Abstract: This invention relates to the irradiation of compositions comprising non-ethylenically unsaturated brominated and chlorinated aromatic polyester fibrous materials with low intensity ultraviolet light radiation for relatively brief periods of time under appropriate conditions to yield a product of enhanced solvent resistance. The irradiation of the halogenated polyesters (as defined) generates free radicals within the fibrous material which react to produce sufficient cross-linking to enhance solvent resistance without a significant detrimental change of other product properties.
Abstract: An aqueous based slurry is disclosed containing an aqueous carrier fluid, an epoxy resin, a curing agent for the resin, a solvent for said resin and curing agent, a finely divided particulate material, a particular quaternary ammonium halide, and a coupling agent to promote bonding of the resin to the particulate. Optionally, the slurry may contain a thickening or gelling agent for the water to enhance its solids carrying capacity and an agent to break the gel after its purpose has been served. The slurry, suitable for use in placing a permeable, consolidated gravel pack adjacent an incompetent subterranean formation, is characterized in that it does not require an oil-based carrier and also in that it can easily be prepared in the field by adding the particulate directly to the aqueous carrier without precoating the particulate with the resin.
Abstract: This invention is concerned with coating and/or impregnating compositions comprising(a) A copolymer of 5 to 50% by weight of dicyclopentenyl acrylate or methacrylate with 50 to 95% by weight of at least one other monoethylenically unsaturated comonomer.(b) An essentially non-volatile reactive comonomer consisting of dicyclopentenyl acrylate or methacrylate or a mixture thereof, or comprising a mixture of at least 50% by weight of one or both of these monomers with up to 50% by weight of at least one other reactive monomer, such as a (C.sub.10 -C.sub.20)alkyl acrylate or methacrylate, a (C.sub.10 -C.sub.20)alkenyl acrylate or methacrylate, a di(C.sub.4 -C.sub.20)-alkyl fumarate, maleate, or itaconate, or a polyethylenically unsaturated monomer, such as a polyol polymethacrylate, e.g. glycol dimethacrylate, or the analogous diacrylate, or mixtures of two or more such monomers.
Type:
Grant
Filed:
May 31, 1977
Date of Patent:
July 11, 1978
Assignee:
Rohm and Haas Company
Inventors:
William D. Emmons, Peter R. Sperry, Kayson Nyi
Abstract: An aqueous siloxane-in-water emulsion containing (A) a polydiorganosiloxane having terminal --OX radicals in which X is hydrogen, alkyl or alkoxyalkyl, and at least two amino-containing substituents per molecule, (B) a siloxane containing silicon-hydrogen groups, (C) one or more nonionic and/or cationic emulsifying agents and (D) magnesium sulphate or sodium sulphate. The compositions can be applied to keratinous fibres by an exhaustion technique to render the fibres resistant to shrinkage during laundering.
Abstract: Aqueous solutions of polymers are rendered thixotropic by addition of a dispersion in aliphatic hydrocarbon of quaternary ammonium modified smectite clay, monohydric alcohol, and cationic surfactant. Conventional soluble film forming polymers include polyvinyl alcohol, polyvinyl acetate, amine neutralized polyester, and acrylic and methacrylic acid copolymers. Also silica flatting agent, flow control agent, pigment, wax and aminoplast cross-linker can be added.
Abstract: A photocurable electroconductive coating composition adapted to be crosslinked and insolubilized by actinic radiation comprises an acrylic monomer, a photoactivatable free radical polymerization initiator and a salt of a copolymerizable organic compound, wherein at least one of the monomers contains more than one polymerizable ethylenically unsaturated group. The cured coatings are insoluble in aqueous and organic solvents and are conductors of electricity suitable for conductive underlayers of photoconductive imaging elements and as antistatic coatings.
Type:
Grant
Filed:
May 2, 1974
Date of Patent:
June 27, 1978
Assignee:
National Starch and Chemical Corporation
Inventors:
Stephen D. Pastor, Martin M. Skoultchi, Henry R. Hernandez
Abstract: Actinic radiation curable compositions comprise chemically bonded portions of at least one free radical polymerizable hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, at least one non-halogenated cyclic anhydride, at least one epoxide and a halogenated free radical initiator which is activatable by actinic radiation. Upon exposure to actinic radiation, these compositions are cured with very little or no inhibition by atmospheric oxygen.
Type:
Grant
Filed:
June 19, 1975
Date of Patent:
June 27, 1978
Assignee:
National Starch and Chemical Corporation
Inventors:
Stephen D. Pastor, Martin M. Skoultchi, Henry R. Hernandez
Abstract: A condensation product of a polyepoxide with a monoalcohol or monocarboxylic acid is reacted with a monoisocyanatoallyl or methallyl carbamate to form a novel compound which can be mixed with a vinyl monomer to form a radiation hardenable lacquer composition.
Abstract: An acrylonitrile-butadiene-styrene terpolymer is added to a phenol formaldehyde novolak to produce a mixture which materially increases the resistance to peelback as compared to the phenol formaldehyde novolak alone when used as a shell process foundry resin.
Type:
Grant
Filed:
November 25, 1975
Date of Patent:
June 13, 1978
Assignee:
Schenectady Chemicals, Inc.
