Patents Examined by P. Niland
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Patent number: 5663262Abstract: The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.Type: GrantFiled: November 8, 1989Date of Patent: September 2, 1997Assignee: Nippon Paint Co., Ltd.Inventors: Shinsuke Shirakawa, Kazunori Kanda, Mitsuo Yamada, Kei Aoki, Satoshi Urano, Nobuaki Tomita
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Patent number: 5631313Abstract: A new stable liquid suspension of a non soluble particulate material, and a method of preparation of same are provided. Such compositions comprise at least one oil, one oil soluble resin and a non oil soluble particulate material mixed together In the appropriate quantities and conditions.Type: GrantFiled: November 14, 1991Date of Patent: May 20, 1997Assignee: Phillips Petroleum CompanyInventors: Marshall D. Bishop, John E. Hostettler
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Patent number: 5521247Abstract: Aqueous coating agent including a water-dilutable mixture of binding agents ofI. 50 to 88 wt. % of a neutralised water-soluble reaction product including(A) 10 to 80 wt. % of a polyurethane resin with an acid number of 70 to 160, at least one terminal blocked isocyanate group devoid of free hydroxyl groups and fatty acid residues with more than 12 C-atoms and with a limiting viscosity number of 6.5 to 12.0 ml/g, measured in DMF at 20.degree. C., and(B) 20 to 90 wt. % of a polyester resin with an OH-number of 50 to 500, an acid number of less than 20, a limiting viscosity number of 8.0 to 13.0 ml/g, measured in DMF at 20.degree. C., with the reaction product having a limiting viscosity number of 13.5 to 18.0 ml/g measured in DMF at 20.degree. C.II. 10 to 40 wt. % of one or several blocked polyisocyanates not capable of being diluted with water, andIII. 2 to 30 wt. % of at least one amine resin by way of additional cross-linking agent.Type: GrantFiled: December 29, 1993Date of Patent: May 28, 1996Assignee: Herberts G.m.b.HInventors: Klaus Dobler, Michael Georgiadis, Wolfgang Goldner, Knut Graf
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Patent number: 5447969Abstract: A polyurethane composition excellent in chlorine resistance containing 0.1 to 10% by weight, based on the polyurethane, of hydrotalcite which has water of crystallization and a C.sub.10 -C.sub.30 fatty acid adhered thereto, capable of being stably spun over a long period of time, and exhibiting neither discoloration in the step of tannin solution treatment nor swelling during chlorine immersion treatment.Type: GrantFiled: May 21, 1993Date of Patent: September 5, 1995Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Yoshiaki Kojima, Akihiko Yoshizato
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Patent number: 5430094Abstract: A water-based vacuum forming laminating adhesive is disclosed. The adhesive includes a vinyl acetate polymer, an ionic water-dispersed polyurethane, and an aziridine. The composition is also substantially free of potentiometrically titratable acid. Also disclosed is a process for adhering a thermoplastic material to a rigid substrate. This process includes applying the above-described adhesive composition to the substrate, drying the composition, heating the thermoplastic material, contacting the thermoplastic material to the dry composition, and applying a vacuum to the thermoplastic material and the substrate for at least about; 10 seconds so as to adhere the thermoplastic material to the substrate. The composition of the present invention is particularly stable and can be used as a one component adhesive for up to 90 days.Type: GrantFiled: July 11, 1991Date of Patent: July 4, 1995Assignee: PPG Industries, Inc.Inventors: Edward F. Gola, Michael A. Misiak
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Patent number: 5407985Abstract: Stable aqueous microdispersions of finely divided polyamide resin particles and methods for the manufacture thereof are provided. The properties of these microdispersions are achieved by the addition thereto of an effective amount of a co-surfactant such as a lower alkyl alcohol. The provided microdispersions can be drawn into films which will form clear, continuous films at ambient or near-ambient temperatures regardless of the softening point of the polyamide resin. Dispersions according to this invention find use in hot melt adhesives, coatings, inks, and the like.Type: GrantFiled: March 25, 1991Date of Patent: April 18, 1995Assignee: Union Camp CorporationInventor: George A. Smith
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Patent number: 5401553Abstract: A composition for carpet backings which comprises:(a) an aqueous dispersion of a high molecular weight polymer; and(b) a blocked polyisocyanate in amounts of about 0.5-30 parts by weight in relation to 100 parts by weight of the solids of the aqueous dispersion.The composition preferably further contains a melamine resin in amounts of about 0.1-10 parts by weight, and/or a vulcanizing agent in amounts of about 0.5-10 parts by weight, each in relation to 100 parts by weight of the solids of the aqueous dispersion.The carpet having backings formed with the composition is excellent in washability so that there takes place little shrinkage and curling after repeated washing.Type: GrantFiled: November 9, 1992Date of Patent: March 28, 1995Assignee: Takeda Chemical Industries, Ltd.Inventors: Masahiro Miwa, Yoshio Kamatani
