Abstract: The present disclosure relates to a process for the processing of perfluoropolymer materials, and to the use of the resultant products in different potential applications, such as in the medical device field. The process can include, for example, the steps of: (i) dissolving one or more uncured perfluoropolymer materials in a solvent containing one or more liquid perfluorinated solvent(s) to form a solution; (ii) optionally adding one or more porogens and/or one or more functional additives to the solution formed in (i) to form a mixture; (iii) applying the resultant solution or mixture formed in steps (i) and (ii) to a substrate to form one or more partial or continuous deposited layers on the substrate; (iv) curing the perfluoropolymer within the deposited layer to form a perfluoroelastomeric product; and (v) optionally removing the porogen from the perfluoroelastomeric product.

Abstract: This invention relates to coating compositions comprising at least one aminoplast crosslinker resin A, binder resins B that have active hydrogen functionality, and a catalyst composition C, wherein the catalyst composition C is a mixture of an organic sulfonic acid C1, and an amine C2 which may be primary, secondary, or tertiary, and which must have a pKa value of not more than 10, and preferably not less than 4, a process for the preparation thereof, and to a method of use thereof.

Abstract: Described herein are processes for producing cold-flexible polyurethane insulation, in which (a) polyisocyanates are mixed with (b) compounds having groups which are reactive to isocyanates, (c) blowing agents, (d) catalysts, (e) plasticizers and optionally (f) further additives to give a reaction mixture and the mixture is applied to a surface and cured to form insulation. Also described herein is a polyurethane insulation obtainable by a process described herein.

Abstract: A method of providing an anticorrosive coating includes applying a first curable liquid layer to the associated substrate, the first layer having a thickness of at least about 100 micrometers, wherein the first layer includes at least one polymer or at least one monomer, quasi-one-dimensional particles or quasi-two-dimensional particles, sacrificial metal particles, and a solvent, wherein a percolation threshold of the particles is not reached in the presence of the solvent, wherein the percolation threshold of the particles is reached when between about 1% and about 20% of the solvent evaporates, applying a second curable liquid layer having a thickness of at least 100 micrometers on the top of the first layer after the percolation threshold of the particles is reached and viscosity of the first layer increases more than 50%, and allowing the first layer and the second layer to cure simultaneously.

Abstract: The present invention provides a selective bonding method of polymer substrates. The present invention allows selective interfacial bonding between a polymer substrate and a parylene layer by using a mask pattern and plasma treatment, and enables the formation of a three-dimensional structure by injecting a fluid into a non-bonded area.

Abstract: Methods have been discovered that make it possible to continuously extrude tubes of P4HB and copolymers thereof. These methods allow tubes of P4HB and copolymers thereof to be produced without radial deformation of the tubes despite the slow crystallization of the polymer and copolymers. The methods can produce tubes of P4HB and copolymers thereof with tightly defined outside and inside diameters which are required for medical application. These tubes are produced by radial expansion at temperatures above the melting temperature of P4HB and copolymers thereof, and using low tube cooling temperatures and prolonged cooling times. The tubes made from P4HB and copolymers thereof are flexible, and can be prepared with high elongation to break values.

Abstract: A coating composition with a stable shelf-life for forming a transparent coating upon eyeglass lenses or other substrates having improved abrasion resistance and tintability. The composition comprising a silicone-based binder component, a curing agent component, and being substantially free of volatiles. The binder component comprises the partial hydrolysis product of an epoxy-functional alkoxysilane, a polyglycidylether, and an acrylic monomer. The curing agent component comprises a cationic photoinitiator and a free radical photoinitiator.

Abstract: A method for preparing an article, the structure of which comprises a substrate of a glass or a glass-ceramic and a coating fixed to at least one portion of the surface of the substrate. In a characteristic way, the coating is generated from at least one loaded polysilsesquioxane resin; the at least one polysilsesquioxane resin not containing any aryl radical in its structure.

Abstract: Provided herein is a method of coating a surface. A silicon-based coating composition is coated onto a surface. The silicon-based coating composition comprises polysilazane and polysilane comprising a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl, which polysilane has a weight average molecular weight of more than 50,000. Also provided are silicon-based coating compositions and cured coatings from those compositions using the provided method.

Abstract: The present invention relates to a method for forming a layered silicate/polymer composite, the composite comprising individual exfoliated silicate layers separated in a continuous polymer matrix, wherein the polymer is a hydrophobic polymer, the method comprising: exfoliating sheet silicate in water to form a silicate suspension; replacing the water in the silicate suspension by an organic solvent to form a silicate/organic solvent suspension; contacting the silicate/organic solvent suspension with a solution of a hydrophobic polymer precursor in an organic solvent to form a silicate/polymer precursor suspension; coating the silicate/polymer precursor suspension on a substrate; removing the organic solvents; curing the hydrophobic polymer precursor of the coating of the silicate/polymer precursor; and annealing the cured coating to form the layered silicate/polymer composite on the substrate.