Inventors:
Lewis H. Bowers, Raymond E. Jankowski, John L. Sullivan
Abstract: A photopolymerizable composition comprises a polymerizable ethylenically unsaturated material, a photosensitizer ##STR1## which is preferably a diketone, e.g. benzil, and a N-alkyl or N-cycloalkylmorpholine.
Abstract: Curable coating compositions particularly suitable as a vehicle for printing inks, comprising a resin obtained by esterifying with acrylic or methacrylic acid a hydroxyl group-containing resin prepared either by reacting ingredients (A) and (B) to form a reaction mixture which is then reacted with ingredient (C) or by reacting the ingredients (A), (B) and (C). The ingredient (A) is a five-membered cyclic compound having conjugated double bonds or a Diels-Alder's reaction product thereof, the ingredient (B) a compound having both a polymerizable double bond and a hydroxyl group in the molecule and (C) a resol type phenolic resin.
Abstract: An electrical conductor insulated with flame-resistant polyolefin compositions comprising the combination of phosphorylated novolak-type phenol-formaldehyde condensate and triallyl cyanurate, and method of producing same.
Type:
Grant
Filed:
December 8, 1975
Date of Patent:
April 18, 1978
Assignee:
General Electric Company
Inventors:
Burton Thornley MacKenzie, Jr., Edward Vincent Wilkus
Abstract: Novel amides, preferably having a molecular weight in the range 1000 to 10,000, are prepared by acylating, partially or fully, amino groups in poly(ethylene imine) or poly(propylene imine) whereby amino-hydrogen atoms are replaced by groups R.sup.3 CH.dbd.CR.sup.2 CO--, where R.sup.3 denotes an aliphatic, cycloaliphatic, araliphatic, or heterocyclic group containing ethylenic unsaturation in conjugation with the indicated double bond and R.sup.2 denotes a hydrogen, chlorine, or bromine atom, a cyano group, or an alkyl group. Particularly preferred are such amides where R.sup.3 CH.dbd.CR.sup.2 CO-- denotes a sorbyl group and containing additional intramolecular linkages introduced by a difunctional reagent capable of reacting with aliphatic amino groups, such as a diepoxide or a di-isocyanate.The amides may be polymerized by means of actinic radiation and are useful in the preparation of printing plates and printed circuits.
Abstract: A polyurethane composition is produced by mixing (a) 100 parts by weight of prepolymer having terminal isocyanate groups and having a number average molecular weight in the range of from 800 to 20,000, (b) 5 - 30 parts by weight of a radical polymerizable vinyl compound, and (c) 0.05 - 1.0 part by weight of a radical initiator, adding (d) a curative selected from the group consisting of polyamine and polyol, and curing the resulting mixture by heating at 70 - 140.degree. C, the equivalent ratio of the active hydrogen of (d) to the isocyanate groups of (a) being in the range of from 0.8 to 1.2.
Abstract: Unsaturated resin compositions, which are curable at elevated temperatures to temperatures below 0.degree. C and which contain a hydroperoxide as the catalyst and a soluble organic vanadium compound as a cure promoter or accelerator, are retarded against gelation without inhibiting the cure by the addition of a ketone peroxide.
Abstract: B-stage polyurethanes comprising the reaction product of at least one hydroxyl-containing ester having a terminal acrylyl or alpha-substituted acrylyl group, an organic diisocyanate and a polyester polyol, are cured by ionizing radiation or actinic light to provide hard, thermoset polyurethanes. The composition may include one or more copolymerizable ethylenic monomers. The method is useful to provide films, coatings and impregnated materials of highly desirable properties.
Abstract: An aqueous based slurry is disclosed containing an aqueous carrier fluid, a chelating agent, an epoxy resin, a curing agent for the resin, a solvent for said resin and curing agent, a finely divided particulate material, a quaternary ammonium halide, and a coupling agent to promote bonding of the resin to the particulate. Optionally, the slurry may contain a thickening or gelling agent for the water to enhance its solids carrying capacity and an agent to break the gel after its purpose has been served. The slurry, suitable for use in placing a permeable, consolidated gravel pack adjacent an incompetent subterranean formation, is characterized in that it does not require an oil-based carrier and also in that it can easily be prepared in the field by adding the particulate directly to the aqueous carrier without precoating the particulate with the resin.
Abstract: An aromatic polyester of an aromatic dicarboxylic acid and halogenated bisphenol having a glass transition point above about 175.degree. C is employed as a non-blooming fire retardant additive for polymer compositions.
Abstract: Shaped articles comprised of PVA and PVC having improved flame-retardancy and resistance to discoloration resulting from heat treatment are provided by the incorporation therein of calcined stannic acid, characterized by a specific crystal size.
Abstract: A water-borne thermosetting coating composition comprising a stable dispersion or solution of:(A) a polymer containing randomly distributed epoxy groups reacted with(B) a tertiary amine; and(C) a nitrogen resinIs provided. Such composition is useful for spray-, flow-, dip-, roller-, and electro-coating metal and paper substrates and provides coatings of improved properties, including high degree of flexibility during machining and stamping of the coated articles, corrosion resistance, gloss, hydrolytic stability, and non-adulterating of foods and beverages in contact therewith.