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Patent number: 5399599Abstract: Thermoplastic elastomeric ablative insulation having good mechanical properties at extremely low temperatures are disclosed. The insulation is based upon a polyamide-ether resin and includes carefully selected fillers to possess good low temperature mechanical properties and still provide suitable charring and ablative insulation performance at low temperatures (-65.degree. F.). A typical insulation within the scope of the present invention includes a polyamide-ether thermoplastic elastomeric polymer resin, an inorganic phosphorus containing compound, such as ammonium polyphosphate, present in the insulation from about 5 to about 60 phr, and a polyhydric alcohol present, such as pentaerythritol, in the insulation from about 1 to about 30 phr. The insulation compositions within the scope of the present invention optionally include silicone resin present in the insulation in range from about 0 to 15 phr. Chopped fiber filler may also be present in the insulation in range from about 0 to 100 phr.Type: GrantFiled: April 6, 1993Date of Patent: March 21, 1995Assignee: Thiokol CorporationInventor: David G. Guillot
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Patent number: 5391343Abstract: Certain polyether-based or polyester-based polyurethaneureas in solutions of organic solvent at a 12 to 20% concentration are particularly suited for use in a mandrel-dipping process for producing thin-walled elastic articles, such as surgical gloves, which are more resistant to puncture and tear than conventional surgical gloves made from rubber latex.Type: GrantFiled: October 26, 1992Date of Patent: February 21, 1995Assignee: E. I. du Pont de Nemours and CompanyInventors: Richard L. Dreibelbis, Nathan E. Houser, Jacob Lahijani
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Patent number: 5369155Abstract: A composite of a gel of swollen hydrocolloid dispersed in a pressure sensitive adhesive matrix is provided. The gel has a natural or synthetically derived hydrocolloid swollen with a non-volatile swelling agent, such that the gel may have a shear modulus of less than 6.2.times.10.sub.6 dynes/cm.sup.2 The gel-adhesive composite has continued skin adhesion whether applied to or existing in dry or moist skin conditions. The gel contributes a high moisture vapor transmission rate to attempt to maintain dry skin conditions while the adhesive maintains skin adhesion. The gel-adhesive composite may be used in a variety of tape, dressing, bandage, drape, or other skin contacting usage and may optionally include antimicrobial agents to treat the skin while adhesion continues.Type: GrantFiled: July 1, 1993Date of Patent: November 29, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventor: Robert A. Asmus
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Patent number: 5367017Abstract: The present invention is directed to a aqueous polyurea dispersion for the preparation of an aqueous polyurea dispersion byI) dispersing in water at an NCO:NH equivalent ratio of 0.5:1.0 to 2.0:1.0a) a polyisocyanate which has an average functionality of 1.5 to 4.0 and an isocyanate content of at least 12% by weight andb) a polyamine component containingi) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups and a molecular weight of at least 1000 andii) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups, a molecular weight of less than 400 and at least one anionic or potential anionic group andII) allowing the polyisocyanate and polyamine component to react to form an aqueous polyurea dispersion.The present invention is also directed to the aqueous polyurea dispersion prepared by this aqueous polyurea dispersion.Type: GrantFiled: May 1, 1992Date of Patent: November 22, 1994Assignee: Miles Inc.Inventors: James W. Rosthauser, Robin E. Tirpak
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Patent number: 5358997Abstract: The present invention is directed to a process for the preparation of an aqueous polyurea dispersion containing blocked isocyanate groups and unreacted isocyanate-reactive groups by(I) dispersing in watera) a polyisocyanateb) a monofunctional blocking agent which is more reactive with isocyanate groups than water andc) an amine componentII) reacting the polyisocyanate with components b) and c) to form an aqueous polyurea dispersion.Type: GrantFiled: May 7, 1992Date of Patent: October 25, 1994Assignee: Miles Inc.Inventors: James W. Rosthauser, Robin E. Tirpak
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Patent number: 5354834Abstract: A curing agent for a two-component type polyurethane, containing as a main constituent a polyisocyanate derived from hexamethylene diisocyanate, the polyisocyanate having a viscosity of lower than 1,400 mP.a/25.degree. C. in substantially free from monomeric hexamethylene diisocyanate and a solvent, having a uretidine dione dimer content of more than 10%, and having an isocyanurate cyclic trimer content of less than 60%.Type: GrantFiled: January 10, 1992Date of Patent: October 11, 1994Assignee: Nippon Polyurethane Industry Co., Ltd.Inventors: Mitsuhiro Yoshida, Susumu Sato, Yukio Obuchi, Shin Konishi, Masanori Shindo
