Patents Examined by Patrick Niland
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Patent number: 8652568Abstract: The instant invention is a coating system, a coating composition, a coating layer, a coated substrate, a method for producing a coating composition, a method for forming a coating layer, a method for making a coated substrate, and a method for healing a coated substrate. The coating system according to the present invention comprises (a) one or more natural oil derived polyols having an average of 3 or more hydroxyl groups per molecule, a number average molecular weight in the range of 300 to 3000 Daltons, a Tg in the range of from less than 0° C.; and (b) one or more polyisocyanates.Type: GrantFiled: September 7, 2011Date of Patent: February 18, 2014Assignee: Dow Global Technologies LLCInventors: Sudhakar Balijepalli, Ray E. Drumright, Sarah T. Eckersley, Brad E. Elwood, Paul Foley, Yanziang Li, Kumar Nanjundiah
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Patent number: 8653213Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.Type: GrantFiled: August 16, 2011Date of Patent: February 18, 2014Assignee: Cytonix, LLCInventor: James F Brown
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Patent number: 8653180Abstract: The present invention provides compositions that enable excellent early hardness development in coating applications, the compositions comprising a blend of one or more copolymer, pA, having a Tg of 20° C. or higher, and one or more polyurethane copolymer in aqueous dispersion, pB, together with one or more additive chosen from a coalescent having a normal boiling point of from 150° C. to no greater than 300° C., a naturally derived plasticizer, and mixtures thereof. The polyurethane copolymer comprises at least 40 wt. %, based on the weight of polyurethane solids, of: (i) a first polyol having a molecular weight of at least 850, wherein the first polyol is a polyether polyol, or (ii) a second polyol chosen from a polyester, a polycaprolactam, a polycarbonate and a combination thereof, wherein the second polyol has a molecular weight of at least 1,500, or (iii) a combination of one or more first polyol and one or more second polyol. The compositions may be ambient curable.Type: GrantFiled: June 5, 2009Date of Patent: February 18, 2014Assignee: Rohm and Haas CompanyInventors: Zhenwen Fu, Andrew Hejl, Aurelia C. Sheppard, Andrew J. Swartz
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Patent number: 8628852Abstract: Disclosed are core-shell resin particles (C2) each comprising one or more film-like shell layers (P) comprising a resin (a) which is a polyurethane resin and a core layer (Q) comprising a resin (b). A core-shell resin particle (C2) is characterized in that the weight ratio between (P) and (Q) is from 0.1:99.9 to 70:30, the volatile content in the resin particle (C2) is not more than 2 weight %, and the content of vinyl resins in the resin (b) is not more than 30 weight %. Such resin particles have a uniform particle diameter and are excellent in electrostatic properties, thermal and storage stability and thermal characteristics.Type: GrantFiled: July 27, 2006Date of Patent: January 14, 2014Assignee: Sanyo Chemical Industries Ltd.Inventors: Takashi Akutagawa, Tsuyoshi Izumi
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Patent number: 8629198Abstract: Disclosed is a non-aqueous inkjet ink that includes a polyvinyl chloride resin synthesized by a suspension polymerization method or an emulsion polymerization method; an organic solvent that is a mixed solvent comprising diethylene glycol ethyl methyl ether, diethylene glycol diethyl ether, and diethylene glycol monoethyl ether in which the polyvinyl chloride resin is dissolved; a pigment; and a radical polymerization inhibitor. In another embodiment, the mixed solvent includes N-methyl-2-pyrrolidone, diethylene glycol diethyl ether, and diethylene glycol monoethyl ether. The radical polymerization inhibitor prevents the polyvinyl chloride resin from gelling in a short period and causing a discharge fault, clogging, etc. Also disclosed is an ink set of inkjet inks includes a combination of the non-aqueous inkjet inks above having respective colors and including at least a cyan ink; a magenta ink; a yellow ink; and a black ink.Type: GrantFiled: February 1, 2011Date of Patent: January 14, 2014Assignee: General Technology Co., Ltd.Inventors: Kozo Isobe, Kengo Nagae
