Abstract: A copolymer includes a main hydrocarbon chain and side groups including carboxylic groups and polyoxyalkylate groups. The copolymer further includes gem-bisphosphonate groups. The copolymer can be included in an admixture for suspensions of mineral particles and in a composition of mineral particles. The copolymer can also be used for fluidifying and maintaining fluid, suspensions of mineral particles and for reducing the sensitivity of hydraulic compositions to clays and alkaline sulfates.
Abstract: The invention provides reactive resins compounds and compositions made from renewable materials, such as plant and animal oils. The reactive resins compounds and compositions may include an accelerator as part of their structure and are made from renewable materials containing a variety of functional groups. The compositions provide excellent adhesion and sealing capability.
Type:
Grant
Filed:
April 16, 2018
Date of Patent:
November 3, 2020
Assignee:
Henkel IP & Holding GmbH
Inventors:
Andrew D. Messana, David P. Dworak, Darel Gustafson, Anthony F. Jacobine
Abstract: The present invention relates to a liquid (meth) acrylic composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer. In particular the present invention it relates to liquid composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer that can be used as a syrup and especially as a syrup for impregnation. More particularly the present invention relates also to a process for preparing a liquid composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer.
Type:
Grant
Filed:
January 11, 2017
Date of Patent:
October 27, 2020
Assignee:
Arkema France
Inventors:
Raber Inoubli, Philippe Hajji, Rosangela Pirri, Pierre Gerard
Abstract: Described herein are embodiments of compositions and methods relating to three-dimensional (3D) printing. Some embodiments are directed to a composition comprising a polymer with one or more dormant functional groups. According to some embodiments, the polymer may be formed through a controlled radical polymerization method. Some embodiments are directed to a composition comprising a polymer with one or more pendent crosslinkable groups. In some cases, the composition may be used as an “ink” for 3D printing. For example, the composition may be injected into a medium. The composition and/or medium may, in some embodiments, further comprise an initiator and/or a crosslinker. After injection of the composition into the medium, the one or more dormant functional groups and/or one or more pendent crosslinkable groups may be activated, and the polymer may be crosslinked. In certain cases, the crosslinked polymer may be removed from the medium to produce a freestanding three-dimensional structure.
Type:
Grant
Filed:
June 1, 2018
Date of Patent:
October 27, 2020
Assignee:
University of Florida Research Foundation, Inc.
Inventors:
Brent S. Sumerlin, Gregory Wallace Sawyer, Thomas Ettor Angelini, Christopher P. Kabb
Abstract: The present invention relates to a modifier represented by Formula 1, a method of preparing the same, a modified conjugated diene-based polymer having a high modification ratio which includes a modifier-derived functional group, and a method of preparing the polymer.
Type:
Grant
Filed:
October 30, 2017
Date of Patent:
October 20, 2020
Assignee:
LG Chem, Ltd.
Inventors:
Seung Ho Choi, Dae June Joe, Won Taeck Lim, Won Mun Choi
Abstract: A primer mixture intended for crosslinking polyethylene, including at least an initiator of free radicals chosen from organic peroxides, azo compounds or mixtures thereof, wherein the mixture has said free-radical initiator and at least one crosslinking promoter chosen from the cycloalkanes having 5 to 7 carbon atoms, substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the aromatic compounds substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the methacrylate, acrylate and maleimide monomers being multi-substituted, and in that the weight ratio of free-radical initiator to the crosslinking promoter is greater than or equal to 1, and preferably between 1.5 and 4. Also, a method and to a use related to this primer mixture.
Abstract: Lactose-derived hydrogels include at least lactose and methacrylic anhydride. A method of preparing lactose-derived hydrogels includes copolymerizing lactose methacrylate, methacrylic acid, and sodium methacrylate using light-induced photopolymerization. Polymerization proceeds in the absence of a photoinitiator. No volatile organic compounds or waste are produced by the method. The lactose may be provided by a milk permeate waste stream from the dairy or food processing industry.
