Abstract: It has been desired to develop a method for producing an oxymethylene polymer, by which an oxymethylene polymer having a high polymerization degree can be produced with high efficiency while suppressing increase in the amount of generation of an odor. Further, it has been desired to develop an oxymethylene polymer resin composition, wherein generation of an odor at the time of molding or after molded to obtain a molded body is suppressed. The present invention provides a method for producing an oxymethylene polymer, wherein the oxymethylene polymer is produced by polymerizing a cyclic oligomer of formaldehyde, and wherein a boron trifluoride compound and an aryl fluoride boron compound are used as polymerization catalysts. The present invention also provides an oxymethylene polymer resin composition containing an oxymethylene polymer and a derivative of an aryl fluoride boron compound.
Abstract: The present invention is directed to an addition polymer comprising an addition polymer backbone; at least one moiety comprising a sulfonic acid group; and at least one carbamate functional group. The present invention is also directed towards methods of making the addition polymer, aqueous resinous dispersions comprising the addition polymer, methods of coating a substrate and coated substrates.
Type:
Grant
Filed:
June 27, 2019
Date of Patent:
April 26, 2022
Assignee:
PRC-DeSoto International, Inc.
Inventors:
Christopher A. Dacko, Michael A. Mayo, Gregory J. McCollum
Abstract: A heat energy storage system may have a shape-stabilized composite prepared using an easy impregnation method involving a porous Ca2+-doped MgCO3 matrix and PEG as the functional phase. The heat storage capability, microstructures, and interactions with the PEG/CaMgCO3 composite can be characterized by DSC, SEM imaging, FT-IR spectroscopy, and TGA. Likely because of the synergistic phase change effect of CaMgCO3 and PEG, the PEG/CaMgCO3 composites can have high thermal enthalpies, and their enthalpy efficiencies are substantially higher than those of traditional shape stabilized PCMs. The functional material PEG can permeate porous CaMgCO3 matrices under capillary action. Liquid PEG can be stabilized within the porous matrix, and/or the CaMgCO3 matrix can improve the thermal stability of the PEG. The high heat energy storage properties and good thermal stability of such organic-inorganic composites offers utility in a range of applications, including thermal energy storage.
Type:
Grant
Filed:
February 19, 2020
Date of Patent:
April 19, 2022
Assignee:
King Fahd University of Petroleum and Minerals
Inventors:
Md. Hasan Zahir, Mohammad Mizanur Rahman
Abstract: There is provided a water-based resin composition that contains a polymer (A) containing, as essential raw materials, a hydrogenated polybutadiene (a1) with an iodine value in the range of 5 to 25, a monomer (a2) with an acid group, and a monomer (a3) with a hydroxy group, a basic compound (B), and an aqueous medium (C), wherein the hydrogenated polybutadiene (a1) constitutes 4% to 38% by mass of the raw materials of the polymer (A), and the polymer (A) has an acid value in the range of 10 to 65 mgKOH/g. A water-based resin composition of the present invention has high storage stability and forms a coating film with good physical properties, such as high adhesiveness to various substrates and high blocking resistance, and is therefore suitably used in a water-based paint.
Abstract: The present invention improves the long-term storage stability of an organoborane-Lewis base complex. First composite particles of the present invention include particles of an organic polymer (B), and an organoborane-Lewis base complex (A) contained in the particles. Second composite particles of the present invention include particles of an inorganic compound (B?), and an organoborane-Lewis base complex (A) adsorbed on the particles.
Abstract: The present invention is directed to a compound of formula I, wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5), wherein R5 comprises a monovalent organic group. The present invention is also directed towards polymers comprising a pendant carbamate-functional moiety comprising the structure: wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5) wherein R5 comprises a monovalent organic group. The present invention is also directed to methods of preparing such compounds and polymers, compositions comprising such polymers, and coatings produced from such compositions.
Abstract: Provided is a thermosensitive phosphazene-based polymer including an amino acid ester moiety, a polyethyleneglycol moiety, and a moiety including a sulfate group linked directly or by a linker in a predetermined ratio, a method of preparing the same, and a hydrogel-formable composition including the same. For example, a hydrogel formed from the composition may be used for tissue regeneration or drug delivery or used as a storage, a body tissue regeneration inducer, or a filler in a body.
Type:
Grant
Filed:
August 9, 2019
Date of Patent:
March 1, 2022
Assignee:
KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
Abstract: The present invention relates to a modified polymerization initiator for a conjugated diene-based polymer, and a modified conjugated diene-based polymer including a functional group derived from the modified polymerization initiator.
Type:
Grant
Filed:
August 21, 2018
Date of Patent:
February 22, 2022
Inventors:
Jung Yong Lee, Jae Hoon Choe, Dong Cheol Choe, Jong Young Choi, Won Jae Lee, Hyeon Hui Kim
Abstract: A coating of an outer plate contains a perylene-based pigment, and satisfies (ROH(P)/ROH(OA))?74, where ROH(P) is the highlight reflectance of the coating of the outer plate at a peak wavelength at which reflectance reaches the maximum value in a spectral reflectance curve, and ROH(OA) is the average highlight reflectance of the coating of the outer plate in a complementary wavelength range. A coating of an inner plate part contains a perylene-based pigment and an iron oxide-based pigment, the content of the perylene-based pigment in the coating of the inner plate part is in units of PWC, and the mass ratio of the content of the iron oxide-based pigment to the content of the perylene-based pigment in the coating of the inner plate part is 3-20%.