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Patent number: 8623950Abstract: The present invention relates to a preparation method of polyurethaneurea elastic fiber, particularly a preparation method of high heat-resistant elastic fiber which retains unique physical properties of elastic fiber under the high temperature process. The polyurethaneurea elastic fiber of the present invention is characteristically prepared without using 1 functional mono-alcohol generally used to regulate the reaction speed and side-reaction during the prepolymer reaction to produce elastic fiber having excellent heat-resistance particularly for the dyeing processing or re-dyeing of polyester but using ethylenediamine alone as a chain extender for the polymerization. To reduce gel formation in polymer after the secondary polymerization and to regulate change of viscosity in the course of process, the ratio of the chain extender amine to the terminal group of prepolymer of the first polymerization is increased.Type: GrantFiled: December 1, 2008Date of Patent: January 7, 2014Assignee: Tae Kwang Ind. Co., Ltd.Inventors: Ickgy Shin, Inrak Jung, Haedong Kim
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Patent number: 8623938Abstract: An inkjet ink includes carbon nanotubes, flake graphites, an organic carrier, a binder, a surfactant, a film enhancer and a solvent. A method for making an inkjet ink includes dispersing the plurality of carbon nanotubes in the surfactant solvent to form a first mixture, dispersing the plurality of flake graphites in the organic carrier solvent to form a second mixture, adding the film enhancer into the second mixture to form a third mixture, and mixing the first mixture and the third mixture.Type: GrantFiled: September 2, 2011Date of Patent: January 7, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Hai-Yan Hao, Bing-Chu Du, Chun-Hai Zhang, Shou-Shan Fan
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Patent number: 8618190Abstract: A latex marking ink suitable for marking rubber articles has been developed. The ink comprises vulcanizable rubber latex, pigment, vulcanizing agent, and non-ionic stabilizer dispersed in water. Shear stability is dramatically and unexpectedly increased by the presence of the non-ionic stabilizer even though viscosity also increases.Type: GrantFiled: February 3, 2011Date of Patent: December 31, 2013Assignee: PolyOne CorporationInventors: Heather E. Burik, Steve White
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Patent number: 8569398Abstract: A fully curable jettable composition having a viscosity less than 30 cps at a temperature within the range of 15° C.-180° C. comprising (i) at least one low viscosity reactive resin; (ii) at least one higher viscosity resin having a viscosity greater than twice that of the low viscosity resin and a functionality of greater than or equal to 2; (iii) at least one curable toughener, (iv) at least one initiator for the polymerization of the resins, and (v) at least one stabilizer for delaying the curing of the resins of the composition. The composition can be jetted from piezo electric printing heads under the control of a computer program to form a multi-layered article, for example, a three dimensional article, in which the adjacent droplets merge and are cured homogeneously together.Type: GrantFiled: December 9, 2010Date of Patent: October 29, 2013Assignee: 3D Systems, Inc.Inventors: Ranjana C. Patel, Yong Zhao, Richard John Peace
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Patent number: 8556405Abstract: There is provided an ink for recording, which contains: a coloring agent; a water-dispersible resin; a wetting agent; a surfactant; and water, wherein a total solid content of the coloring agent and the water-dispersible resin is 10% by mass to 30% with respect to a total mass of the ink, a ratio B/C is 0.1 to 1.6 where B is a solid content of the coloring agent in the ink, and C is a solid content of the water-dispersible resin in the ink, a viscosity of the ink is 5 mPa·s to 20 mPa·s at 25° C., and a surface tension of the ink is 35 mN/m or less.Type: GrantFiled: August 22, 2011Date of Patent: October 15, 2013Assignee: Ricoh Company, Ltd.Inventors: Hisashi Habashi, Michihiko Namba, Mariko Kojima, Akihiko Gotoh, Tamotsu Aruga, Kiyofumi Nagai