Type:
Grant
Filed:
November 9, 2018
Date of Patent:
October 13, 2020
Assignee:
REGENTS OF THE UNIVERSITY OF MINNESOTA
Inventors:
Hasmukh Patel, Marc Andrew Hillmyer, Larissa Ribeiro da Fonseca, Philip Thomas Dirlam
Abstract: A process for increasing MFR2 of a polyethylene copolymer or an ethylene plastomer or elastomer comprising: (I) extruding a copolymer of polyethylene copolymer having a density of 910 to 970 kg/m3 and an MFR2 of 1 and 100 g/10 min or an ethylene plastomer or elastomer having a density of 855 to 910 kg/m3 and an MFR2 of 0.5 and 100 g/10 min in the presence of 0.1 to 2 wt % of a non-peroxide radical initiator so as to produce a polyethylene copolymer having an MFR2 of 200 g/10 min or more, or an ethylene plastomer or elastomer having a MFR2 of 200 g/10 min or more.
Abstract: The present invention relates to the field of inhibition of metal corrosion in hot acidic hydrocarbons, wherein acidity is derived from presence of naphthenic acid. More particularly, it relates to a polymeric additive for inhibiting high temperature napthenic acid corrosion, wherein said polymeric additive is polymeric phosphate ester of polyisobutylene succinate ester or oxide derivative of polymeric phosphate ester of polyisobutylene succinate ester. A polymeric phosphate ester of polyisobutylene succinate ester which is capable of acting as naphthenic acid corrosion inhibitor by inhibiting naphthenic acid corrosion in crude oil/feedstock/hydrocarbon streams containing naphthenic acid, and demonstrating higher thermal stability at elevated temperature varying from about 200° C. to about 400° C. [about 400° F. to about 750° F.] is disclosed.
Type:
Grant
Filed:
August 26, 2009
Date of Patent:
September 29, 2020
Assignee:
Dorf Ketal Chemicals (India) Private Limited
Abstract: Method of production of highly saturated nitrile rubber, including: polymerization step of polymerizing monomer mixture containing at least ?,?-ethylenically unsaturated nitrile monomer and diene monomer in medium to obtain dispersion or solution of nitrile rubber; coagulation step causing the nitrile rubber dispersion or solution to coagulate at 10-60° C.
Abstract: In various embodiments, the present invention is directed to a centrally-functionalizable living cationic polymer or copolymer having a centrally-substituted tetraene group having the formula wherein each R is selected from the group consisting of a polymer or a copolymer, such as a polyisobutylene polymer or a poly(isobutylene-b-styrene) copolymer.
Type:
Grant
Filed:
January 25, 2019
Date of Patent:
September 15, 2020
Assignee:
The University of Akron
Inventors:
Joseph P. Kennedy, Turgut Nugay, Nihan Nugay, Tejal J. Deodhar, Susan Dollinger
Abstract: The present invention is: a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:50, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1), R1SiO3/2??(a-1) wherein R1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group, the component (B) being fine particles having an average primary particle size of 5 to 40 nm, and the component (C) being a silane coupling agent that comprises an acid anhydride structure in its molecule.
Abstract: A copolymer comprising a copolymer chain A bearing a function B selected from the group consisting of the functions B1 and B2, the copolymer chain A being a copolymer chain comprising monomer units M1 and monomer units M2, M1 being a conjugated diene and M2 being a monomer selected from the group consisting of ?-monoolefins, ethylene and mixtures thereof, B1 being selected from the group consisting of N(SiMe3)2; N(SiMe2CH2CH2SiMe2); para-C6H4(NMe2); para-C6H4(OMe); para-C6H4(N(SiMe3)2); ortho-CH2-C6H4NMe2; ortho-CH2-C6H4OMe; C6F5; C3F7; C6F13; CH(OCH2CH2O); B2 being a function that is derived from B1, is provided. Such a copolymer is synthesized by using a transfer agent bearing the function B1 and a carbon-metal bond, the metal being an alkaline-earth metal, zinc or aluminium.
Type:
Grant
Filed:
December 7, 2016
Date of Patent:
August 25, 2020
Assignee:
COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Abstract: There is provided a rubber composition in which an antistatic agent is uniformly dispersed and the rubber composition has antistatic ability, coefficient of friction, and wear resistance. A rubber composition includes 7 parts by mass or more of a polyether/polyolefin block copolymer resin with respect to 100 parts by mass of a rubber component, and the total amount or a part of a rubber component is mixed with a polyether/polyolefin block copolymer resin at a temperature that is equal to or higher than a melting point of the polyether/polyolefin block copolymer resin.
