Patents Examined by Richard A Huhn
  • Patent number: 11505630
    Abstract: Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan ? at 0.1 sec?1 from 0.5 to 0.9 degrees, a tan ? at 100 sec?1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec?1 from 1.3×106 to 1×107 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.
    Type: Grant
    Filed: March 15, 2021
    Date of Patent: November 22, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Carlos A. Cruz, Yongwoo Inn, John R. Rathman, Youlu Yu, Ashish M. Sukhadia, Jay M. Chaffin
  • Patent number: 11505629
    Abstract: The present invention relates to a vinyl chloride polymer and a production method thereof. More specifically, the present invention provides a vinyl chloride polymer having a polydispersity index of 2.0 to 2.3 and a porosity of 60% or greater and a production method thereof in which a vinyl chloride polymerization seed having a conversion rate of 5-20% is first prepared through preliminary polymerization and then a vinyl chloride monomer is introduced into the vinyl chloride polymerization seed to polymerize (main polymerization) a vinyl chloride polymer.
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: November 22, 2022
    Assignee: LG Chem, Ltd.
    Inventors: Seong Yong Ahn, Kun Ji Kim, Se Woong Lee, Jin Hyuck Ju, Hyun Kyou Ha
  • Patent number: 11498986
    Abstract: The present invention relates to a continuous high-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer feed comprising the ethylene and the acrylate is polymerized in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to the liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: November 15, 2022
    Assignee: BASF SE
    Inventors: Martin Wendker, Ivette Garcia Castro, Jan Strittmatter, Karolin Geyer, Wolfgang Grabarse, Markus Scherer, Rene Koschabek
  • Patent number: 11492469
    Abstract: A thermoplastic elastomer composition including (A) ethylene rubber by 10 to 90 wt %, and (B) propylene polymer by 10 to 90 wt %, where a total amount of the thermoplastic elastomer composition is 100 wt %, is provided. A pressed sheet obtained by press-molding the thermoplastic elastomer composition under molding conditions has a sink-in temperature of 115° C. or higher. The sink-in temperature is measured based on JIS K7196-1991 as a temperature measured when a pressure load sinks in from a sheet surface by 100 ?m. The molding conditions are such that the thermoplastic elastomer composition is hot press molded at a temperature of 200° C. with a maximum pressure of 10 MPa for 5 min, and thereafter cold press molded at a temperature of 23° C. with a maximum pressure of 10 MPa for 5 min, so as to prepare the pressed sheet.
    Type: Grant
    Filed: March 17, 2021
    Date of Patent: November 8, 2022
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Ryosuke Kurokawa, Yukari Hiraguchi
  • Patent number: 11485847
    Abstract: The present invention provides a methacrylic resin composition comprising 75 to 99.8 mass % of a methacrylic resin [A], 0.1 to 15 mass % of a UV absorber [B], and 0.1 to 10 mass % of a polymer [C] having an SP value of 6.0 to 9.7 (cal/cm3)1/2 calculated by the Fedors method.
    Type: Grant
    Filed: December 20, 2018
    Date of Patent: November 1, 2022
    Assignee: KURARAY CO., LTD.
    Inventors: Shigeru Sakamoto, Takuro Niimura, Taketomo Yamashita, Atsuhiro Nakahara
  • Patent number: 11479624
    Abstract: Provided herein are polyethylene compositions suitable in the fabrication of PE-RT pipes for use in cold and hot water plumbing in accordance with ISO 22391-2, and processes for making the same.
    Type: Grant
    Filed: October 12, 2018
    Date of Patent: October 25, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Donald A. Winesett, Haiqing Peng, Antonios K. Doufas
  • Patent number: 11472952
    Abstract: A rubber composition for anti-vibration rubber comprising, based on 100 parts by weight of ethylene-propylene-diene-based copolymer rubber (EPDM): (A) 32 to 60 parts by weight of carbon black A having an average particle diameter of 60 to 100 nm, an iodine absorption amount of 14 to 23 g/kg, and a DBP oil absorption amount of 100 ml/100 g or more; (B) 10 to 30 parts by weight of carbon black B having an average particle diameter of 40 to 50 nm, an iodine absorption amount of 35 to 49 g/kg, and a DBP oil absorption amount of 100 to 160 ml/100 g; (C) 2 to 10 parts by weight of ethylene-?-olefin copolymer; and (D) 0 to 16 parts by weight of silica. The rubber composition for anti-vibration rubber that has low dynamic magnification (small increase in elastic modulus associated with an increase in rubber deformation rate), excellent durability (bearing force against breakage due to repeated deformation of rubber), excellent heat resistance, etc.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: October 18, 2022
    Assignee: NOK CORPORATION
    Inventors: Akihiro Suzuki, Tomohiro Kaise
  • Patent number: 11472899
    Abstract: An ethylene-?-olefin copolymer capable of implementing formation of a film having excellent slipperiness and suppressed fish eyes, a method of producing the ethylene-?-olefin copolymer, an ethylene-based resin composition containing the ethylene-?-olefin copolymer, and a film containing the ethylene-?-olefin copolymer or the ethylene-based resin composition. An ethylene-?-olefin copolymer according to the present invention has: a monomer unit (1) based on ethylene; and a monomer unit (2) based on an ?-olefin having 3 to 20 carbon atoms, wherein a branching parameter is 0.70 to 0.90, and a light scattering area ratio is 1.60 to 3.60.
