Abstract: The present disclosure is directed to methods of forming polyamic acid and polyimide gels in water. The resulting polyamic acid and polyimide gels may be converted to aerogels, which may further be converted to carbon aerogels. Such carbon aerogels have the same physical properties as carbon aerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based. The disclosed methods are advantageous in reducing or avoiding costs associated with use and disposal of potentially toxic solvents and byproducts. Gel materials prepared according to the disclosed methods are suitable for use in environments involving electrochemical reactions, for example as an electrode material within a lithium-ion battery.

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications.

Abstract: A coating composition comprises a base coat component and a top coat component. The base coat component comprises at least one resin selected from the group consisting of a styrene, a styrene-ethylene/butylene-styrene block polymer and a mixture thereof, and at least one solvent for the resin. The top coat component comprises a Methyl-methacrylate-Acrylate-Methyl-methacrylate block polymer and a solvent for the Methyl-methacrylate-Acrylate-Methyl-methacrylate block polymer. A method of temporarily coating a substrate comprises applying the base coat component to a substrate, allowing the base coat component to dry and applying the top coat component and allowing the top coat to dry. The resulting coating can be removed from the substrate by peeling, even after extended exposure to ultraviolet light.

Abstract: [Problem] Provided is a two-component type curable resin composition that allows a mixture of an A agent and a B agent to have excellent dispersibility and printability, causes no visible-copper phenomenon, and provides an excellent packing form (receivability) for transportation. [Solution] A two-component type curable resin composition according to the present invention is characterized by including: an A agent containing a carboxyl group-containing resin; and a B agent containing a thermosetting ingredient, wherein the A agent has a viscosity value in the range of 50 dPa·s or more and 200 dPa·s or less at 25° C. at 5 rpm, wherein the B agent has a viscosity value in the range of 100 dPa·s or more and 300 dPa·s or less at 25° C.

Abstract: A method of manufacturing copolymer includes mixing and reacting a polyester, an aliphatic polyol or an aliphatic polyol oligomer, and a first catalyst in a first region of a screw to form a polyester polyol, and side-feeding a lactone or a lactam to a second region of the screw to copolymerize the lactone or a lactam and the polyester polyol to form a copolymer, wherein the first region and the second region are continuous connecting regions.

Abstract: One object of the present invention is to provide an emulsion composition comprising a silicone and an emulsion of a resin having a film forming property, which emulsion composition may provide a coating agent which effectively exhibits slidability of silicone on a substrate, while maintaining transparency. Another object of the present invention is to provide a laminate having a film made of the coating agent. The present invention provides an emulsion composition comprising (I) an emulsion of a resin having a film forming property in a solid content of 60 to 99.9 parts by mass and (II) an emulsion of a silicone-acrylic core-shell resin in solid content of 0.

Abstract: A zwitterionic polysiloxane polymer (e.g., a polyurethane elastomer) composition having poly(dialkylsiloxane) blocks and a zwitterionic moiety is prepared by the copolymerization of a poly(dialkylsiloxane) diol, a diisocyanate, a tertiary amine alkyl diol, and a poly(dialkylsiloxane) diamine to form a poly(urethane urea) copolymer. A substituted saturated heterocylic compound is reacted with the tertiary amine of the poly(urethane urea) copolymer to introduce a zwitterionic group into the poly(urethane urea) copolymer backbone. A polysiloxane polymer having a zwitterionic moiety is prepared by reacting a diallyl tertiary amine compound and a substituted saturated heterocylic compound to form a diallyl zwitterionic macromer and cross-linking a vinyl terminated poly(dialkylsiloxane) and the diallyl zwitterionic macromer with a curing agent to introduce a zwitterionic group into the poly(dialkylsiloxane) polymer.

Abstract: A method for preparation of a starch-promoted alkyl ketene dimer (AKD) sizing emulsion is provided. The inventive method comprises adding a sizing promoter comprising high-charge cationic starch and polyaluminum chloride (PAC) to a stabilized AKD emulsion and further wherein addition of said sizing promoter comprising high-charge cationic starch and PAC is effected at ambient temperature, after emulsification, stabilization, and homogenization of said stabilized AKD emulsion; and prior to addition of the starch-promoted AKD sizing emulsion to papermaking furnish, pulp, or fiber stock.

Abstract: The present disclosure relates to a preparation method of a super absorbent polymer. More specifically, it relates to a preparation method of a super absorbent polymer capable of significantly reducing the amount of fine powder generated during the process by mixing a hydrogel polymer with an additive having a specific structure, pulverizing it, and then drying it with a paddle-type dryer.

Abstract: The current disclosure provides reinforced aerogel compositions that are durable and easy to handle, have favorable performance in aqueous environments, have favorable insulation properties, and have favorable, reaction to fire, combustion and flame-resistance properties. Also provided are methods of preparing or manufacturing such reinforced aerogel compositions. In certain embodiments, the composition has a silica-based aerogel framework, reinforced with an open-cell macroporous framework, and includes one or more fire-class additives, where the silica-based aerogel framework comprises at least one hydrophobic-bound silicon and the composition or each of its components has desired properties.

