Patents Examined by Nhat D. Phan
  • Patent number: 5585319
    Abstract: A process for preparing an oil sorbent excellent in oil sorptivity and water repellency and a device preparing the same are disclosed. The process for preparing an oil sorbent comprises mechanically fibrillating, or shredding and grinding lignocellulose material while substantially maintaining cell structure; and heating the resultant at a temperature of 250 to 450.degree. C. or 350 to 400.degree. C. for a predetermined period of time; followed by predetermined cooling to form an oil sorbent. The device for continuously preparing an oil sorbent having such a basic structure that three pipes with a "ellipse-shaped" cross-section each of which includes therein a screw type transferring means are arranged on top of one another, and the heating and the cooling are effected externally.
    Type: Grant
    Filed: February 8, 1994
    Date of Patent: December 17, 1996
    Assignee: Hokkaido
    Inventors: Masaru Saitoh, Katsuo Umehara, Nobuya Minemura, Fumito Nakamura, Yukihiro Kato, Hiromu Endoh
  • Patent number: 5535469
    Abstract: An improved abrasive pellet for use in abrading fabrics during a wash cycle. A pellet is formed of a mixture of plastic resin, plasticizer resin and abrasive filler mixed at temperature sufficient to maintain the mixture as a liquid. The mixture is then extruded through a die of a desired shape and cut so that a pellet of desired cross-sectional shape and size is formed. The pellet is hard at room temperature, but becomes pliant at normal wash water temperatures. The abrasive filler provides the desired abrasive qualities in the pellet.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: July 16, 1996
    Inventor: Raymond Terry
  • Patent number: 5525322
    Abstract: Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.
    Type: Grant
    Filed: October 12, 1994
    Date of Patent: June 11, 1996
    Assignee: The Regents of the University of California
    Inventor: R. Scott Willms
  • Patent number: 5523512
    Abstract: Complexing reagents are provided which comprise Cu(I) carboxylates or Cu(I) sulfonates and high molecular weight olefins. The invention complexing reagents are useful for separating olefins from mixtures of olefins and paraffins.
    Type: Grant
    Filed: June 24, 1993
    Date of Patent: June 4, 1996
    Assignee: Phillips Petroleum Company
    Inventors: Ted H. Cymbaluk, Gerhard P. Nowack, Marvin M. Johnson
  • Patent number: 5510562
    Abstract: A processing cycle for separating C.sub.8 aromatics (mixtures of ortho-, para-, meta-xylene and ethylbenzene) is disclosed, in which a first subdivision of the mixture is preformed into two streams respectively comprising: para-xylene and ethylbenzene as the first stream; and meta- and ortho-xylene as the second stream followed by a separation of the first stream by rectification, during which ethylbenzene within specifications is obtained as the overhead fraction, with the second stream also being sent to a separation by rectification, with ortho-xylene within specifications being obtained as the bottom fraction. The possible content of C.sub.9 species can be furthermore removed by subsequent distillation.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: April 23, 1996
    Assignee: Enichem S.p.A.
    Inventors: Giancarlo Paret, Renato Paludetto
  • Patent number: 5510567
    Abstract: A method of separating a mixture of gases by the following stages:a) absorbing a part G2 of a gas mixture G1 by a solvent L1 in an absorption zone C1;b) expanding the solvent L1, leading to partial vaporization of the absorbed gases G2 and cooling of the solvent L1;c) desorbing the gas fraction G2 in a desorption apparatus D1 having a reboiling zone B1 and an internal heat exchange zone Z1, wherein the solvent L1 from stage (b) is circulated in countercurrent contact with the vapor phase, and simultaneously has counter-current heat exchange with the solvent phase from the reboiling zone B1;d) passing the regenerated solvent leaving the reboiling zone B1 into the heat exchange zone Z1, and transferring the regenerated solvent to the top of said internal heat exchange zone; ande) recycling the regenerated solvent to the absorption zone C1.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: April 23, 1996
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Lermite, Joseph Larue, Alexandre Rojey
  • Patent number: 5492881
    Abstract: The present invention provides a sorbent with a high pickup ratio (>30 to 1) that has environmental benefits relating to renewable resource use of waste material as primary ingredients and is biodegradable; that is suitable for use on water and on land in a wide variety of forms; that is fire retardant; that incorporates a manufacturing process resulting in a finished product of low embodied energy; and results in a sorbent that is uncommonly simple, inexpensive, and effective. The improved sorbent also provides three options for disposal when the sorbent is full of oil. The first option allows extraction of absorbed oil by simple compression that results in a 70% recovery of oil without contamination by water. The used sorbent can be reused repeatedly afterward. A second option allows a used sorbent that, although flame resistant in its unused state, can be burned as fuel to recover 100% of energy with the sorbent contributing only 1% ash.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: February 20, 1996
    Inventor: Charles M. Diamond
  • Patent number: 5484580
    Abstract: A sorbent capable of removing trace amounts of oxygen (ppt) from a gas stream at a high temperature above 200.degree. C. comprising a porous alumina silicate support such as zeolite containing from 1 to 10 percent by weight of ion exchanged transition metal such as copper or cobalt ions and 0.05 to 1.0 percent by weight of an activator selected from a platinum group metal such as platinum. The activation temperature, oxygen sorption and reducibility are all improved by the presence of the platinum activator.
