub.30 alkylene group, and (D) an epoxy resin. The primer composition assists in the adhesion of silicone elastomers to metallic and plastic substrates and is useful as adhesive.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: August 24, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Syuuichi Azechi
  • Patent number: 5942590
    Abstract: The present invention is hydrophobic silica gels having a reduced surface area and a method for their preparation under neutral conditions. The method comprises two steps, where in the first step the pH of a mixture comprising a silica hydrosol and colloidal silica is adjusted with a base to within a range of pH 3 to pH 6 to facilitate formation of a silica hydrogel having incorporated therein colloidal silica. In the second step the silica hydrogel is contacted with an organosilicon compound in the presence of a catalytic amount of a strong acid to effect hydrophobing of the silica hydrogel to form a hydrophobic silica gel having a surface area within a range of about 100 m.sup.2 /g to 450 m.sup.2 /g in the dry state. In a preferred process the hydrophobic silica gel is contacted with a sufficient quantity of a water-immiscible organic solvent to convert the hydrophobic silica hydrogel into a hydrophobic silica organogel.
    Type: Grant
    Filed: February 11, 1998
    Date of Patent: August 24, 1999
    Assignee: Dow Corning Corporation
    Inventors: Gary Thomas Burns, Qin Deng, James Richard Hahn, Clifford Carlton Reese
  • Patent number: 5939487
    Abstract: A room temperature curable organopolysiloxane composition including:(A) a diorganopolysiloxane terminated with a hydroxyl group at the both terminal ends and having a viscosity at 25.degree. C. of 25 to 1,000,000 cSt,(B) an organosilane having 3 or more hydrolyzable groups per molecule, a partially hydrolyzed and condensed product thereof or a mixture thereof, said hydrolyzable group is a ketoxime group or an alkenyloxy groups, anda thin leaf-like inorganic filler. This can give cured products with good oil resistance, and suitable as FIPG materials for automobiles.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: August 17, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsuneo Kimura, Kazuyuki Suzuki, Mamoru Teshigawara
  • Patent number: 5939507
    Abstract: A method for manufacturing a siloxane compound described by formula R.sup.1.sub.m Si{OSi(CH.sub.3).sub.2 H}.sub.(4-m) comprising reacting a silane compound or condensation product of a silane compound described by formula R.sup.1.sub.m Si(OR.sup.2).sub.(4-m), where R.sup.1 is selected from the group consisting of hydrogen and substituted or unsubstituted monovalent hydrocarbon groups, R.sup.2 is hydrogen, alkyl groups and alkoxyalkyl groups, and m is an integer from 0 to 3, with 1,1,3,3-tetramethyldisiloxane in an aqueous solution of an acid in which the acid concentration is 1.0 wt % or less, and the molar ratio of the aqueous solution to the 1,1,3,3-tetramethyldisiloxane is in the range of 0.5 to 1.5. The method is particularly useful for manufacturing siloxane compounds having dimethylhydrodosiloxy groups.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: August 17, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Tadashi Okawa
  • Patent number: 5936054
    Abstract: An addition-crosslinkable silicone rubber composition comprising the constituents(I) an alkenyl-functional polyorganosiloxane(II) a SiH-functional crosslinker(III) a hydrosilylation catalyst and(IV) at least one 1H-benzotriazole-5-carboxylic acid derivative selected from a group consisting of 1H-benzotriazole-5-carboxylic acid esters and 1H-benzotriazole-5-carboxylic acid amides.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: August 10, 1999
    Assignee: Wacker-Chemie GmbH
    Inventors: Frank Achenbach, Christof Worner, Brigitte Ostermeier, Georg Eberl, Jelica Gegic
  • Patent number: 5935372
    Abstract: Disclosed is a blend capable of forming a semi-interpenetrating network when cured of (A) a solution of about 30 to about 50 wt % solids in an organic solvent of a fully imidized polyimidesiloxane and (B) about 5 to about 30 pbw per 100 pbw of the polyimidesiloxane of an epoxy resin which comprises a cycloaliphatic epoxy and an epoxy curing agent. The polyimidesiloxane is the reaction product of an aromatic dianhydride and diamine. The diamine is about 5 to about 80 mole % non-siloxane containing aromatic diamine and the remainder a siloxane diamine, where the siloxane diamine is about 40 to about 80 wt % of the weight of the polyimidesiloxane. The blend is used to bond metal parts to ceramic packages.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: August 10, 1999
    Assignee: Occidental Chemical Corporation
    Inventors: Sergio Rojstaczer, David Y. Tang, Jerald C. Rosenfeld
  • Patent number: 5936014
    Abstract: Biodegradable thermoplastic materials made of blends of starch esters and polyalkylene glycols with additions of polybasic aliphatic carboxylic acids and oxycarboxylic acids are improved with respect to water stability and mechanical characteristics and barrier properties by admixing to the blends aliphatic polycarbonates at levels of from 5:95 to 95:5 with the optional addition of ecologically compatible plasticizers and fillers.These materials can be used for all goods which are to be packaged in films, in particular tobacco products, but also soap, paper tissues, toilet articles, and the like. In addition to biodegradability, said materials are characterized in that they may be fed to a special recycling process, but also to conventional recycling processes without adversely affecting them.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: August 10, 1999