Abstract: The present invention relates to a polymeric gel comprising crosslink points, which are dissociated in response to nitrogen monoxide, and to a method for preparing a hydrogel, the method comprising the steps of: a) polymerizing a mixture of monomers comprising a monofunctional hydrophilic monomer and a monomer comprising a plurality of functional groups comprising an o-phenylenediamine residue; and b) separating a hydrogel formed by the polymerization.

Abstract: Two-component polycarbonate-based composite products are contemplated in which the composite is formed as the cured reaction product of a polycarbonate polyurethane dispersed within an aqueous colloid along with a coalescent agent, a secondary polymer additive dispersed within the aqueous colloid, and a secondary polymer crosslinker. The aqueous colloidal dispersion may be applied as a coating to a surface that is intended to be coated and subsequently permitted to react and dry, resulting in the formation of a coating at the location at which it is applied. The composite product may be further formulated with additional constituents to be optically clear, glossy, and/or pigmented.

Abstract: Described herein is a mixer system for producing aqueous coating materials from at least one aqueous pigment paste A, including at least one effect pigment, and at least one pigment-free component B, including an aqueous, acrylate-based microgel dispersion having a glass transition temperature Tg of 50 to 60° C., where both the aqueous pigment paste A and the component B each have a VOC value of less than or equal to 250 g/L. Further described herein is a method for producing aqueous coating materials having a VOC content of 0 to 250 g/L, in which the individual components A and B are stored separately and not mixed until shortly before application, to give the aqueous coating material. Further described herein is a method of using the mixer system of for producing aqueous coating materials for refinishing and/or for coating automobile bodies and/or plastics parts.

Abstract: A method for preparing a carbon nano tube/polyacrylic acid hydrogel, a product and an application thereof are provided. The method includes: oxidizing a carbon nanotube into a carboxylated carbon nanotube, thereafter performing in-situ polymerization with acrylic acid, sodium hydroxide, ammonium persulfate, triethanolamine and N, N-methylenebisacrylamide to obtain a carbon nanotube/polyacrylic acid hydrogel. The hydrogel has a uniform porous structure, facilitating a rapid transmission and supply of water. The carbon nanotubes in the hydrogel are of an array structure, achieving a full absorption of solar energy to realize a high-efficiency photothermal conversion. The gel is attached to a sponge base to obtain a solar-powered carbon nano tube/polyacrylic acid hydrogel steam generator for the photothermal conversion. The steam generator is used for solar seawater desalination, but can improve evaporation rate and evaporation efficiency.

Abstract: An aqueous solution (20) containing carbohydrate for generating smoke consists of 91.9-98.95 wt % of pure water, 1-8 wt % of carbohydrate, and 0.05-0.1 wt % of a water soluble aromatic substance of orange flavor. A method for generating smoke includes preparing an aqueous solution (20) including 91.9-98.95 wt % of pure water, 1-8 wt % of carbohydrate, and 0.05-0.1 wt % of a water soluble aromatic substance of orange flavor; and vibrating the aqueous solution (20) at a high frequency, causing gradual atomization from a surface of the aqueous solution (20) to form droplets containing the carbohydrate and having a diameter in a range of 6-20 ?m.

Abstract: The present invention discloses a spirooxazine photochromic exterior wall coating, comprising the following components by mass percent: 0.6%-1.5% of spirooxazine photochromic compound, 40%-45% of resin, 0.3%-1% of dispersant, 0.2%-0.3% of antifoamer, 1%-3% of additive, 22%-24% of pigment and 30%-32% of solvent. The additive comprises 0.9 wt %-2 wt % of NaCl or KCl solution. The present invention further provides a preparation method for the spirooxazine photochromic exterior wall coating, comprising measuring, grinding, dispersing, mixing, adjusting pH and filtering. Experiments prove that the spirooxazine photochromic exterior wall coating provided by the present invention has good light fatigue resistance effect and can meet the needs of long-term use of building exterior walls.

Abstract: The invention relates to powder coating compositions suitable for low temperature powder coating crosslinking typically at curing temperature is between 75 and 140° C. which can be used for powder coating temperature-sensitive substrates like MDF, wood, plastic or temperature sensitive metal alloys.

Abstract: A process for producing a barrier composition includes subjecting a siloxane compound having 1 to 3 amino groups and an aqueous solution including water and an alcohol to hydrolysis and first-stage condensation under required conditions, subjecting a first colloidal mixture obtained and an additional alcohol to second-stage condensation, subjecting a second colloidal mixture obtained, which has a particular solid content, to heating under required conditions, and subjecting a cured product obtained to aging under required conditions. A barrier composition produced by the process is also disclosed.

Abstract: This disclosure provides, e.g., methods for coupling Formation of Surface Carboxylates on PES an entity to a solid substrate. The method can comprise treating the with Exposure Time substrate with a plasma, e.g., a CO2 plasma, to increase its reactivity. The entity can be, e.g., a biological polymer that binds a microbe. Substrates produced by these methods can be used in a variety of applications, including hemodialysis and diagnostic assays.

Abstract: Polyesters having both ?,?-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoester and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and cure at temperatures less than 230° C. without the use of isocyanates.