    Type: Grant
    Filed: October 1, 2020
    Date of Patent: October 18, 2022
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Naoko Ochi, Risa Murata, Yuki Azuma
  • Patent number: 11466106
    Abstract: A latex of an acid-modified conjugated diene polymer including the acid-modified conjugated diene polymer obtained by modifying a conjugated diene polymer with an acid group-containing compound, in which a content of a structural unit derived from the acid group-containing compound is 0.2 to 0.7 parts by weight with respect to 100 parts by weight of the acid-modified conjugated diene polymer; a content of a water-soluble polymer in the latex is 2 parts by weight or less with respect to 100 parts by weight of the acid-modified conjugated diene polymer; when a solids content of the latex is adjusted to 60 wt %, a viscosity at 25° C. is 800 mPa·s or less; and when the solids content of the latex is adjusted to 50 wt %, the viscosity at 25° C. is 300 mPa·s or less.
    Type: Grant
    Filed: February 22, 2019
    Date of Patent: October 11, 2022
    Assignee: ZEON CORPORATION
    Inventors: Yoshitaka Satoh, Hidetake Ishii, Junji Kodemura
  • Patent number: 11459453
    Abstract: Provided is a reactor grade polypropylene suitable for injection molding applications comprising within a range from 0 wt % to 4 wt % ethylene and/or C4 to C12 ?-olefin derived units, the polypropylene produced from a single catalyst and single stage polymerization process, and having a melt flow rate (MFR, 230° C./2.16 kg) greater than 10 g/10 min, and a 1% secant flexural modulus of at least 250 kpsi (1720 MPa).
    Type: Grant
    Filed: May 9, 2018
    Date of Patent: October 4, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: George J. Pehlert, David K. Brown
  • Patent number: 11453627
    Abstract: Implementations described herein generally relate to methods for purifying alpha-olefins. The alpha-olefins may be used to form drag reducing agents for improving flow of hydrocarbons through conduits, particularly pipelines. In one implementation, a method of increasing alpha-olefin content is provided. The method includes providing an olefin feedstock composition having an alpha-mono-olefin and at least one of a diolefin having an equal number of carbon atoms to the alpha-mono-olefin and/or a triolefin having an equal number of carbon atoms to the alpha-mono-olefin. The method further includes contacting the olefin feedstock composition with ethylene in the presence of a catalyst composition including an olefin metathesis catalyst. The method further includes reacting the olefin feedstock composition and ethylene at metathesis reaction conditions to produce an alpha-olefin product comprising the alpha-mono-olefin and alpha-olefins having fewer carbon atoms than the alpha-mono-olefin.
    Type: Grant
    Filed: February 28, 2020
    Date of Patent: September 27, 2022
    Assignee: LIQUIDPOWER SPECIALTY PRODUCTS, INC.
    Inventor: Stuart N. Milligan
  • Patent number: 11453769
    Abstract: Plasticizer composition for a construction polymers. The plasticizer composition includes 35-65% (by weight) of polyvinylbutyral and 65-35% (by weight) of one or more alloying copolymers. The construction polymer is e.g. polyvinyl chloride, polypropylene, poly urethane, acryl butadiene styrene or polyethylene and/or mixtures thereof. The resulting polymer construction polymer constitutes 25-90% by weight and the plasticizer composition constitutes 10-75% by weight of the polymer blend composition. The components of the plasticizer composition are non-migrating and provide surprising physical properties of the final polymer composition.
    Type: Grant
    Filed: March 15, 2019
    Date of Patent: September 27, 2022
    Assignee: SHARK SOLUTIONS APS
    Inventors: Jens Holmegaard, Frank Mundt
  • Patent number: 11447579
    Abstract: The present invention relates to a process for preparing a poly(meth)acrylic acid, characterized in that a (meth)acrylic acid-containing process stream from (meth)acrolein synthesis is subjected to free-radical polymerization. The invention also relates to the esterification of the polymer obtained to give a homopolymer or copolymer ester, and to the use thereof as additive, flow improver and water reducer.
    Type: Grant
    Filed: August 1, 2018
    Date of Patent: September 20, 2022
    Assignee: Roehm GmbH
    Inventors: Steffen Krill, Johannes Vorholz, Andreas Weber, Marita Kaufmann, Andrea Wittkowski
  • Patent number: 11434308
    Abstract: Object: To provide a method for manufacturing a polymer, which is a method for forming a polymer having a homogeneous copolymer composition and a narrow molecular weight distribution. Resolution Means: A method for manufacturing a polymer using a microreactor including a flow path capable of mixing a plurality of liquids to perform radical polymerization of a monomer component containing two or more types of monomers in the presence of a polymerization initiator; wherein the microreactor includes a first inlet port configured to feed the monomer component and an additional inlet port located downstream of the first inlet port; and the method includes feeding the monomer component through the first inlet port and the additional inlet port.
