Patents Examined by Roberto Rábago
  • Patent number: 9481740
    Abstract: A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.
    Type: Grant
    Filed: March 5, 2015
    Date of Patent: November 1, 2016
    Assignee: Fina Technology, Inc.
    Inventors: Likuo Sun, Jose Sosa, Serge Eon, Carlos Corleto, Scott Cooper
  • Patent number: 9464664
    Abstract: The present invention relates to a polypropylene which has—a melt flow rate MFR(230° C., 2.16 kg) of at least 13 g/10 min,—an amount of xylene solubles XS of 6.0 wt % or less, and—a crystalline fraction, wherein at least 10% of the crystalline fraction melts the temperature range of from 160 to 170° C., as determined by the stepwise isothermal segregation technique (SIST).
    Type: Grant
    Filed: October 5, 2011
    Date of Patent: October 11, 2016
    Assignee: Borealis AG
    Inventors: Saeid Kheirandish, Petar Doshev, Michael Reisecker, David Friel, Sybille Simon
  • Patent number: 9458287
    Abstract: A process for producing an aliphatic polyester, comprising: subjecting at least two serial stages of bulk-phase ring-opening polymerization and a solid-phase polymerization step, wherein a cyclic ester held in a dry air atmosphere is supplied to a first reactor to perform a first stage polymerization, thereby obtaining a partially polymerized molten product, and the resultant partially polymerized molten product is supplied to a second reactor held under a dry inert gas atmosphere to perform a second stage polymerization. As a result, the production efficiency can be improved, while maintaining excellent properties of the aliphatic polyester product.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: October 4, 2016
    Assignee: KUREHA CORPORATION
    Inventors: Yoshinori Suzuki, Fumio Maeda, Takahiro Watanabe, Hiroyuki Sato
  • Patent number: 9458310
    Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g? value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: October 4, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Pradeep P. Shirodkar, Jianya J. Cheng, Andy H. Tsou, Pamela J. Wright, Johannes M. Soulages
  • Patent number: 9458275
    Abstract: A cross-linkable rubber composition containing a carboxyl group-containing nitrile rubber (A) with an iodine value of 120 or less, a polyamine cross-linking agent (B), and a specific basic cross-linking accelerator (C) is provided. The basic cross-linking accelerator (C) is preferably dicyclopentylamine or dicyclohexylamine.
    Type: Grant
    Filed: September 25, 2013
    Date of Patent: October 4, 2016
    Assignee: ZEON CORPORATION
    Inventor: Kentaro Mori
  • Patent number: 9458267
    Abstract: It is an object of the present invention to provide a chlorinated polyolefin resin having favorable adhesion to a polyolefin resin and high solubility in a composition containing an alcohol-based solvent. The present invention provides a chlorinated polyolefin resin that exhibits, in infrared spectroscopy spectrum measurement, a peak area ratio A/B×100 of 10% or higher, a peak area ratio C/B×100 of 30 to 80%, and a peak area ratio A/C×100 of 30% or higher (wherein “A” is the area of a peak resulting from hydroxyl groups, “B” is the area of a peak resulting from methylene groups, and “C” is the area of a peak resulting from carbonyl groups). The present invention also provides an ink composition for gravure printing or flexography that contains the chlorinated polyolefin resin, a printed material obtained using the above composition, and a printing method using the above composition.
    Type: Grant
    Filed: March 19, 2014
    Date of Patent: October 4, 2016
    Assignee: NIPPON PAPER INDUSTRIES CO., LTD.
