Abstract: A semiconductor manufacturing method that includes defining a substrate, depositing a first layer over the substrate, providing a protection layer over the first layer, providing a layer of photoresist over the protection layer, patterning and defining the photoresist layer to form at least one photoresist structure having at least one substantially vertical sidewall and one substantially horizontal top, depositing a photo-insensitive material over the at least one photoresist structure and the protection layer with a chemical-vapor deposition process having at least one reactive gas, wherein an amount of the photo-insensitive material deposited on the top of the photoresist structure is substantially greater than an amount of the photo-insensitive material deposited on the at least one sidewall of the photoresist structure, and wherein the protection layer is non-reactive with the at least one reactive gas, and anisotropically etching the protection layer and the layer to be etched.