Patents Examined by Sam Acquah
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Patent number: 5292865Abstract: Process for simultaneous removal of aldehyde, solid-phase postcondensation and drying of linear polyesters and copolyesters by after-treating the polyester pellets with a diffusion surface of 1.95 to 2.90 m.sup.2 /kg, an individual pellet weight of 5 to 15 mg and a bulk density of 750 to 900 kg/m.sup.3 at 140.degree. to 210.degree. C. with a flow of a dry gas mixture consisting of 60-90 vol % N.sub.2, 5-21% O.sub.2 and 0.1-25% CO.sub.2 (total 100%) at a quantity ratio of 0.5 to 2.5 kg/h gas mixture per kg/h polyester.Type: GrantFiled: December 3, 1992Date of Patent: March 8, 1994Assignee: Zimmer AktiengesellschaftInventors: Hans Kerpes, Ulrich Thiele
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Patent number: 5290631Abstract: Hydrosoluble/hydrodispersible polyester copolycondensates, well suited for the sizing of textile threads, comprise terephthalate, isophthalate, sulfoaryl dicarboxylate, ethylene glycol and polyoxyethylene glycol recurring structural units, have a glass transition temperature ranging from 15.degree. to 40.degree. C. at 85% relative humidity and the turbidity of aqueous formulations thereof are storage-stable over time; such polyester copolycondensates are conveniently prepared by (i) transesterifying admixture of dimethyl terephthalate, dimethyl sulfoaryl dicarboxylate and ethylene glycol, (ii) introducing isophthalic acid and an additional amount of ethylene glycol into the medium of transesterification and therein directly esterifying same, and (iii) polycondensing the resulting product of transesterification/direct esterification.Type: GrantFiled: October 29, 1992Date of Patent: March 1, 1994Assignee: Rhone-Poulenc ChimieInventors: Etienne Fleury, Yvette Girardeau
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Patent number: 5288559Abstract: Provided is a coating composition for a two-piece can containing a polyester resin (A) consisting essentially of terephthalic acid and propylene glycol and containing tri- or more functional polycarboxylic acid or polyol comonomer(s) and an alkyl-etherified aminoformaldehyde resin (B); and the coating film (C) to be obtained by reacting these (A) and (B) in the composition has larger tensile strength and elongation than the film made of only (A). The coating composition is coated on at least one surface of a metal sheet to give a coated metal sheet for a two-piece can. The coated metal sheet may be formed into a drawn and ironed can or a drawn and re-drawn can. The adhesiveness of the coated film to the metal sheet is high, and the coated film has excellent resistance to blistering and resistance to whitening and has excellent flavor preservability.Type: GrantFiled: October 15, 1992Date of Patent: February 22, 1994Assignee: Toyo Boseki Kabushiki KaishaInventors: Masami Oka, Takao Aoki, Hiroshi Fujimoto, Hiroshi Tachika
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Patent number: 5288804Abstract: A composition comprising a first component including a compound comprising at least two acetoacetate groups, and a second component including a compound comprising at least two groups which will react with an acetoacetate group, at least one of which is an aromatic aldimine group having a relatively low reactivity with water when compared with its reactivity with an acetoacetate group.The components may be premixed in water prior to application.The invention further includes a product comprising a cured blend of the two components. The product of the invention is usually a coating or film.Type: GrantFiled: January 3, 1992Date of Patent: February 22, 1994Assignee: Reichhold Chemicals, Inc.Inventors: Kyu-Jun Kim, Roy C. Williams
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Patent number: 5286835Abstract: Vinyl ether terminated ester oligomers having a range of molecular weights are prepared by reacting a vinyl ether terminated polybasic ester with a polyol in the presence of a catalyst. Continual removal of a hydroxy monovinyl ether avoids formation compounds containing acetal moieties. Alternatively, a polybasic ester is chain extended with a polyol with continual removal of the alcohol by-product. Then, the terminal ester moieties are end capped with a monohydroxy vinyl ether. The oligomers have application in coatings and the like.Type: GrantFiled: August 24, 1992Date of Patent: February 15, 1994Assignee: Allied-Signal Inc.Inventors: George D. Green, James R. Snyder, Darryl K. Barnes
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Patent number: 5271855Abstract: The invention is a processing aid for thermoplastic polyesters which is a salt of a polycarboxylic acid or the salt of a polycarboxylic partial ester. The polycarboxylic acids are partial esters or sales of modified acids such as succinic acid, adipic acid, phthalic acid, citric acid, dicarboxylphenyl group and the like. The addition of the processing aid improves the slip and transparency.Type: GrantFiled: November 2, 1992Date of Patent: December 21, 1993Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rainer Hoefer, Dieter Krampitz, Andreas Lippmann