    Inventors: Isamu Ono, Yuu Kitamura, Takao Yoshimoto, Masanori Tanaka, Shunji Sekiguchi
  • Patent number: 9441060
    Abstract: Provided herein are ethylene copolymers, methods for making such copolymers, and compositions made from such copolymers. The ethylene copolymers have 70 wt. % to 85 wt. % of units derived from ethylene and at least 12 wt. % of units derived from at least one ?-olefin having 3 to 20 carbon atoms. The copolymers preferably further have a weight-average molecular weight (Mw) ranging from about 50,000 to about 200,000 g/mol, melting point of at least 100° C., ratio of Mw/Mn of about 1.5 to about 3.5, a content of group 4 metals of no more than 25 ppm, and a ratio of wt ppm Group 4 metals/wt ppm Group 5 metals of at least 3. Such copolymers may be particularly useful as viscosity modifiers for lubricating oil compositions.
    Type: Grant
    Filed: November 22, 2013
    Date of Patent: September 13, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Rainer Kolb, Donna J. Crowther, Peijun Jiang
  • Patent number: 9428672
    Abstract: The present invention provides a crosslinking aid comprising triallyl isocyanurate (TAIC), which serves for obtaining an adhesive resin exhibiting excellent insulation properties while maintaining good transparency, adhesive properties, heat resistance and flexibility of conventional crosslinked ethylene-vinyl acetate copolymers. The crosslinking aid of the present invention comprises a urethane poly(meth)acrylate in combination with triallyl isocyanurate.
    Type: Grant
    Filed: February 21, 2014
    Date of Patent: August 30, 2016
    Assignee: NIPPON KASEI CHEMICAL COMPANY LIMITED
    Inventors: Mabuko Yamaura, Yukio Orikasa, Kazuya Senzaki
  • Patent number: 9428594
    Abstract: The present invention pertains to a polyethylene polymer characterized by the following properties: A number average molecular weight Mn of at least 2.0*105 g/mol, a weight average molecular weight of at least 2.0*106 g/mol, a Mw/Mn ratio of above 6, and a strain hardening slope of below 0.10 N/mm at 135° C. It has been found that a polymer with these properties have be converted through solid state processing into films and fibers with good properties. A solid state processing process, films and fibers, and their use are also claimed.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: August 30, 2016
    Assignee: TEIJIN ARAMID B.V.
    Inventors: Sanjay Rastogi, Sara Ronca, Giuseppe Forte, Hendrik Jacob Tjaden
  • Patent number: 9428592
    Abstract: Provided are new partially hydrogenated nitrile rubbers which are distinguished by a specific ratio of viscosity to molecular weight, and also vulcanizable mixtures and vulcanizates based on said rubbers, and also the associated preparation processes. The partially hydrogenated nitrile rubbers lead to compounded formulations having advantageous processing properties in conjunction with excellent vulcanizate properties.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: August 30, 2016
    Assignee: LANXESS Deutschland GmbH
    Inventors: Werner Obrecht, Julia Maria Müller, Oskar Nuyken, Martin Schneider
  • Patent number: 9422385
    Abstract: This invention relates to polyethylene copolymers comprising ethylene and vinyl terminated macromonomers. The polyethylene copolymers are achieved by copolymerization of ethylene and vinyl terminated macromonomers in a polymerization reactor, particularly in high yields and with a wide range of VTM molecular weights, that can be made at commercial rates.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: August 23, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Peijun Jiang
  • Patent number: 9422425
    Abstract: The present invention is a method for producing a film particularly well suited for shrink film applications, said method comprising the steps of selecting a target polyethylene resin and then increasing the melt strength of the polyethylene resin by reacting the polyethylene resin with an alkoxy amine derivative, and then forming a film from the reacted target polyethylene.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: August 23, 2016
    Assignees: Dow global Technologies LLC, Dow Brasil S.A.
