Abstract: An anion exchange membrane is composed of a copolymer of 1,1-diphenylethylene and one or more styrene monomers, such as 4-tert-butylstyrene. The copolymer includes a backbone substituted with a plurality of ionic groups coupled to phenyl groups on the backbone via hydrocarbyl tethers between about 1 and about 7 carbons in length. High-temperature conditions enabled by these copolymers enhance conductivity performance, making them particularly suitable for use in anion exchange membranes in fuel cells, electrolyzers employing hydrogen, ion separations, etc. The properties of the membranes can be tuned via the degree of functionalization of the phenyl groups and selection of the functional groups, such as quaternary ammonium groups. Several processes can be used to incorporate the desired ionic functional groups into the polymers, such as chloromethylation, radical bromination, Friedel-Crafts acylation and alkylation, sulfonation followed by amination, or combinations thereof.

Abstract: Provided is a fluororesin coating composition for forming a topcoat having improved non-tackiness and water and oil repellency. The fluororesin is crystalline tetrafluoroethylene and perfluoro(ethyl vinyl ether) copolymer having a perfluoro(ethyl vinyl ether) content of 8 to 20 mass % based on the total mass of the copolymer.

Abstract: A composite proton conductive membrane, comprising an inorganic filler having covalently bonded acidic functional groups and a high surface area of at least 150 m2/g; and a water insoluble ionically conductive polymer. This membrane provides advantages over traditional polymeric proton conductive membranes for redox flow battery, fuel cell, and electrolysis applications include: 1) enhanced proton conductivity/permeance due to the formation of additional nanochannels for proton conducting; 2) improved proton/electrolyte selectivity for redox flow battery application; 3) reduced membrane swelling and gas or electrolyte crossover; 4) improved chemical stability; 5) increased cell operation time with stable performance, and 6) reduced membrane cost.

Abstract: The present disclosure is directed to provide a methacrylic resin and a methacrylic resin composition which enable production of a shaped article excellent in color tone in a long path length. A methacrylic resin of the present disclosure has a structural unit (X) including a cyclic structure in a main chain thereof. The methacrylic resin having a glass transition temperature (Tg) of higher than 120° C. and 160° C. or lower. An emission intensity at 514 nm in terms of a concentration of a solution of fluorescein in ethanol is 30×10?10 mol/L or less when a solution containing 2.0 mass % of the methacrylic resin in chloroform is spectroscopically analyzed using an excitation wavelength of 436 nm and a slit width of 2 nm.

Abstract: Anion exchange membrane and methods of making and using the same. In one embodiment, the anion exchange membrane may be made by a method that includes a two-step polymerization. In the first step, an ?-olefin monomer containing a pendant halide, such as 8-bromo-1-octene, may be polymerized by Ziegler-Natta polymerization to form a first polymer portion, the first polymer portion being a homopolymer. In the second step, the polymerization is charged with a non-functionalized ?-olefin monomer, such as ethylene, thereby forming a second polymer portion, the second polymer being a copolymer made up predominantly of the non-functionalized olefin monomer. If desired, a small amount of an ?-olefin monomer containing a crosslinking functionality may be included in the first and/or second steps. Following the two-step polymerization, the polymer is fabricated into a thin film. Thereafter, the thin film may be functionalized by replacing the pendant halides with pendant cations.

Abstract: A method of forming an etched part includes forming a substrate including a thermoset resin and etching a surface of the substrate. The thermoset resin includes a vat photopolymerization (VPP) thermoset resin and at least one of an etchable phase and etchable particles disposed within the VPP thermoset resin. The etching removes the etchable phase from the VPP thermoset resin at the surface of the substrate such that a plurality of micro-mechanical bonding sites are formed on an etched surface of the substrate.

Abstract: The present invention relates to a process for preparation of superabsorbent polymer with high fluid absorptivity. The present invention also relates to a composition comprising said superabsorbent polymer and their use for absorbing aqueous fluids, for example in the agricultural industry.

