Patents Examined by Robert E. Sellers
  • Patent number: 6255364
    Abstract: A crosslinkable waterborne dispersion of an epoxidized polydiene block polymer composition which comprises: (a) 10 to 65% w of a polydiene block polymer containing at least five olefinic epoxy groups per molecule which are sterically hindered, (b) 0.2 to 25% w of a compatible aminoplast, (c) 0.1 to 10% w of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. The invention also describes a water-continuous process and an inversion processes for making such dispersions.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: July 3, 2001
    Assignee: Shell Oil Company
    Inventors: David John St. Clair, James Robert Erickson
  • Patent number: 6153672
    Abstract: A process for preparing a tris-lactam crosslinking agent, tris-pyrrolidonyl triazine, from N,N',N"-tris(4-chlorobutyryl)melamine by treatment of the chlorobutyryl derivative with a base such as sodium or potassium carbonate to effect intramolecular cyclization to the tris-lactam. A curable composition comprised of tris-pyrrolidonyl triazine as the crosslinking agent and a hydroxyfunctional or aminofunctional material as a resin. Thick films with no pinholes are prepared from the curable compositions using powder coating techniques.
    Type: Grant
    Filed: January 7, 1993
    Date of Patent: November 28, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Ram B. Gupta, Robert G. Lees
  • Patent number: 6136305
    Abstract: A thickener comprises a water-in-oil reverse emulsion and a copolymer having moieties derived (i) from a monounsaturated monocarboxylic acid monomer containing from 3 to 5 carbon atoms, the monocarboxylic acid either being in free form or in the form of an inorganic salt, and (ii) from a monoacrylamide monomer. The copolymer is in solution in the aqueous phase constituting the emulsion, the oil phase of this emulsion consisting of a mixture of at least one volatile oil and at least one non-volatile oil. The weight ratio between the volatile oil and the non-volatile oil is between 90/10 and 10/90. The oil phase represents from 10 to 60% by weight of the whole. Water represents from 30 to 70% by weight of the whole. The copolymer represents from 10 to 30% by weight of the whole and a surfactant represents from 5 to 20% by weight of the whole.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: October 24, 2000
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques, S.E.P.P.I.C.
    Inventors: Nelly Michel-Lecocu, Chantal Amalric
  • Patent number: 6136922
    Abstract: A curable composition comprisingA) a mixture ofA1) at least one polymer based on acrylate and/or methacrylate monomers and containing on average 0.1 to 4.0 equivalents of free carboxyl groups per kilogram of polymer, andA2) at least one carboxyl-terminated polyester which contains on average0.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: October 24, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Isabelle Frischinger, Jacques-Alain Cotting, Jacques Fran.cedilla.ois
  • Patent number: 6133377
    Abstract: The present invention provides an epoxy resin composition comprising: (a) an epoxy resin having two or more epoxy groups in each molecule; (b) a phenolic resin composition comprising a condensation product of: (i) a phenol; (ii) a compound having a triazine ring; and (iii) an aldehyde, the mixture or condensation product being substantially free from any unreacted aldehydes, or methylol groups; (c) a rubber component; and (d) a curing accelerator. The epoxy resin composition has minute protrusions having a maximum height (Ry) .ltoreq.1.0 .mu.m, formed on its surface by thermosetting at or above 80.degree. C. The invention also provides a process for manufacturing a multilayer printed-wiring board of the build-up type which has a formed copper plating layer.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: October 17, 2000
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Yuki Miyazawa, Tadahiko Yokota
  • Patent number: 6130297
    Abstract: A crosslinker composition based on a combination of 1,3,5-tris-(2-carboxyethyl)isocyanurate and a dicarboxylic acid crosslinking agent is provided. Also provided is a curable epoxy composition employing, as the crosslinker component, a combination of 1,3,5-tris-(2-carboxyethyl)isocyanurate and a dicarboxylic acid crosslinking agent, which curable composition finds use, for example, in coating applications.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: October 10, 2000
    Assignee: Cytec Technology Corp.
    Inventor: Subban Ramesh
  • Patent number: 6127508
    Abstract: An epoxy resin composition containing a) an epoxy resin and b) a liquid amine terminated polyamine curing agent prepared by condensing an aminoalkylpiperazine and a dicarboxylic acid. The epoxy resin composition typically requires less than 35% of solvent to produce a sprayable viscosity. A hydroxy-functional flexibilized resin is also produced by reacting (a) an epoxy resin, (b) a liquid aminoalkylpiperazine-based amine terminated polyamine and (c) a hydroxy-functional amine.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: October 3, 2000
    Assignee: Shell Oil Company
    Inventors: Larry Steven Corley, Martin L. Ehrlich
  • Patent number: 6121339
    Abstract: An epoxy resin composition according to the present invention is one initiating cationic polymerization upon irradiation with energy rays. The epoxy resin composition is formed of at least bisphenol epoxy resin (A) as an active ingredient, epoxy resin (B) shown in the following formula and cationic polymerization catalyst (C).
