Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula; and one or more divalent units independently represented by formula: The copolymer has an —SO2X equivalent weight in a range from 300 to 2000. A polymer electrolyte membrane that includes the copolymer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.

Abstract: The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

Abstract: The invention provides for the use of specific microemulsions comprising quaternary ammonium compounds for production of clear fabric softener formulations having improved performance properties, and also the corresponding formulations and a process for production thereof.

Abstract: The present invention is directed to partially fluorinated copolymers and the production thereof. More specifically, the copolymers, which are preferably produced by a solution polymerization process, preferably have at least three units, the first unit selected from 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene, the second unit having a polymerized monomer selected from the vinyl esters and vinyl ethers, and the third unit having a polymerized monomer derived from a hydroxyl group-containing vinyl ether. The resulting copolymer is environmentally friendly, has favorable molecular weight characteristics, and may be shipped economically in high concentration.

Abstract: A detergent composition includes a surfactant component including a linear alkylbenzene sulfonate in an amount of from about 10 to about 35 wt % actives, an alkoxylated alcohol in an amount of from about 10 to about 30 wt % actives, water in a total amount of from about 10 to about 27 wt %, sodium and/or potassium hydroxide in an amount of from about 2 to about 4 wt % actives, an acidic defoamer in an amount of from about 1 to about 10 wt % actives, and a filler in an amount of at least about 25 wt % actives. The filler includes (1) propylene glycol, (2) glycerin, and (3) high fructose corn syrup in a weight ratio of actives of about (0 to 0.5):(0 to 0.5):(0.5 to 0.95). The composition includes less than 5 wt % actives of an alcohol ethoxy sulfate and less than 0.1 wt % actives of monoethanolamine.

Abstract: The present invention relates to a primer coating composition that includes, (a) a (meth)acrylic polymer that includes hydroxyl groups, and which has a Tg of at least 30° C. The primer coating composition further includes, (b) a polyester that includes hydroxyl groups, and which has a weight average molecular weight of less than 3000, and a hydroxyl value of at least 100. The primer coating composition also includes, (c) a crosslinking agent having at least two isocyanate groups. The present invention also relates to a coated article that includes a repaired area that includes a primer coating formed from the primer coating composition of the present invention. The primer coating compositions, in accordance with some embodiments, provide reduced or minimal ringing defects.

Abstract: A coating composition comprises a functionalized epoxy resin and a fluoroalkyl-modified particle, such as activated carbon or silica. The functionalized epoxy resin is a ternary polymer composition comprising one or more epoxy resin moieties linked to a polyethylene backbone through an oxygen atom, fluoroalkyl(poly)propionyl groups being grafted to the polyethylene backbone. The coating compositions have superhydrophobic properties useful for self-cleaning surfaces and bubble release from sensors.

Abstract: A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, the polymerization agent comprising: fluoropolyether acid or salt thereof having a number average molecular weight of at least about 800 g/mol; and fluorosurfactant having the formula: [R1—On-L-A?]Y+ wherein: R1 is a linear or branched partially or fully fluorinated aliphatic group which may contain ether linkages; n is 0 or 1; L is a linear or branched alkylene group which may be nonfluorinated, partially fluorinated or fully fluorinated and which may contain ether linkages; A? is an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion, and phosphonate; and Y+ is hydrogen, ammonium or alkali metal cation; with the proviso that the chain length of R1—On-L- is not greater than 6 atoms.

Abstract: A detergent composition includes a surfactant component present in an amount of from about 5 to about 70 weight percent actives based on a total weight of the composition, water present in an amount of from about 5 to about 90 weight percent based on a total weight of the composition, polyvinyl alcohol particles present in an amount of from about 0.1 to about 5 weight percent based on a total weight of the composition, and a functional material that is encapsulated in the polyvinyl alcohol particles and is chosen from enzymes, surfactants, functional polymers, and combinations thereof and present in an amount of from about 0.05 to about 2 weight percent actives based on a total weight of the composition.

Abstract: A detergent additive comprising an active, the active comprising one or both of tetraacetylethylenediamine and triacetylethylenediamine; and polyvinyl butyral. A method of preparing a detergent additive comprising providing a solvent to a reaction mixture; providing polyvinyl butyral to the reaction mixture; providing an active to the reaction mixture, the active comprising one or both of tetraacetylethylenediamine and triacetylethylenediamine; mixing the reaction mixture; and spray-drying the reaction mixture.

