Abstract: The title compounds, having the formula (RO.sub.2 CNHCH.sub.2).sub.3 P, are prepared by reacting a quaternary phosphonium salt, having the formula (RO.sub.2 CNHCH.sub.2).sub.4 P.sup.+ X.sup.-, with a base, preferably one that is capable of reacting with and thereby inactivating the by-product formaldehyde or formaldehyde derivative. The products are useful as intermediates for the preparation of finishing agents that impart flame retardant properties to cotton fabrics.
Type:
Grant
Filed:
November 29, 1978
Date of Patent:
May 20, 1980
Assignee:
The United States of America as represented by the Secretary of Agriculture
Abstract: This invention involves a method of producing vinyl esters by the reaction of olefins with carboxylic acids in the presence of alkali and alkaline earth metal salts of carboxylic acids, a noble metal compound, and a regenerative oxidant capable of maintaining the noble metal in oxidized form.
Abstract: Vicinal hydroxyesters and diesters are prepared by the oxidation of olefins with molecular oxygen in a carboxylic acid at a temperature of over 150.degree. C. in the presence of a catalyst combination containing tellurium and an iodide source.
Abstract: Diacyloxy olefins are prepared by the reaction of a conjugated diolefin with a carboxylic acid in the presence of free oxygen and a catalyst system consisting essentially of an alkali metal compound and a compound of gold or silver.