    Type: Grant
    Filed: January 19, 1994
    Date of Patent: January 16, 1996
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Pramod K. Sharma
  • Patent number: 5482906
    Abstract: An adsorption material and process for producing the same is disclosed, comprising milled activated carbon fiber and together by fibrils of a polytetrafluoroethylene resin. The adsorption material has high tensile strength and elongation and good softness. Furthermore, the adsorption material has high adsorptivity, high packing density and good gas permeability.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: January 9, 1996
    Assignee: Toho Tayon Co., Ltd.
    Inventors: Naoki Sakai, Tetsuro Shigei, Takayuki Tanaka
  • Patent number: 5481059
    Abstract: A method for accelerating the settling of finely divided solids in hydrocarbon fluids comprising adding to the hydrocarbon a sufficient settling amount of a polyacrylic acid adducted alkylphenol-formaldehyde resin alkoxylate compound. Preferably, the hydrocarbon is a fluid catalytic cracker slurry containing spent catalyst fines.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: January 2, 1996
    Assignee: Betz Laboratories, Inc.
    Inventors: Gene F. Brock, Mark S. Binford, Paul R. Hart
  • Patent number: 5481060
    Abstract: A process for the removal of trace quantities of polynuclear aromatic compounds from the vapor effluent of a hydrocarbon dehydrogenation zone containing normally gaseous olefinic hydrocarbons, trace mononuclear aromatic compounds and trace polynuclear aromatic compounds by contacting the vapor effluent of a hydrocarbon dehydrogenation zone with a lean liquid absorption stream comprising at least one mononuclear aromatic compound to absorb at least a portion of the trace mononuclear aromatic compounds and the trace polynuclear aromatic compounds to produce a rich liquid absorption stream and a gaseous olefin-containing hydrocarbon stream having a reduced concentration of mononuclear aromatic compounds and polynuclear aromatic compounds. The rich liquid absorption stream is separated to produce a stream rich in mononuclear aromatic compounds and a stream comprising polynuclear aromatic compounds.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: January 2, 1996
    Assignee: UOP
    Inventors: Norman H. Scott, Joseph E. Zimmermann, Bryan K. Glover
  • Patent number: 5476986
    Abstract: A method for cleaning a mixture of air and vapour from volatile crude oil with recovery of the hydrocarbons, wherein the vapours are absorbed in an absorption means (3) by direct contact with a petroleum distillate, such as "petroleum" which has been cooled sufficiently beforehand to cause combined cooling condensation and absorption of the hydrocarbons, the petroleum distillate having a substantially constant hydrocarbon concentration is transferred from the absorption means (3) to a buffer tank (5), from which it is conveyed either to a stripping means (4) in which the hydrocarbons dissolved in the petroleum distillate are stripped so that the petroleum distillate circulates in a substantially closed circuit, or for further processing or use. Prior to absorption under pressure in the absorption means (3) the entering mixture of air and vapour is compressed in a compressor (1) and washed with crude oil under pressure in a washing column (2).