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Patent number: 5346947Abstract: The binder composition of this invention contains a beta-hydroxy urethane functional material and a polycarboxylic acid. Coated glass fibers are prepared by contacting said fibers with the binder composition of the invention and thereafter curing the composition. This invention is also an improved method of treating glass fibers by contacting them with the improved binder composition of the invention.Type: GrantFiled: February 6, 1992Date of Patent: September 13, 1994Assignee: Cytec Technology Corp.Inventors: Gerald J. Guerro, William Arthur, Balwant Singh
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Patent number: 5344873Abstract: The present invention relates to an aqueous binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containingA1) at least one water-dilutable polyester resin containing sulfonate and hydroxyl groups and having a molecular weight (M.sub.n) of 500 to 50,000, an OH number of 20 to 240 mg KOH/g, a content of sulfonate groups (--SO.sub.3.sup.-) of 4 to 70 milliequivalents per 100 g of polyester resin and a content of carboxylate groups (--COO.sup.-) of 0 to 40 milliequivalents per 100 g of polyester resin andA2) optionally a reactive thinner containing at least one water-soluble monohydric or polyhydric alcohol which has a molecular weight (M.sub.n) below 500 and which is non-distillable at normal pressure or has a boiling point of at least 150.degree. C., andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.Type: GrantFiled: October 8, 1992Date of Patent: September 6, 1994Assignee: Bayer AktiengesellschaftInventor: Harald Blum
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Patent number: 5336702Abstract: An aqueous resin dispersion containing as an aqueous resin component a polyurethane-modified epoxy-polyamine resin comprising a reaction product of an epoxy group-containing polyurethane compound obtained by the reaction of a polyhydroxy compound having a number average molecular weight of 50 to 8,000, a polyisocyanate compound, and a compound containing one hydroxyl group and at least one alicyclic epoxy group in a molecule; a bisphenol compound; a bisphenol diglycidyl ether compound; and an active hydrogen-containing amine compound. Said aqueous resin dispersion has excellent corrosion resistance and is suited especially for cathode electro-deposition coating.Type: GrantFiled: December 3, 1992Date of Patent: August 9, 1994Assignee: Kansai Paint Co., Ltd.Inventor: Koji Kamikado
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Patent number: 5334637Abstract: The present invention relates to isocyanatocarboxylic acids containinga) 1 to 30% by weight of isocyanate groups attached to (cyclo)aliphatic tertiary carbon atoms andb) 0.5 to 500 milliequivalents, per 100 g of isocyanatocarboxylic acids, of carboxyl groups which may be at least partially present in carboxylate salt form.The present invention also relates to a process for the preparation of these isocyanatocarboxylic acids and to their use as cross-linking agents for aqueous coating compositions.Type: GrantFiled: December 10, 1992Date of Patent: August 2, 1994Assignee: Bayer AktiengesellschaftInventors: Christian Zwiener, Rainer Rettig, Klaus Nachtkamp, Josef Pedain, Dieter Arlt
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Patent number: 5334650Abstract: A coating composition is disclosed comprising:(a) an aqueous medium,(b) a water-dispersible polyurethane resin that is the reaction product of a mixture comprising:(1) a long-chain aliphatic polyol having 18 to 60 carbon atoms,(2) a multifunctional compound having at least one active hydrogen group and at least one water-stabilizing group,(3) an active hydrogen-containing capping and/or chain extending agent, and(4) a polyisocyanate, and(c) an aminoplast crosslinking agent.Type: GrantFiled: September 29, 1992Date of Patent: August 2, 1994Assignee: BASF CorporationInventors: Paul Serdiuk, Alan L. Steinmetz
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Patent number: 5330846Abstract: Heat-curable, aqueous synthetic resin mixtures for coating woodworking materials, based on etherified melamine/formaldehyde condensates and aqueous synthetic resin dispersions, a process for the preparation of these mixtures and their use for coating woodworking materials.Type: GrantFiled: September 13, 1991Date of Patent: July 19, 1994Assignee: BASF AktiengesellschaftInventors: Wolfgang Eisele, Hans Etling, Walter Pfalzgraf, Walter Pitteroff, Otto Wittmann
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Patent number: 5328179Abstract: Gasketing paper is commonly made by the beater addition process. In the beater addition process a furnish composition is prepared by mixing latex into a fiber slurry which also typically contains one or more fillers. The beater addition process is currently being scrutinized because of environmental concerns. More specifically, conventional lattices used in the beater addition process contain curatives, such as amines, sulfur, and zinc compounds, which are discharged into the environment via the affluent from the process. By practicing the process of this invention gasketing paper can be manufactured by an environmentally sound technique. In one embodiment of this invention gasketing paper is made by beater addition with the latex utilized in the process being comprised of (a) at least one rubber having both pendant blocked isocyanate groups and groups containing at least one active Zerewitinoff hydrogen, (b) at least one emulsifier, and (c) water.Type: GrantFiled: November 4, 1991Date of Patent: July 12, 1994Assignee: The Goodyear Tire & Rubber CompanyInventors: Joel Muse, Dane K. Parker, Robert F. Roberts