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: September 19, 2000
    Assignee: Sony Chemicals Corporation
    Inventors: Hiraku Kominami, Kozaburo Hayashi, Kazuki Shibata
  • Patent number: 6119743
    Abstract: A tire tread comprises a copolymer of butadiene with isoprene and/or styrene having a room temperature elasticity of between 5 and 35% at 22.degree. C., polybutadiene rubber and an aromatic oil selected from the group consisting of an aromatic oil, naphthenic oil, paraffinic oil, and a mixture thereof.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: September 19, 2000
    Assignee: Huels Aktiengesellschaft
    Inventor: Walter Hellermann
  • Patent number: 6117952
    Abstract: A powder coating composition comprising(A) a solid epoxy resin mixture that comprises at least one epoxy resin component (A1) and one epoxy resin component (A2) and(B) a free-carboxyl-group-containing polyester in an amount sufficient for the full cure of the composition,in which the epoxy resin component (A1) consists of one or more epoxy resins and has overall a mean epoxy functionality that is greater than 2,wherein the epoxy resin component (A2) consists of one or more advanced epoxy resins each of which has a mean epoxy functionality of at least 1.2 but less than 1.95 and is the product of a reaction in which (i) at least one diglycidyl compound is simultaneously reacted with (ii) at least one bisphenol compound and (iii) at least one monophenol as starting materials, and the difference between the mean epoxy functionality of the epoxy resin mixture (A) and the mean epoxy functionality of component (A2) of the mixture is at least 0.05 but less than 0.8.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: September 12, 2000
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Jurgen Finter, Isabelle Frischinger, Christine Poget
  • Patent number: 6113906
    Abstract: Branched, substantially non-antigenic polymers are disclosed. Conjugates prepared with the polymers and biologically active molecules such as proteins and peptides demonstrate extended circulating life in vivo. Substantially fewer sites on the biologically active material are used as attachment sites. Methods of forming the polymer, conjugating the polymers with biologically active moieties and methods of using the conjugates are also disclosed.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: September 5, 2000
    Assignee: Enzon, Inc.
    Inventors: Richard B. Greenwald, Anthony J. Martinez
  • Patent number: 6114450
    Abstract: An adhesive for bonding a die of an integrated circuit chip comprises an aryl cyanate (ester) resin and/or a diepoxide resin admixed with tetrahydropyranyl-protected hydroxylmethylated phenolic resin or hydroxymethylated poly(hydroxystyrene) optionally further containing an electrically or thermally conductive filler.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: September 5, 2000
    Assignee: International Business Corporation
    Inventors: Krishna Gandhi Sachdev, Michael Berger, Anson Jay Call, Frank Louis Pompeo Jr.
  • Patent number: 6114467
    Abstract: Compounds having the formula F(CF.sub.2).sub.q --(CH.sub.2).sub.p-1 --COX' wherein q ranges from 6-15, p ranges from 3-15 and X' is halogen are useful as reactants for hydroxylated block copolymers or polyamines to produce fluorinated polymers.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: September 5, 2000
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Christopher K. Ober, Jianguo Wang, Edward J. Kramer
  • Patent number: 6111014
    Abstract: The invention provides a water degradable polyolefin-containing film having greater than about 55 weight percent of a modified polyolefin and less than about 45 weight percent of unmodified poly(ethylene oxide). The polyolefin is modified by grafting thereto a monomer selected from 2-hydroxyethyl methacrylate and polyethylene glycol ethyl ether methacrylate in an amount ranging between about 0.1 weight percent and about 30 weight percent, based on the total weight of the polymer blend. The polyolefin-containing film, when immersed in water for about 30 seconds, loses at least 10% in two or more of the tensile properties: percent strain-to-break, peak stress, energy-to-break and modulus when compared to the dry or pre-immersion values. Also provided are flushable personal care articles such as infant diapers, feminine hygiene napkins, and adult incontinence garments having a backing or barrier layer comprising a water degradable polyolefin-containing film of the invention.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: August 29, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James Hongxue Wang, David Michael Schertz
  • Patent number: 6111015
    Abstract: Curable suspensions of an epoxy resin formulation comprisinga) a storage-stable suspension of an epoxy resin and a toughener suspended therein which contains no groups that react with a curable epoxy resin system,b) dicyandiamide, a polycarboxylic acid, a polycarboxylic anhydride, a polyamine, a polyaminoamide, an amino group-containing adduct of an amine and a polyepoxide, a polyol or a catalytically curing hardener, and, as optional components,c) a curing catalyst, conventional fillers or reinforcing materials,are particularly suitable for use as casting resins, laminating resins or adhesives.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: August 29, 2000