    Type: Grant
    Filed: August 13, 2019
    Date of Patent: September 6, 2022
    Assignee: DAICEL CORPORATION
    Inventor: Tadashi Teranishi
  • Patent number: 11427658
    Abstract: A method for manufacturing a low molecular weight acrylic resin, and more particularly, to a method for manufacturing a low molecular weight acrylic resin having a high conversion rate and a low poly dispersion index includes maintaining the temperature of a reacting part with a screw stirrer at a specific temperature during a continuous polymerization of a solvent-free acrylic composition in a continuous flow reactor having the reacting part.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: August 30, 2022
    Inventors: Woo Yeon Kim, Jun Man Choi, Jang Soon Kim, Kwang Su Seo
  • Patent number: 11421054
    Abstract: The present disclosure provides for a system and method for producing a polyethylene polymer (PE) that includes measuring a melt flow index (MFI) of the PE, comparing the measured value of the MFI to a predetermined desired range for the MFI, changing a catalyst feed rate to the polymerization reactor based on the compared values of the MFI, where changes in the catalyst feed rate preemptively compensate for subsequent changes in an oxygen flow rate to the polymerization reactor that maintain a predetermined residence time and bring the MFI of the PE into the predetermined desired range for the MFI; and changing the oxygen flow rate to the polymerization reactor thereby maintaining both the predetermined residence time and bringing the MFI of the PE into the predetermined desired range for the MFI. The measuring and comparing steps are repeated to ensure the measured value of the MFI is within the predetermined desired range of the MFI at the predetermined residence time.
    Type: Grant
    Filed: October 23, 2020
    Date of Patent: August 23, 2022
    Assignee: Univation Technologies, LLC
    Inventors: Samuel Bernal, Mark G. Goode, Francois Alexandre, William A. Matthews
  • Patent number: 11414506
    Abstract: The present invention pertains to a process for manufacturing a semi-crystalline fluoropolymer, to the fluoropolymer obtainable by said process and to uses of said fluoropolymer in various applications.
    Type: Grant
    Filed: April 9, 2018
    Date of Patent: August 16, 2022
    Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Mattia Bassi, Alessio Marrani, Fulvia Roncati, Eliana Ieva, Valeriy Kapelyushko
  • Patent number: 11407867
    Abstract: A heat-shrinkable label made from or containing a terpolymer film containing propylene, ethylene and 1-hexene, wherein the terpolymer has: (i) a content of ethylene derived units ranging from 0.5 wt % to 5.0 wt %, (ii) a content of 1-hexene derived units ranging from 1.0 wt % to 6.0 wt %, (iii) a melt flow rate (MFR) (ISO 1133 230° C., 2.16 kg) ranging from 0.5 to 20 g/10 min, and (iv) a polydispersity index (P.I.) ranging from 2.0 to 7.0.
    Type: Grant
    Filed: October 31, 2018
    Date of Patent: August 9, 2022
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Andrea Felisati, Marco Izzi, Paolo Bassi, Claudio Cavalieri
  • Patent number: 11396592
    Abstract: Polymer compositions may include a matrix phase comprising a polypropylene-based polymer; and an elastomeric rubber phase; wherein the polymer composition has melt flow rate (MFR) according to ASTM D1238 at 230° C./2.16 kg equal to or greater than 90 g/10 min and at least one feature selected from (I) an Izod impact resistance according to ASTM D256A at 23° C. equal to or greater than 400 J/m; (II) an instrumented drop impact at ?30° C., average total energy, equal to or greater than 17 J; or (III) an instrumented drop impact at ?30° C., average percent ductility, equal to or greater than 60%.
    Type: Grant
    Filed: February 19, 2020
    Date of Patent: July 26, 2022
    Assignee: Braskem S.A.
    Inventors: Moisés Magalhães Werlang, Joel Carr, Tadeu Forest
  • Patent number: 11396572
    Abstract: Disclosed is a block copolymer including one or more blocks of an acrylate polymer and one or more blocks of a chloroprene polymer, wherein the number average molecular weight of the block copolymer is 110,000 or more, the number average molecular weight of the block of a chloroprene polymer is 80,000 or more in total, and the block copolymer has a functional group with a structure represented by the following chemical formula (1) or (2): wherein in the chemical formula (1), R1 represents hydrogen, chlorine, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group or a substituted, or unsubstituted heterocyclyl group.
    Type: Grant
    Filed: July 31, 2018
    Date of Patent: July 26, 2022
    Assignee: Denka Company Limited
    Inventors: Yuhei Ishigaki, Suguru Onuki, Shogo Hagiwara, Uichiro Yamagishi