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Patent number: 5270439Abstract: A method of producing a curable composition containing a prepolymer having a polythioether skeleton, characterized by comprising addition reacting (A) 4,4'-bis(methacryloylthio)-diphenylsulfide having the formula (I): ##STR1## wherein R is a polyvalent organic group composed of an aliphatic or aromatic hydrocarbon and n represents an integer of 2 or more, with the functional group equivalent ratio of the mercapto groups of the component (B) (ii) to the methacryloyl groups of the component (A) being from 0.02 to 1.01, in another vinyl monomer copolymerizable with 4,4'-bis(methacryloylthio)diphenylsulfide having the above formula (I) in the presence of a base catalyst.Type: GrantFiled: September 28, 1992Date of Patent: December 14, 1993Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Satoshi Maruyama, Naoki Minorikawa, Tsutomu Arakawa, Haruo Yoshida, Hirotaka Tagoshi, Kazuto Abe
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Patent number: 5270444Abstract: According to the present invention, a process which comprises bringing polyethylene terephthalate having an intrinsic viscosity of at least 0.50 dl/g and a density of 1.38 g/cm.sup.3 or more into contact with water is provided.In the water-treated polyethylene terephthalate obtained in the present invention, amounts of oligomers and acetaldehyde formed at the time of molding said polyethylene terephthalate into molded articles are small, and the contamination of the mold therewith is difficult to occur and further the contents of said molded articles does not change in flavor and fragrance.Type: GrantFiled: March 12, 1993Date of Patent: December 14, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shigemi Shiraki, Yasuhiro Tanaka, Masayuki Sakai
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Patent number: 5268445Abstract: The invention relates to segmented copolyesteramides built up from units derived from one or more flexible segments, 1,4-butanediol, 1,4-butanediamine and terephthalic.Type: GrantFiled: June 24, 1992Date of Patent: December 7, 1993Assignee: General Electric CompanyInventors: Reinoud J. Gaymans, Jeannette L. Haan
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Patent number: 5262157Abstract: Pneumocystis carinii pneumonia may be prevented in a subject susceptible to infection by Pneumocystis carinii by administering to the subject an amount of a pentamidine in aerosol form effective to prevent infection by Pneumocystis carinii and thus prevent Pneumocystis carinii pneumonia. Also, this invention provides a composition for the prevention of Pneumocystis carinii pneumonia which comprises an amount of a pentamidine effective to prevent infection by Pneumocystis carinii and thus prevent Pneumocystis carinii pneumonia in aerosol form and a pharmaceutically acceptable carrier.Type: GrantFiled: December 20, 1988Date of Patent: November 16, 1993Assignee: Sloan-Kettering Institute for Cancer ResearchInventors: Edward M. Bernard, Donald Armstrong
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Patent number: 5260405Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.Type: GrantFiled: October 26, 1992Date of Patent: November 9, 1993Assignee: Rutgerswerke Aktiengesellschaft AGInventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
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Patent number: 5254639Abstract: A binding agent for molded bodies and molding compositions produced by prereacting a mixture of 5 to 60% by weight of lignin or a lignin fraction produced by the Organosolv process and 40 to 95% by weight of a phenol novolac resin and subjecting the latter to high shear forces in a kneader or extruder and optionally mixing the same with a curing agent useful in molding compositions and high temperature-stable molded products such as refractory products, friction coatings, textile fleeces and carbon or graphite materials.Type: GrantFiled: October 26, 1992Date of Patent: October 19, 1993Assignee: Rutgerswerke Aktiengesellschaft AGInventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
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Patent number: 5219980Abstract: The invention presents a biodegradable polyester polymer comprising ##STR1## wherein: n=number of repeating polymer units of the formula shown; p=0 or 1, 0 indicating the absence of the subscripted constituent; q=0 or 1, 0 indicating the absence of the subscripted constituent; when p=0, 1=1; when p=1, 1=0; R.sup.1 =a divalent organic substituent which can include oxygen, nitrogen or sulfur atoms as part of the polymer backbone; R.sup.2 =a divalent organic substituent which can include oxygen, nitrogen or sulfur atoms as part of the polymer backbone; R.sup.3 and R.sup.4 are each independently hydrogen or an organic substituent or together form a divalent ring which may be optionally substituted; and each R is independently H, alkyl, alkenyl or alkynyl, aryl, aralkyl, cycloalkyl, cycloalkenyl or cycloalkynyl, all optionally substituted with F, Cl, Br, I, CN or NO.sub.2.Type: GrantFiled: April 16, 1992Date of Patent: June 15, 1993Assignee: SRI InternationalInventor: Ronald Swidler