Abstract: Techniques regarding the synthesis of one or more polymers through one or more ring-opening polymerizations conducted within a flow reactor and facilitated by one or more anionic catalysts are provided. For example, one or more embodiments can comprise a method, which can comprise functionalizing, via a post-polymerization reaction within a flow reactor, a chemical compound by covalently bonding a trimethylsilyl protected thiol to a pendent functional group of the chemical compound in a presence of a catalyst. The pendent functional group can comprise a perfluoroaryl group and a methylene group.
Type:
Grant
Filed:
July 6, 2018
Date of Patent:
August 11, 2020
Assignees:
INTERNATIONAL BUSINESS MACHINES CORPORATION, THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY
Inventors:
Nathaniel H. Park, James L. Hedrick, Victoria A. Piunova, Dmitry Zubarev, Gavin O. Jones, Robert M. Waymouth, Binhong Lin
Abstract: Phosphate-based polyallyl isocyanurate cross-linker compounds, polyalkenyl isocyanurate cross-linker compounds, and a flame-retardant resin are disclosed. The phosphate-based polyallyl isocyanurate compound can have allyl phosphate substituents with variable functional groups. The phosphate-based polyallyl isocyanurate compound can have three or six allyl phosphate substituents. The brominated polyalkenyl isocyanurate compound can have brominated alkene-terminated substituents. The brominated alkene-terminated substituents can have variable functional groups and variable chain lengths. Both the phosphate-based polyallyl isocyanurate compounds and the brominated polyalkenyl isocyanurate compounds can be cross-linkers for epoxide polymers, acrylate polymers, vinylbenzene-terminated poly(phenyleneoxide) polymers, etc. The phosphate-based polyallyl isocyanurate compounds and the brominated polyalkenyl isocyanurate compounds can also be flame-retardant.
Type:
Grant
Filed:
December 6, 2016
Date of Patent:
August 11, 2020
Assignee:
International Business Machines Corporation
Inventors:
Scott B. King, Brandon M. Kobilka, Joseph Kuczynski, Jason T. Wertz
Abstract: Provided are methods for producing a thermoplastic vulcanizate and thermoplastic vulcanizates provided therein. The method includes introducing vulcanizable rubber, thermoplastic resin, a masterbatch of a propylene-based elastomer and a cure accelerator for a phenolic resin curative to the reactor, and phenolic resin curative to a reactor and dynamically vulcanizing the rubber with the phenolic resin curative in the presence of the cure accelerator and the thermoplastic resin.
Type:
Grant
Filed:
December 10, 2015
Date of Patent:
August 4, 2020
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Declan Whelan, Stephen F. Roche, Porter C. Shannon
Abstract: Antioxidant polymer foams and uses thereof are described herein. These foams are synthesized using a Carboni-Lindsey reaction of 1,2,4,5-tetrazine with a polymer having alkenyl functional groups. The foams feature dihydropyridazine functional groups which can be oxidized to consume surrounding reactive oxidizing chemicals and are consequently antioxidant.
Type:
Grant
Filed:
June 12, 2018
Date of Patent:
August 4, 2020
Assignee:
ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIVERSITY OF ARIZONA
Inventors:
Douglas A. Loy, Robb E. Bagge, Wenmo Sun
Abstract: Disclosed are saturated cyclic monopolymers derived from hexyne, octyne, nonyne, pentadecyne and saturated cyclic copolymers derived from acetylene and a second alkyne monomer that is hexyne, octyne, nonyne, or pentadecyne.
Type:
Grant
Filed:
September 22, 2017
Date of Patent:
August 4, 2020
Assignee:
University of Florida Research Foundation, Inc.
Abstract: The invention relates to a fluorinated copolymers which are particularly based on vinylidene fluoride (VDF) or trifluoroethylene (TrFE) and particularly functionalized by functional and/or functionizable vinyl ethers. The invention also relates to methods for producing said copolymers, and to the applications thereof.
Type:
Grant
Filed:
October 18, 2016
Date of Patent:
August 4, 2020
Assignee:
Arkema France
Inventors:
Thierry T. Lannuzel, Fabrice Domingues Dos Santos, Thibaut Soulestin, Vincent Ladmiral, Bruno Ameduri