Abstract: A modified polytetrafluoroethylene which can be formed under a low extrusion pressure and with which changes of the extrusion pressure are suppressed, even in paste extrusion at a high RR ratio, and its production method. The modified polytetrafluoroethylene having units based on tetrafluoroethylene, 0.020 to 0.040 mass % of units based on a monomer represented by the following formula (1), and 0.003 to 0.080 mass % of units based on a monomer represented by the following formula (2), each based on all units of the modified polytetrafluoroethylene. The monomers of formulae (1) and (2) are represented by: CH2?CH—CnF2n+1 (1), wherein n is from 2 to 6; and CF2?CFO(LO)mRf (2), wherein L is a perfluoroalkylene group, Rf is a perfluoroalkyl group, and m is an integer of from 0 to 4.

Abstract: Disclosed are latexes, suspensions, and colloids having a cationic antimicrobial compound complexed with an anionic surfactant. The surfactant may have greater affinity for the antimicrobial compound than other anionic surfactants and other anions in the latex, suspension, or colloid that contribute to disperse phase stability to prevent disrupting the dispersions. Dispersions containing the antimicrobial compound may therefore have a shelf life comparable to dispersions that are otherwise identical but lack the cationic antimicrobial compound and its complexed anionic surfactant. Coatings made with the complexes can exhibit essentially undiminished antimicrobial activity.

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain polyfunctional perfluoropolyether derivatives including a plurality of ionisable groups selected from the group consisting of —SO3Xa, —PO3Xa and —COOXa, whereas Xa is H, an ammonium group or a monovalent metal, and whereas said groups are comprised as pendant groups in the perfluoropolyether chain, and to fluoropolymer dispersions therefrom.

Abstract: The invention concerns methods for dielectrically insulating electrical active parts using certain fluorinated nitroalkanes, as well as compositions and apparatus comprising such compounds.

Abstract: A procedure for improved temperature control in controlled radical polymerization processes is disclosed. The procedure is directed at controlling the concentration of the persistent radical in ATRP and NMP polymerizations procedures and the concentration of radicals in a RAFT polymerization process by feeding a reducing agent or radical precursor continuously or intermittently to the reaction medium through one of more ports.

Abstract: The invention relates to aqueous polyurethane-vinyl polymer hybrid dispersions comprising, as building blocks hydrophobically modified hydroxy-functional polyesters A, acids B that have further groups which react with isocyanates under formation of urethanes, ureas, or thiourethanes, compounds G having only one hydroxyl group, and one or more tertiary amino groups, olefinically unsaturated monomers H2 having a polymerisable ethylenic unsaturation and a further functional group which reacts with an isocyanate group under bond formation, olefinically unsaturated monomers H1 having at least one polymerisable ethylenic unsaturation and no further functional group which reacts with an isocyanate group, and multifunctional isocyanates I having at least two isocyanate groups per molecule, to a process of their preparation, and to a method of use thereof.

Abstract: A method for producing a vinyl ether polymer containing an oxyethylene chain is provided, including a the step of polymerizing vinyl ether represented by formula (1) in the presence of water as a polymerization solvent, a basic compound as an additive, and an organic azo-based compound as a radical polymerization initiator, and in pH of 5 or more, and the amount of the basic compound used is 0.01 to 0.5 mol % based on an amount of the vinyl ether. Formula (1) is wherein R1 represents an alkyl group having 1 to 3 carbons, and n represents an integer from 1 to 10.

Abstract: A fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer and a method for producing it are provided. The fluorinated ether compound is represented by A-O—(Rf1O)m-Q1(R1)b, wherein A is a C1-20, perfluoroalkyl group, Rf1 is a perfluoroalkylene group, m is an integer of from 2 to 500, (Rf1O)m a n d may consist of two or more types of Rf1O differing in the number of carbon atoms, Q1 is a (b+1) valent perfluorohydrocarbon group which may have a hydroxy group, R1 is a monovalent organic group having at least one hydrolyzable silyl group, b is an integer of at least 2, and the b R1 may be the same or different.

Abstract: The present invention relates to a coated article comprising a partial or complete fluorinated coating on the surface of an article, wherein the coating comprises 5 to 99% by weight of a hydrophobic compound, and 1 to 95% by weight of a fluorinated surface effect agent, both based on the total solids weight of the coating, where the hydrophobic compound is selected from a hydrophobic cyclic or acyclic ester alcohol.

Abstract: An endless belt includes a substrate layer, and a first surface layer that is disposed on an outer circumferential surface of the substrate layer and that includes a cross-linked fluororesin layer. A layer containing a cross-linked fluororesin forms the inner circumferential surface of the belt. Martens hardness of the inner circumferential surface of the belt at 130° C. is higher than Martens hardness of the outer circumferential surface of the belt at 130° C.