    Assignees: Buna Sow Leuna Olefinverbund GmbH, Reynolds Tobacco GmbH
    Inventors: Hans-Dieter Voigt, Manfred Gehring, Christel Rom, Dieter Weiwad, Inno Rapthel, Rolf Kakuschke, Kerstin Reichwald
  • Patent number: 5932654
    Abstract: The present invention provides a primer composition for polyolefins which has sufficient adhesion to polyolefin base materials and excellent resistance to gasohol and high pressure washing of cars. This primer composition for polyolefins comprises: acid anhydride-modified polypropylene chloride (A), which includes polypropylene chloride moiety (a1) and acid anhydride moiety (a2) as bonded thereto, and has a chlorine content of 19.5 to 20.5 wt %, an acid anhydride moiety content of 0.8 to 1.2 wt %, and a weight-average molecular weight of 30,000 to 36,000; and acryl-modified polypropylene chloride (B), which includes polypropylene chloride moiety (b1) and acrylic polymer chain moiety (b2) as grafted thereon, and has a weight-average molecular weight of 30,000 to 200,000, wherein: polypropylene chloride moiety (b1) has a chlorine content of 20 to 30 wt %; acrylic polymer chain moiety (b2) has a glass transition temperature of 60.degree. C.
    Type: Grant
    Filed: November 15, 1997
    Date of Patent: August 3, 1999
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Nippon Bee Chemical Co., Ltd.
    Inventors: Takeshi Ogawa, Katsuo Miyazaki, Makoto Hashimoto
  • Patent number: 5932060
    Abstract: Substantially branched alkenyl silicone polymer compositions having on average at least two branching points per molecule provide laminate release compositions that provide releasable laminates against methyl and phenyl silicone pressure sensitive adhesives.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: August 3, 1999
    Assignee: General Electric Company
    Inventors: Michael J. O'Brien, Roy M. Griswold
  • Patent number: 5929269
    Abstract: The present invention relates to a process for preparing organosilicon compounds which contain at least one H.sub.2 C.dbd.CH--Si-group, by reacting an organosilicon compound which contains at least one H--Si-group with acetylene in a gas/liquid phase in the presence of at least one addition catalyst and extracting the organosilicon compound which contains at least one H.sub.2 C.dbd.H--Si-group from the reaction mixture, wherein an organosilicon compound which contains at least one H--Si-group, the acetylene, which is used in stoichiometric excess, and a substantially inert liquid phase is brought into very intimate contact in a jet tube loop reactor in the presence of a catalyst, and the organosilicon compound which contains at least one H.sub.2 C.dbd.CH--Si-group is subsequently extracted from the reaction mixture and the excess acetylene is recycled into the process.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: July 27, 1999
    Assignee: Huels Aktiengesellschaft
    Inventor: Frank Steding
  • Patent number: 5929159
    Abstract: Corrosion resistant coatings are provided by aqueous-alcoholic acidic dispersions of the partial condensate of monomethyl silanol (by hydrolysis of monomethyl alkoxysilane) alone or in admixture with minor amounts of other silanol, e.g., gamma-glycidyloxy silanol, phenyl silanol, etc, wherein the dispersions contain divalent metal cations, e.g., Ca.sup.+2, in place of all or most of colloidal silica used in prior formulations of this type. The coatings may be applied to boat hulls, including aluminum hulls and are effective in preventing corrosion from salt water for extended periods.
    Type: Grant
    Filed: October 23, 1997
    Date of Patent: July 27, 1999
    Assignee: Adsil LC
    Inventors: John B. Schutt, Anthony A. Gedeon
  • Patent number: 5929187
    Abstract: A novel branched siloxane-silalkylene copolymer containing a plurality of silicon-bonded hydrogen atoms or silicon-bonded alkoxy groups in the molecule. The copolymers are used to improve properties, such as, mechanical strength, adhesiveness, and durability of an end product.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: July 27, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Makoto Yoshitake
  • Patent number: 5929186
    Abstract: A release agent composition for use in an electrophotographic process is disclosed. This composition includes a specifically-defined heat-stable silicone oil-silicone wax random copolymer. The copolymer has a melting point such that it is liquid on the hot fuser roll, but solidifies at room temperature on the printed page. A random silicone copolymer, in the form of a paste or pliable caulk, which is useful for sealing leaks in toner cartridges is also disclosed. Finally, the method for preparing these copolymers is disclosed.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: July 27, 1999
    Assignee: Lexmark International, Inc.
    Inventors: Jing X. Sun, Terence E. Franey, Bradley L. Beach, Kathryn E. Dowlen
  • Patent number: 5929143
    Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: July 27, 1999
    Assignee: General Electric Company
    Inventors: Brian John Ward, Edward Matthew Jeram, Richard Albert Striker