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Patent number: 8552089Abstract: There is provided an ink composition for forming a light shielding film in an organic semiconductor device which is capable of stably forming a fine pattern when forming a finely patterned light shielding film by the letterpress reverse printing method or microcontact printing method, which can be baked at a temperature equal to or less than the substrate heatproof temperature, and which is also capable of providing light shielding property and mechanical strength, the ink composition for forming a light shielding film in an organic semiconductor device which is an ink composition for forming a light shielding film in an organic semiconductor device comprising a black pigment; a resin component; a surface energy modifier; a quick-drying organic solvent; a slow-drying organic solvent; and a mold releasing agent, wherein the resin component comprises a solid resin that is in a solid state at 200° C. or less and a liquid resin that is in a liquid state at 10 to 50° C. at a ratio (solid resin/liquid resin) of 0.Type: GrantFiled: April 26, 2010Date of Patent: October 8, 2013Assignee: DIC CorporationInventors: Hideki Etori, Hiroshi Isozumi, Masanori Kasai
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Patent number: 8552109Abstract: Disclosed is an aqueous polyurethane resin dispersion which comprises a polyurethane resin which is obtained by reacting (A) a polyurethane prepolymer obtained by reacting (a) a polycarbonate polyol having an alicyclic structure in the main chain, (b) an acidic group-containing polyol compound and (d) a polyisocyanate, and (B) a chain-elongating agent, being dispersed in an aqueous medium, a carboxylic acid group content of the above-mentioned (A) polyurethane prepolymer based on a solid component of (A) the polyurethane prepolymer is 2.0 to 13.0% by weight, and a number of a hydroxyl equivalent of a mixture of the above-mentioned (a) polycarbonate polyol having an alicyclic structure in the main chain, the above-mentioned (b) acidic group-containing polyol compound, and, if necessary, (c) a polyol other than (a) and (b) is 70 to 270.Type: GrantFiled: May 28, 2009Date of Patent: October 8, 2013Assignee: Ube Industries, Ltd.Inventors: Taku Nakamura, Masahiro Naiki, Atsushi Morikami, Fumio Adachi, Manabu Takahashi
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Patent number: 8536246Abstract: The present invention provides an inkjet ink composition including color material particles, a water soluble polymerizable compound, a water soluble silicate salt and water, which is excellent in ejection stability even in a case in which the ink composition is stopped from ejecting in the inkjet recording device and left alone for a certain period of time, and ejection of the ink composition is resumed thereafter, which has a good maintenance property, and in which abrasion resistance of images formed with the ink composition is excellent; an ink set including the inkjet ink composition; and an image forming method using the ink set.Type: GrantFiled: December 20, 2010Date of Patent: September 17, 2013Assignee: FUJIFILM CorporationInventors: Jun Matsumoto, Masao Ikoshi
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Patent number: 8530544Abstract: The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C?C—C?O and/or an a,b-unsaturated thiocarbonyl group C?C—C?S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N?C?O or thioisocyanate —N?C?S groups, and trivalent groups of formula >C?CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.Type: GrantFiled: March 27, 2009Date of Patent: September 10, 2013Assignee: PolyriseInventors: Vincent Gaud, Fabien Rouge
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Patent number: 8524801Abstract: The first invention relates to a water-based ink for ink-jet printing which includes colorant-containing polymer particles (A) obtained by dispersing a colorant with a water-soluble polymer (x) and a water-insoluble polymer (y), a water-soluble organic solvent (B) and water, wherein a weight ratio of the water-insoluble polymer (y) to the water-soluble polymer (x) [(y)/(x)] is from 2.0 to 5.0, and a content of the water-soluble organic solvent (B) in the ink is from 10 to 70% by weight. The water-based ink for ink-jet printing according to the first invention is excellent in ejection property and optical density and exhibits a low viscosity.Type: GrantFiled: December 17, 2009Date of Patent: September 3, 2013Assignee: Kao CorporationInventors: Hiroyuki Yoshida, Tsuyoshi Oda, Takahiro Sato, Yusuke Shimizu, Koji Kamei, Toshiya Iwasaki
