Abstract: The present disclosure describes a fractional distillation tower that uses color sensing technology that provides nearly real time cutpoint analysis of high value products. With this information, the cutpoints may be aggressively shifted to a financially advantageous product slate and stay aggressive throughout each day rather than wait for a once or twice daily report of what products have been made and their analyses with respect to specifications.

Abstract: A system and method to remove gas, water, and salt from crude oil via a GOSP train and discharging the crude oil from a desalter vessel of the GOSP train as unstabilized crude oil to a stabilizer distillation column, removing gas from the unstabilized crude oil via the stabilizer distillation column to reduce vapor pressure of the unstabilized crude oil to give stabilized crude oil, and diverting a bypass portion of the unstabilized crude oil discharged from the desalter vessel to the stabilized crude oil downstream of the stabilizer distillation column.

Abstract: A process for recovering hydrogen from dehydrogenation reactor effluent is disclosed. A feed stream comprising hydrocarbons and hydrogen to a dehydrogenation reactor maintained at dehydrogenation conditions to provide a dehydrogenation reactor effluent. The dehydrogenation reactor effluent is passed to a cold box separation unit to provide a liquid hydrocarbon product stream and a recycle hydrogen stream. A return portion of the recycle hydrogen stream is passed to the reactor effluent compressor. The subject matter disclosed improved process and apparatus which enables the paraffin dehydrogenation reactor to run at reduced H2/HC ratio without requiring an investment in a resized compressor or resized turboexpanders or separators in the cold box.

Abstract: Provided in one embodiment is an improved and more flexible process for preparing a finished base oil or a white oil product comprising passing a dewaxed base oil product to a distillation column and separating the dewaxed base oil product into fuel and base oil product streams. The base oil product streams are tested to determine if they meet desired specifications. Base oil product streams that meet the desired minimum base oil specifications are passed to a hydrofinishing reactor to prepare a white oil product, or passed to direct sale.

Abstract: A method for in-situ remediation and recovery of a tar mat TM layer of a sub-surface formation can include deasphalting oil obtained from an oil column to produce a deasphalted oil, extracting an aromatic solvent from the deasphalted oil to provide a residual deasphalted oil and an extracted solvent; and injecting the residual deasphalted oil and the extracted solvent into the tar mat TM layer of the sub-surface formation using at least one horizontal well selected from the group consisting of a single horizontal well, two parallel horizontal wells, and a plurality of horizontal wells arranged in a radial configuration.

Abstract: A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

Abstract: Automated methods and systems for blending high sulfur hydrocarbons, particularly those derived from transmix, into low sulfur hydrocarbon streams are provided. Also provided are methods for splitting transmix into usable hydrocarbon fractions and blending the fractions back into defined hydrocarbon streams.

Abstract: The present invention relates to a method for the extraction of mercury from a mercury-containing hydrocarbon feed, and to the use of a hydrophilic deep eutectic solvent for the extraction of a mercury source from a hydrocarbon feed.

Abstract: Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

Abstract: A device for desulfurizing crude oil comprises a desulfurization system for sulfur-containing crude oil which forms a hydrogen sulfide-containing acid gas; a system for extracting elemental sulfur and a hydrogen sulfide-containing tail gas as exhaust gas from the acid gas; a device for generating electricity and gypsum from the tail gas; and a gas line system for supplying acid gas from the desulfurization system to the system and to the device, and for supplying tail gas from the system to the device. The gas line system has a gas distributing apparatus which supplies acid gas solely to the system in a first position, supplies acid gas solely to the device in a second position, and supplies a first part of the acid gas to the system and a second part of the acid gas to the device in a distributing position.

Abstract: The present invention relates to a process for converting the waste plastics along with the petroleum feedstock in a Catalytic Cracking Unit, in particular a Fluid Catalytic Cracking Unit employed in petroleum refineries. The invention also provides a method and hardware system to enable waste plastic to fuel conversion along with hydrocarbon catalytic cracking. The invented process aims to convert any type of waste plastic including polystyrene, polypropylene, polyethylene, metal containing Polyethylene-Polypropylene multilayer plastics & other metal containing plastics along with the petroleum derived feedstock such as vacuum gas oil, reduced crude oil, vacuum residue etc. in catalytic cracking unit.

Abstract: The invention provides a method for enriching diluents with butane so as not to violate pre-defined limits for liquid hydrocarbon fuels with respect to density, volatility and low density hydrocarbon content.

Abstract: A supported catalyst having catalytic species including molybdenum as well as cobalt and/or vanadium as a promoter disposed on a support material containing zeolite modified with titanium dioxide. Various methods of preparing and characterizing the supported catalyst are disclosed. The utilization of the catalyst in treating a hydrocarbon feedstock containing sulfur compounds (e.g. dibenzothiophene) to produce a desulfurized hydrocarbon stream is also provided.