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Patent number: 5219979Abstract: New polyoxazolidines can be defined with the general formula: ##STR1## where R, R.sub.1, R.sub.2 and n have the meaning specified in the description. These polyoxazolidines are useful cross-linking agents for hydrocuring systems based on polyisocyanates, acrylate polymers and polyepoxides, in compositions for paints, coatings, sealants and adhesives.Type: GrantFiled: February 10, 1992Date of Patent: June 15, 1993Assignee: Enichem Synthesis S.p.A.Inventor: Alberto Greco
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Patent number: 5215825Abstract: A polyester film comprising a polyester whose dicarboxylic acid copolymerized component contains (i) an aromatic dicarboxylic acid having a metal sulfonate and/or a derivative thereof and (ii) a polyetherdicarboxylic acid represented by the following chemical formula (a) and having a mean molecular weight in the range of 600 to 20000 and/or a derivative thereof.R.sup.1 OOCCH.sub.2 --(O--R.sup.2).sub.n --OCH.sub.2 COOR.sup.3 (a)Where, "R.sup.1 " and "R.sup.3 " are H or alkyl groups each having a carbon number of 1 to 8, "R.sup.2 " is alkylene group having a carbon number of 2 to 8 and "n" is a positive integer. The polyester film has excellent transparency, mechanical properties and dimensional stability such as those of a PET film and an excellent water absorption property such as that of a TAC film.Type: GrantFiled: December 18, 1991Date of Patent: June 1, 1993Assignee: Toray Industries, Inc.Inventors: Toshihiko Hiraoka, Kenji Tsunashima, Masaru Suzuki, Takashi Mimura, Hirokazu Kurome
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Patent number: 5216090Abstract: A thermosetting powder coating composition having improved optical properties, such as orange peel, gloss and Distinctness of Image (DOI), which includes a reactable mixture of a carboxylic acid group-containing polyester or acrylic, a fatty acid hydroxyalkylamide group-containing material and beta-hydroxyalkylamide curing agent.Type: GrantFiled: July 27, 1992Date of Patent: June 1, 1993Assignee: Rohm and Haas CompanyInventors: Richard F. Merritt, Kurt A. Wood, Aurelia de la Cuesta Sheppard
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Patent number: 5213856Abstract: Copolyesters having an improved combination of barrier, mechanical, thermal and rheological properties and consisting of acylic and glycolic radicals, wherein the acylic radicals derive from at least isophthalic acid and 2,6-naphthalene dicarboxylic acid and at least 90% by mols of the glycolic radicals derive from ethylene glycol.Type: GrantFiled: December 20, 1991Date of Patent: May 25, 1993Assignee: Istituto Guido Donegani S.p.A.Inventors: Riccardo Po', Paolo Cioni, Ernesto Occhiello, Fabio Garbassi
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Patent number: 5213891Abstract: Block copolyetheramides, well adopted for conversion into a wide variety of useful thermoplastic elastomer shaped articles, have the formula: ##STR1## in which D is the residue of a diacid oligamide having an Mn ranging from 300 to 3,000 and/or the residue of the diacid chain limiter, PE is the residue of a polyetherdiol having an Mn ranging from 200 to 5,000,.times.is a straight or branched chain (cyclo)aliphatic or aromatic hydrocarbon having from 4 to 20 carbon atoms, n is a number ranging from 1 to 4, and m is an average number ranging from 2 to 50; these are prepared by polycondensing a multiblock polymer having the formula: ##STR2## with a diamine H.sub.2 N--X--NH.sub.2.Type: GrantFiled: January 30, 1992Date of Patent: May 25, 1993Assignee: Elf Atochem S.A.Inventors: Philippe Maj, Daniel Cuzin
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Patent number: 5204418Abstract: A light-weight polyester film which comprises (A) from 50 to 95% by weight of a crystalline polyester resin and (B) from 5 to 50% by weight of a maleimide copolymer, said maleimide copolymer being dispersed in the film in the form of particles having diameters of from 0.1 to 20 .mu.m and fine voids being present in the film, and which has an apparent specific gravity of from 0.3 to 1.1, wherein said maleimide copolymer comprises from 30 to 50 mol % of a maleimide monomer group, from 30 to 70 mol % of an aromatic vinyl monomer group, from 0 to 40 mol % of an unsaturated dicarboxylic anhydride monomer group and from 0 to 40 mol % of other copolymerizable monomer group, and said maleimide copolymer has a glass transition temperature higher by at least 10.degree. C. than the crystalline polyester resin.Type: GrantFiled: January 30, 1992Date of Patent: April 20, 1993Assignee: Unitika Ltd.Inventors: Kenji Yasue, Eiji Y. Yamamoto, Katsuyuki Toma, Minoru Kishida, Yoshiaki Kozuka
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Patent number: 5198529Abstract: A high molecular weight unsaturated polyester having a number-average molecular weight of 5,000 or greater, the polyester being represented by a general formula: ##STR1## wherein G denotes a glycol residue, m denotes 1 to 10, n denotes 1, and M denotes a number corresponding to a number-average molecular weight greater than 5,000. The high molecular unsaturated polyester of the present invention is an unsaturated polyester having a large molecular weight unattainable by conventional methods, and can find wide application by utilizing its improved physical properties.Type: GrantFiled: November 18, 1991Date of Patent: March 30, 1993Assignee: Showa Highpolymer Co., Ltd.Inventors: Eiichiro Takiyama, Yositaka Hatano