Abstract: A light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an interlayer disposed between the first electrode and the second electrode and including an emission layer patterned into a red emission layer and a green emission layer for a corresponding sub-pixel, wherein the red emission layer includes a red dopant having a horizontal dipole moment, and the green emission layer comprises a green dopant having a horizontal dipole moment, and the horizontal dipole moment of the green dopant is greater than the horizontal dipole moment of the red dopant.

Abstract: A curable composition can comprise a polymerizable material including a monomer of Formula (1), with R being H or alkyl or alkylaryl, n being 1-4, m being 0-6, X1 being C1-C6 substituted or unsubstituted alkyl, X2 being CH3 or H, After forming a cured layer of the curable composition, the cured layer can have an excellent etch resistance.

Abstract: Fluorinated compositions include a fluorinated copolymer formed from a fluorine-containing monomer and vinyl chloride, the fluorine-containing monomer in an amount of from 0.5 weight % to 10.0 weight % based on a combined weight % of fluorine-containing monomer and vinyl chloride. Methods of making a fluorinated copolymer are further provided. Ultraviolet-protective films formed from a mixture including a fluorinated copolymer are further provided.

Abstract: The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the ?-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.

Abstract: The present invention relates to a curable adhesive composition based on acetoacetate compound, and to its use in multi-purpose bonding applications. In particular, the present invention relates to a curable adhesive composition based on a multifunctional acetoacetate compound and polyoxyalkylene polyamines.

Abstract: An extruder including a housing, a first material inlet for a mixture at least consisting of a solvent and a dissolved medium, a material outlet, a screw, a screw drive, and at least one distillation region between the inlet and the outlet, which allows an outflow of solvent, and a discharge line for the solvent.

Abstract: Meltable flame retardant compositions and fibers fabricated thereof are provided. Compositions of the present disclosure comprise a polymer, a nitrogenous compounds and/or a phosphorus compound. Fibers and compositions of the present disclosure can be used to make fabrics. When fibers, fabrics, and compositions of the present disclosure are exposed to flame, non-flammable gases are released such that the flames is retarded and/or extinguished.

Abstract: The present invention provides a metal-oxo complex represented by the following general formula (1), wherein in the general formula (1) above, “M” represents a molybdenum atom or a tungsten atom; “A” represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom; X1 and X2 each independently represent a halogen atom; R1 to R5 each independently represent a hydrogen atom, a straight or branched chain alkyl group that is substituted or unsubstituted and has 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms; each of R1 to R3 may be bonded to one another to form a ring.

Abstract: Presented are multilayer composite panels for motor vehicles, methods for making/using such panels, and motor vehicles with transparent composite roof panels having localized reinforcement features. A sandwich-type multilayer composite panel contains one or more exterior layers each including a transparent rigid material, one or more bonding layers each including a transparent adhesive material, and one or more structural reinforcement layers each including a fiber-reinforced polymer material. Each structural reinforcement layer may be attached directly to a bonding layer and/or exterior layer. The composite panel may also include one or more IR-reflective layers, one or more light-absorbing sunshade layers, and one or more insulating low-k layers.

Abstract: Described are ion-exchange membranes that include a porous polymeric membrane and imidazole ion-exchange groups at surfaces of the membrane; ion-exchange membranes and filters that contain the ion-exchange membranes; and methods of using the ion-exchange membranes and filters for separating charged biological molecule from a liquid.

Abstract: This application provides reactive, flexible, water-resistant hydroxyethylpyrrolidone methacrylate/glycidyl methacrylate copolymers having the structure: wherein a and b are integers, the sum of which less than 100, covalently linked to active agents that are useful in a wide variety of compositions. The present application also discloses hydroxyethylpyrrolidonemethacrylate/glycidyl methacrylate copolymer convently linked to one or more surface active moiety having a structure: wherein a, b, and c are integers, the sum of which equals 100, and M is a surface-active moiety.

Abstract: A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Abstract: Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.