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Sameer H. Eldin, Robert Peter Peyer, Frans Setiabudi, Urs Gruber
  • Patent number: 6106011
    Abstract: Disclosed is a thermoplastic elastomer composition comprising 100 parts by weight of a mixture of two different specific hydrogenated block copolymers which are different in molecular structure and number average molecular weight; 25 to 60 parts by weight of a polyolefin resin having a melt flow rate of from 5 to 50 g/10 minutes; and 0 to 30 parts by weight of a hydrocarbon oil. Also disclosed is a cover for an air bag device, which comprises a molded body formed by molding the thermoplastic elastomer composition.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: August 22, 2000
    Assignee: Asahi Kasei Kogyo Kabushiki
    Inventors: Tetsuo Masubuchi, Mitsuhiro Tanaka
  • Patent number: 6107369
    Abstract: A process for preparing a tris-lactam crosslinking agent, tris-pyrrolidonyl triazine, from N,N',N"-tris(4-chlorobutyryl)melamine by treatment of the chlorobutyryl derivative with a base such as sodium or potassium carbonate to effect intramolecular cyclization to the tris-lactam. A curable composition comprised of tris-pyrrolidonyl triazine as the crosslinking agent and a hydroxyfunctional or aminofunctinoal material as a resin. Thick films with no pinholes are prepared from the curable compositions using powder coating techniques.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 22, 2000
    Assignee: Cytec Technology Corp.
    Inventors: R. B. Gupta, Robert G. Lees
  • Patent number: 6103825
    Abstract: Epoxy resins which are obtainable by a process in which, first of all(a) by reacting(A1) at least one substance selected from the substances of the formula (I) and of the formula (II): ##STR1## in which Alc is the radical of a diol which has been freed fromI ts hydroxyl groups and comprises 2 to 20 carbon atoms,Ac is the radical of a dicarboxylic acid which has been freed from its carboxyl groups and comprises 2 to 20 carbon atoms,[Ph] is the radical of a difunctional phenolic compound which has been freed from its phenolic hydroxyl groups and has 6 to 20 carbon atoms, andc is a number greater than 1 but not more than 2, with(A2) at least one liquid diglycidyl ether based on a first bisphenol compound in an amount chosen so that there are more than two equivalents of glycidyl groups of component (A2) for a total of one equivalent of carboxyl and phenolic hydroxyl groups of component (A1),a pre-advanced diglycidyl ether resin is formed in dispersion in the liquid diglycidyl ether of which there is at least one
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: August 15, 2000
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Isabelle Frischinger, Jurgen Finter, Christine Poget, Philippe-Guilhaume Gottis
  • Patent number: 6103835
    Abstract: An epoxy-functional polyester storage-stable at temperatures of up to 40.degree. C. and having a Tg of more than 40.degree. C. is prepared by the reaction of an epoxy-functional polyester intermediate (III) produced by glycidating a carboxyl-functional polyester derived from (a) at least one secondary carboxyl groups-containing aromatic or cycloaliphatic dicarboxylic acid (anhydride), (b) at least one aliphatic hydroxyl groups-containing diol, (c) optionally, a compound containing one primary or secondary hydroxyl group, or a compound comprising one primary or secondary hydroxyl group and one tertiary aliphatic carboxyl group, (d) optionally, a compound comprising a tertiary aliphatic carboxyl group and two aliphatic hydroxyl groups and (e) optionally, a trihydroxyalkane or tetrahydroxyalkane; with (IV) a carboxyl-functional polyester obtained from (a) and (b) above, or (a) alone.
    Type: Grant
    Filed: November 11, 1998
    Date of Patent: August 15, 2000
    Assignee: Shell Oil Company
    Inventors: Edward John Marx, Simon Ming-kung Li, Petrus G. Kooijmans
  • Patent number: 6100330
    Abstract: The invention provides a water degradable modified polyolefin-modified poly(ethylene oxide-containing film having greater than about 55 weight percent of a modified polyolefin and less than about 45 weight percent of a modified poly(ethylene oxide). The polyolefin and poly(ethylene oxide) polymers are modified by having grafted thereto from about 0.1 weight percent to about 30 weight percent of a monomer selected from 2-hydroxyethyl methacrylate or polyethylene glycol ethyl ether methacrylate. The modified polyolefin-modified poly(etheylene oxide)-containing film of the invention, when immersed in water for about 30 seconds, loses at least 10% in two or more of the tensile properties: percent strain-to-break, peak stress, energy-to-break and modulus when compared to the dry or pre-immersion values.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: August 8, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James Hongxue Wang, David Michael Schertz