Abstract: A robust catalyst useful for hydrodesulfurization (HDS) of sulfur-containing hydrocarbons such as sulfur-containing diesel fuel. The catalyst contains a modified mesoporous silica, such as SBA-15, Zr atoms, Ni, Mo, Ce atoms. A method for removing sulfur from a hydrocarbon, such as diesel fuel or a refinery feedstock using the catalyst. A one-pot method for making the catalyst.

Abstract: A system that includes a feedstock of a non-petroleum or renewable feedstock containing oxygen and contaminants of one or more of metals, gums, and resins that is introduced into the reactor at a flow velocity of from 20 ft/sec to 100 ft/sec. The feedstock is heated within the reactor to a temperature of from 700° F. to 1100° F. to remove and/or reduce the content of one or more of gums and resins in the fats and/or oils of the feedstock. The system further includes a reactor product that is formed in the reactor from the feedstock that has the one or more of gums and resins in the fats and/or oils of the feedstock removed and/or reduced and a heat exchanger to cool the reactor product. A separator unit separates and removes non-condensable gases, metals and water from the cooled reactor product. A final product of the system is separated from the non-condensable gases, metals and water from the cooled reactor product.

Abstract: The chemical conversion of renewable oil to obtain a hydrocarbon product suitable as a fuel, includes (i) renewable oil including corn distillers oil (CDO), fatty acid glyceryl esters (FAGE), triacylglycerols (TAG), lipids, and free fatty acids (FFA), which are derived from non-fossil-fuel sources that include animals, plants, vegetables, fruits, grains, algae, and plankton (collectively “oil”); (ii) the chemical transformation of the oil by substantially reducing or eliminating the carboxylate functionality and native unsaturations of fatty acids contained therein; (iii) wherein the hydrocarbon product is substantially a mixture of saturated hydrocarbons, or alkanes, originating from corresponding structures in the oil, e.g., the hydrocarbon chains of fatty acids; and (iv) the product mixture is suitable as fuel that may be blended with or be used in place of fuel such as diesel derived from petroleum.

Abstract: A reactor system configured for efficiently removing contaminants (CCR, nickel, vanadium, nitrogen, sodium, iron, calcium, chlorine etc.) from a heavy portion of the crude oil. The products are routed to a common main fractionation section. The heavy feed with lower contaminants may then be processed in a fluid catalytic cracking (FCC) unit, the overall concept employing a fluid catalytic reaction platform with carbon rejection approach. Also disclosed is a reactor system for efficiently processing crude oil in a fluid catalytic cracking unit with a dual-reactor and dual catalyst system to maximize petrochemical building blocks such as ethylene, propylene, butylenes, BTX (benzene, toluene and xylene) rich naphtha from a variety of crude oils.

Abstract: The present invention describes an extractive oxidation process for removing contaminants from hydrocarbon streams using an ionic liquid combined with an organometallic ionic complex of iron(II), which comprises a complex of iron(II) cation with an ionophilic binder, catalyst of iron(II) with ionophilic binder in its molecular structure, oxidation of which is performed with an oxidizing agent and is catalysed by the organometallic iron(II) complex present in the phase of the ionic liquid. Besides maintaining its characteristics of selective solvent of oxidizing compounds, the ionic liquid combined with the organometallic complex of iron(II) with catalytic ionophilic binder of the oxidizing agent, stimulating the reactive phenomenon taking place in the ionic liquid phase, with the effect that the iron remains stable in the ionic liquid phase, without being leached into the oily phase. This measure results in a considerable improvement in removal of the heteroatoms from the hydrocarbon medium.

Abstract: A process for treating a disulfide oil composition that includes combining a supercritical water stream, a hydrogen stream, and a disulfide oil composition in a mixing device to create a combined disulfide feed stream; introducing the combined disulfide feed stream into a supercritical water hydrogenation reactor operating at a temperature greater than a critical temperature of water and a pressure greater than a critical pressure of water; and at least partially converting the combined disulfide feed stream to an upgraded disulfide product.

Abstract: Separation of asphaltenes from residual oil is carried out with naphtha as solvent. In particular, straight run naphtha obtained from the same crude oil source as the residual oil feed is used as the solvent. The mixture of deasphalted oil and solvent is passed to a hydroprocessing zone, without typical separation and recycle of the solvent back to the solvent deasphalting unit. Asphalt is separated from the residual oil (residue from atmospheric or vacuum distillation); the mixture of deasphalted oil and naphtha solvent is passed to the hydroprocessing unit.