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: December 19, 1995
    Inventor: Anker J. Jacobsen
  • Patent number: 5476987
    Abstract: A safe and reliable method of removing halogenated aromatic compounds present in small amounts in hydrocarbon oil constituted mainly by non-aromatic hydrocarbon oil. The hydrocarbon oil is contacted with a heat-resistant alkaline polar solvent in the presence of an alkaline at a temperature ranging from about 100.degree. C. to 300.degree. C., and the non-aromatic hydrocarbon oil and heat-resistant alkaline polar solvent are then separated, thereby removing the halogenated aromatic compounds from the hydrocarbon oil.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: December 19, 1995
    Assignees: Research Institute For Production Development, Mitsui & Co., Ltd.
    Inventors: Shuji Kitamura, Tsuneo Yano, Humio Tanimoto
  • Patent number: 5476985
    Abstract: An adsorptive process to separate the components of a solution of linear and branched hydrocarbons into a linear hydrocarbon portion and a branched hydrocarbon portion where the adsorbent is an alkylene-bridged polysilsesquioxane has been developed. The hydrocarbon components to be separated may be alkanes, alkenes, or alkynes, and the alkylene-bridging group of the adsorbent may contain from about 2 to about 14 carbon atoms. A specific embodiment of the invention is one where the process is operated in the simulated moving bed mode.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: December 19, 1995
    Assignee: UOP
    Inventors: James R. Lansbarkis, Timothy A. Brandvold
  • Patent number: 5476984
    Abstract: A novel, improved process and catalyst are provided for the catalytic hydrodechlorination of a chlorinated alkane to its corresponding less-chlorinated and preferably non-chlorinated alkane, for example the hydrodechlorination of 1,2-dichloropropane to propane, the catalyst comprising a mixture of active Group VIII hydrogenating metals in elemental or compound form on a support.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: December 19, 1995
    Assignee: The Dow Chemical Company
    Inventors: Mark D. Cisneros, Michael T. Holbrook, Larry N. Ito
  • Patent number: 5470814
    Abstract: The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: November 28, 1995
    Assignees: University of Delaware, E. I. Du Pont de Nemours & Co., Inc.
    Inventors: Henry C. Foley, George C. Sonnichsen, Loren D. Brake, Ravindra K. Mariwala, David S. Lafyatis
  • Patent number: 5463168
    Abstract: A process is described wherein the HCN in FCC hydrocarbon gas streams is converted to NH.sub.3 over a catalyst. This conversion has the desirable result of decreasing the amount of CN.sup.- in the water leaving the sour-water stripper, and ultimately in the refinery water effluent.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: October 31, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Costandi A. Audeh, David S. Shihabi, Richard F. Socha, Scott A. Stevenson
  • Patent number: 5463167
    Abstract: A method of removing contaminants from a hydrocarbon stream which involves contacting the hydrocarbon stream containing a heavy-metal contaminant with a porous material under conditions suitable for adsorption of the contaminant by the porous material. A process for preparing an adsorbent which involves forming a mixture of metal oxide powder and support powder, shaping the mixture into an aggregate, and reducing the aggregate to transform the metal oxide to the metallic state.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: October 31, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: John D. Y. Ou
  • Patent number: 5463154
    Abstract: A method for acetylene hydrogenation which involves adding a member selected from the group consisting of arsine and phosphine to moderate the activity of acetylene hydrogenation catalysts while maintaining acceptable catalyst activity and avoiding the risk of product quality contamination by the acetylene converter moderator. The acetylene hydrogenation process involves adding arsine at a concentration level within the range of about 1 wppb-3 wppb to the gas, such as ethylene, containing acetylene to prevent temperature runaway during the exothermic acetylene hydrogenation reaction. By controlling the presence of arsine levels to such a relatively low level, temperature runaway during the highly exothermic acetylene hydrogenation reaction is prevented while maintaining acceptable catalyst activity levels for purposes of the acetylene hydrogenation reaction.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: October 31, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David R. Slim, Edgar L. Mohundro, Stephen M. Mayo
  • Patent number: 5463155
    Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain an isoparaffin-rich product for blending into gasoline. A naphtha feedstock is subjected to ring cleavage to convert naphthenes to paraffins using a nonacidic catalyst followed by isomerization of paraffins to obtain an increased proportion of isoparaffins.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: October 31, 1995
    Assignee: UOP
    Inventors: Leonid B. Galperin, Jeffery C. Bricker, Jennifer S. Holmgren