    Inventors: Teresa P. Karjala, Nicolas Cardoso Mazzola, Mehmet Demirors, Jorge Caminero Gomes, Michael A. Terrasa
  • Patent number: 9416210
    Abstract: The invention generally relates to zwitterionic polymers (including zwitterionic copolymers), such as polymethacrylic structures, with pendent functional moieties, such as therapeutic or biologic moieties. More particularly, the invention relates to phosphorylcholine-substituted methacrylic polymers prepared by free radical polymerization and click chemistry, for example, and compositions and products comprising same, as well as related methods and uses of the compositions, for example, as biological or therapeutic agents and in drug delivery thereof.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: August 16, 2016
    Assignee: THE UNIVERSITY OF MASSACHUSETTS
    Inventors: Todd Emrick, Xiangji Chen, Samantha McRae
  • Patent number: 9416262
    Abstract: Heterophasic propylene copolymer comprising —a matrix (M) being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate MFR2 (230° C.) and at least one of the three polypropylene fractions has a melt flow rate MFR2 (230° C.) in the range of 1.0 to 15.0 g/10 min, and —an elastomeric propylene copolymer dispersed in said matrix, wherein —the heterophasic propylene copolymer has a melt flow rate MFR2 (230° C.) of equal or more than 20.0 g/10 min, and —the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.
    Type: Grant
    Filed: August 1, 2011
    Date of Patent: August 16, 2016
    Assignee: BOREALIS AG
    Inventors: Cornelia Kock, Petar Doshev, Elisabeth Potter, Guenter Gsellmann, Pauli Leskinen
  • Patent number: 9404024
    Abstract: An adhesive composition includes an acrylic copolymer having at least one alkyl group, at least one hydroxyl group, and at least one furyl based group; and a curing agent.
    Type: Grant
    Filed: June 16, 2014
    Date of Patent: August 2, 2016
    Assignee: CHEIL INDUSTRIES, INC.
    Inventors: Kyoung Jin Ha, Irina Nam, Lee Jun Kim, Kil Sung Lee, Eun Hwan Jeong, Woo Jin Jeong
  • Patent number: 9394380
    Abstract: The present invention relates to a modified polymer obtained by grafting of a compound comprising at least one group Q and at least one group A, bonded together by at least, and preferably, one “spacer” group Sp in which: Q comprises a dipole containing at least, and preferably, one nitrogen atom, capable of being grafted onto the polymer chain by [1,3]-dipolar cycloaddition, A comprises an associative group comprising at least one nitrogen atom, Sp is an atom or a group of atoms forming a bond between Q and A.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: July 19, 2016
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: José Araujo Da Silva, Jean-Michel Favrot, Anne Frédérique Salit, Nicolas Seeboth
  • Patent number: 9376557
    Abstract: A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.942 to 0.970 g/cm3 and an HLMI of from 0.5 to 150 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a chromium catalyst in a reactor. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product. The homogeneous polyethylene product can include at least 25% by weight of the first polyethylene resin.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: June 28, 2016
    Assignee: Total Research & Technology Feluy
    Inventors: Daan Dewachter, Eric Damme
  • Patent number: 9371442
    Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, stiffness, and environmental stress crack resistance. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.
    Type: Grant
    Filed: August 18, 2015
    Date of Patent: June 21, 2016
    Assignee: NOVA Chemicals (International) S.A.
    Inventor: XiaoChuan Wang
  • Patent number: 9372282
    Abstract: Disclosed are improved ophthalmic and otorhinolaryngological device materials and devices formed therewith. The device materials are soft, high refractive index styrenic device materials that are used to form the ophthalmic or otorhinolaryngological devices, particularly ophthalmic implants (e.g., intraocular lenses).
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: June 21, 2016
    Assignee: Novartis AG
    Inventors: Xuwei Jiang, Walter R. Laredo
  • Patent number: 9346901
    Abstract: Chlorinated vinyl chloride resin may be produced through a heat chlorination reaction of an aqueous suspension of vinyl chloride resin in a hermetically sealable reaction vessel, the method including carrying out a first heat chlorination reaction while raising the temperature of an aqueous suspension of a vinyl chloride resin powder to a predetermined temperature within the range of 85° C. to 95° C., and subsequently carrying out a second heat chlorination reaction at the predetermined temperature.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: May 24, 2016
    Assignee: TOKUYAMA SEKISUI CO., ;TD.
    Inventor: Masatoshi Harada