Abstract: Siliconized fibrous webs are described. The siliconized webs include a fibrous web saturated with an electron beam cured silicone composition. Siliconized webs with electron beam cured silicone coating are also described. Methods of preparing both the coated and uncoated siliconized fibrous webs are also described.

Abstract: The present invention relates to urethane (meth)acrylates comprising residual isocyanate groups which are obtained from the reaction of: a) at least one di- or poly-isocyanate, and b) at least one hydroxyl-functional (meth)acrylic acid ester of at least one polymer chain which comprises: at least one (meth)acryloyl group, at least one free hydroxyl group and at least one polymer chain, wherein the equivalent ratio of OH groups to NCO groups is 0.05:1 to 0.66:1, a process for preparing thereof and their use in radiation-curable coating composition.

Abstract: An EUV photoresist composition includes paramagnetic particles that are adapted to block EUV radiation. The magnetic manipulation of the paramagnetic particles within a deposited layer of EUV photoresist can beneficially impact focus control and the achievable line width roughness during subsequent photolithographic processing. A spin-coating apparatus for dispensing the EUV photoresist composition onto a substrate includes a plurality of concentric electromagnets located beneath the substrate that influence the distribution of the paramagnetic particles in the photoresist layer.

Abstract: A method for producing polymer particles is disclosed in which a fluid preparation is ejected in drop form from a nozzle of an ink jet print head. At least one nozzle ejects droplets in response to electrical signals, and radiation from a radiation source is directed on the droplets in flight, whereby the fluid preparation is at least partially cured by irradiation, so that particles are obtained from the fluid drops before impact or collection. The fluid preparation contains a prepolymer, an oligomer, monomers, or reactive diluents as well as at least one photoinitiator. The fluid preparation has a polymerizable group that is radically polymerizable. Further, a printed product and a device for making the printed product are disclosed. The printed product has a rough polymeric coating that is composed of spherical or largely spherically shaped polymer particles.

Abstract: A method of manufacturing a mineral fiber insulating board comprising i) spraying a formaldehyde free aqueous binder solution onto a plurality of mineral fibers, the aqueous binder solution comprising binder reactants comprising a) a reducing sugar reactant and b) an amine reactant, wherein the reducing sugar reactant is selected from the group consisting of: a reducing sugar; a reducing sugar yielded by a carbohydrate in situ under thermal curing conditions; and combinations thereof, wherein the percent by dry weight of the reducing sugar reactant with respect to the total weight of the binder reactants in the binder solution ranges from about 73% to about 96%, and wherein the percent by dry weight of the amine reactant with respect to the total weight of the binder reactants in the binder solution ranges from about 4% to about 27%, ii) dehydrating the aqueous binder solution such that a dehydrated binder is disposed on the plurality of mineral fibers, and iii) curing the dehydrated binder on the plurality o

Abstract: A method of manufacturing a gas barrier film includes depositing an atomic layer deposition film on a surface of a plastic substrate to form a gas barrier laminate, using atomic layer deposition; depositing a curable resin layer on a support from which the layer is peelable, to form an overcoat laminate; laminating the overcoat laminate to the gas barrier laminate, with the atomic layer deposition film and the curable resin layer facing each other, and transferring the curable resin layer onto the atomic layer deposition film; curing the curable resin layer through application of heat or an active energy beam; and releasing the curable resin layer from the support.

Abstract: Methods for producing cylindrical flexographic printing elements, the cylindrical flexographic printing elements having a relief-forming layer, and the relief-forming layer being produced by successive application of a plurality of layers of a relief-forming material in liquid melt form, preferably of a photopolymerizable material in liquid melt form, to a rotating cylindrical sleeve in a continuous process.

Abstract: This injection molding method uses an injection molding machine for two-material molding, which comprises a first mold part that is provided with a cavity and a second mold part that is provided with a cavity and is arranged in tandem with the first mold part. This injection molding method comprises: a first molding step wherein a material is injected into the cavity of the first mold part and the material in the cavity is compressed; and a second molding step wherein a material is injected into the cavity of the second mold part. A pressure, which is generated in the second mold part by injecting the material into the cavity in the second molding step, acts on the first mold part, and a compressive force is applied to the material in the cavity in the first molding step.

Abstract: This disclosure provides effective methods for expanding the processing window for poly(ethylene furanoate) (PEF) and poly(ethylene furanoate) co-polymer (PEF co-polymer) polyester preforms, such that these preforms can be beneficially used in the fabrication of bottles and containers, including bottles for carbonated soft drinks. The processing window is expanded by, for example, pre-conditioning the PEF or PEF co-polymer preform prior to stretch blow-molding by contacting the PEF or PEF co-polymer preform with water or high (>50%) relative humidity air for a desired time period and at a temperature greater than or equal to ambient temperature, to take advantage of the unique and unexpected properties afforded the preform by water sorption at these temperatures.

Abstract: A method of forming a structure for a downhole application comprises forming an interfacial material comprising at least one of self-reinforced polyphenylene, polyphenylene sulfide, polysulfone, and polyphenylsulfone between opposing surfaces of a first substrate and a second substrate. A downhole structure and a downhole assembly are also described.