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Patent number: 8513332Abstract: Disclosed is a color filter ink composition that includes an acrylic-based copolymer resin including repeating units represented by a particular chemical formula, a polymerizable monomer, a pigment, and a solvent. According to the present invention, the color filter ink composition can have excellent ejection properties and ejection stability by using a new acrylic-based copolymer resin as a binder resin, and also can have excellent storage stability, so that it can be used for a long period. In addition, a pattern formed using the color filter ink composition can have improved heat resistance, chemical resistance, and film strength.Type: GrantFiled: April 16, 2010Date of Patent: August 20, 2013Assignee: Cheil Industries Inc.Inventors: Jong-Seung Park, In-Jae Lee, Jin-Ki Hong, Seung-Joo Shin, Sung-Woong Kim, Tae-Woon Cha
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Patent number: 8513334Abstract: The present invention relates to aqueous polyurethane urea dispersions having integral functional groups and coating agents produced therefrom, to a method for the production thereof, and to the use thereof for producing coating agents.Type: GrantFiled: February 10, 2010Date of Patent: August 20, 2013Assignee: Bayer Materialscience AGInventors: Hans Georg Grablowitz, Thomas Feller, Thomas Michaelis
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Patent number: 8507585Abstract: A non-aqueous pigment ink comprising a pigment, a non-aqueous solvent, and non-aqueous resin dispersion microparticles having a pigment dispersion capability, wherein the non-aqueous resin dispersion microparticles are an acrylic polymer comprising an alkyl (meth)acrylate unit having an alkyl group of 12 or more carbon atoms and a (meth)acrylate unit having a urethane group. The acrylic polymer is a copolymer of a monomer mixture comprising an alkyl (meth)acrylate (A) having an alkyl group of 12 or more carbon atoms and a reactive (meth)acrylate (B) having a functional group capable of reacting with an amino group, wherein the urethane group is introduced by a reaction between the functional group capable of reacting with an amino group, an amino alcohol and a polyvalent isocyanate compound, and the mass ratio within the acrylic polymer between the copolymer portion and the introduced urethane group portions is within a range from 60:40 to 99:1.Type: GrantFiled: April 8, 2009Date of Patent: August 13, 2013Assignee: Riso Kagaku CorporationInventors: Tetsuo Hosoya, Hiroshi Hayashi, Yoshifumi Watanabe, Kazuyuki Ando, Marie Morinaga
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Patent number: 8507583Abstract: An actinic energy radiation curable ink-jet ink comprising an actinic energy radiation polymerizable compound, wherein the actinic energy radiation polymerizable compound comprises a vinyl ether compound, a total content of the vinyl ether compound is 30% or more by mass, the vinyl ether compound comprises a bis-vinyl ether compound and a multifunctional vinyl compound having three or more vinyl ether groups, 10 to 70% by mass of the ink is the bis-vinyl ether compound, and 5 to 70% by mass of the ink is the multifunctional vinyl compound having three or more vinyl ether groups.Type: GrantFiled: March 9, 2010Date of Patent: August 13, 2013Assignee: Konica Minolta IJ Technologies, Inc.Inventors: Atsushi Nakajima, Masaki Nakamura
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Patent number: 8507584Abstract: Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1? are the same, and wherein R1 and R1? are each an aromatic group; and wherein R2 and R2? and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups; or wherein, in embodiments, R1 and R1? can be the same or different, and wherein R1 and R1? each, independently of the other is an alkyl group having a least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, an alkylaryl group having at least one ethylenic unsaturation, or an aromatic group, provided that at least one of R1 and R1? is an aromatic group; and provided that neither of R1 or R1? is a photoinitiator group. Also disclosed herein is a method of printing with the phase change ink.Type: GrantFiled: April 22, 2010Date of Patent: August 13, 2013Assignee: Xerox CorporationInventors: Naveen Chopra, Michelle N. Chretien, Barkev Keoshkerian, Jennifer L. Belelie, Peter G. Odell