Abstract: A resin emulsion for a coating material, which contains emulsion particles each having an inner layer and an outer layer, and wherein: each emulsion particle has a resin layer containing a polymer (I) that is obtained by emulsion polymerizing a monomer component A containing 80 to 100% by mass of a styrene monomer and 0 to 20% by mass of a monomer other than the styrene monomer and a resin layer containing a polymer (II) that is obtained by emulsion polymerizing a monomer component B containing 70 to 100% by mass of a (meth)acrylic acid ester and 0 to 30% by mass of a monomer other than the (meth)acrylic acid ester; and the content of the styrene monomer in all monomer components used as starting materials for the emulsion particles is 10 to 55% by mass.
Abstract: The present invention relates to a copolymer including 20 to 65 wt % of units derived from an alkyl styrene-based monomer; 10 to 40 wt % of units derived from a (meth)acrylate-based monomer; and 20 to 40 wt % of units derived from vinyl cyan-based monomer, based on the total weight of the copolymer, wherein the residual monomer content is 780 ppm or less, and a method for preparing the same.
Type:
Grant
Filed:
July 26, 2018
Date of Patent:
November 23, 2021
Assignee:
LG CHEM, LTD.
Inventors:
Jae Bum Seo, Dae Woo Lee, Jung Tae Park, Gyu Sun Kim, Ji Uk Jang
Abstract: Provided are an irreversibly discoloring pigment for preventing overheating, a thermochromic molded article including the same, and a method of preparing the same, and more particularly, a discoloring pigment which becomes discolored when overheated, and then maintains the discoloration even after being cooled to room temperature, a thermochromic molded article including the discoloring pigment, and methods of preparing the discoloring pigment and the thermochromic molded article.
Abstract: Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) for fabricating the object, in combination with acid-activatable pre-catalyst and an acid generator activator. Kits containing modeling material formulations usable in the methods are also provided.
Type:
Grant
Filed:
February 5, 2017
Date of Patent:
September 14, 2021
Assignee:
Stratasys Ltd.
Inventors:
Yuval Vidavsky, Ira Yudovin-Farber, Asher Razlan, Lev Kuno, Gilles Recher, Renata Drozdzak-Matusiak
Abstract: Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
Type:
Grant
Filed:
March 10, 2019
Date of Patent:
September 14, 2021
Assignee:
Bridgestone Corporation
Inventors:
Xiao-Dong Pan, Zengquan Qin, Yuan-Yong Yan, Dennis R. Brumbaugh
Abstract: In some examples, a braze material includes a first set of particles, a second set of particles, and a polymeric binder. The first set of particles includes a braze powder, where the braze powder comprises an Si-containing alloy. The first set of particles defines an average or median particle diameter between about 1 ?m and about 40 ?m. The second set of particles includes at least one of SiC or a transition metal carbide, where the second set of particles has a multimodal particle size distribution.
Type:
Grant
Filed:
September 21, 2018
Date of Patent:
September 7, 2021
Assignee:
Rolls-Royce Corporation
Inventors:
Scott Nelson, Raymond Ruiwen Xu, Sean E. Landwehr, Daniel Kent Vetters, Samantha Tatar
Abstract: The present invention provides a hybrid supported catalyst capable of easily preparing an olefin polymer capable of having improved melt strength even while having appropriate molecular weight distribution, and thus having improved bubble stability and exhibiting excellent blown film processability, and a method for preparing an olefin polymer using the same.
Type:
Grant
Filed:
August 18, 2017
Date of Patent:
August 17, 2021
Inventors:
Sung Ho Park, Heon Yong Kwon, Hyun Jee Kwon, Jin Young Lee, Ki Soo Lee, Dae Sik Hong, Sol Cho, Oh Joo Kwon
Abstract: The present invention provides moldable compositions that are capable of resisting slumping and cracking when allowed to dry and harden. Embodiments of the moldable composition comprise water, fillers including arrowroot and kaolin clay, at least one polar polymeric resin (e.g., polyvinyl alcohol), at least one thickening agent (e.g., ammonium pentaborate tetrahydrate), one or more pH adjusters (e.g., triethanolamine, sodium bicarbonate), a humectant (e.g., propylene glycol, glycerin), optionally at least one releasing agent (e.g., mineral oil), and optionally at least one additive.
Type:
Grant
Filed:
May 2, 2018
Date of Patent:
August 10, 2021
Assignee:
Crayola LLC
Inventors:
Michael G. Moskal, Anthony C. Drago, III, David E. Rowan, Michael L. Spera, Eric Alexander Boschi
Abstract: [Problem] To provide a film forming composition curable at low temperature and a film forming method using the same. [Means for Solution] A film forming composition comprising a polysilazane, an organic solvent and aspecific additive, and a film forming method comprising applying it on a substrate and curing. The specific additive is selected from the group consisting of (A) guanidines substituted by a hydrocarbylgroup, (B) crown ether amines containing oxygen and nitrogen as a member thereof, (C) cycloalkanes having an amino-substituted polycyclic structure, (D) oximes substituted by a hydrocarbyl group, and (E) imidazolines.
Abstract: Disclosed is a rubber composition for protecting a sidewall of a tire from ozone and a tire manufactured using the same. More specifically, disclosed is a tire including a rubber sheet for preventing aging between a sidewall and a carcass, wherein the rubber sheet for preventing aging includes a rubber composition including 100 parts by weight of a base rubber, 20 to 60 parts by weight of carbon black, and 2 to 5 parts by weight of an amine-based anti-aging agent. The tire produced from the rubber composition has an effect of exhibiting significantly improved ozone resistance without changing a degree of blackness in terms of appearance.
Abstract: Provided is a thermoplastic resin composition which has improved ultraviolet absorbing capability, mechanical characteristics, hydrolysis resistance, transparency, and blooming resistance and is used for protecting an article used outdoors from ultraviolet light. A problem is solved by a thermoplastic polyurethane resin composition which is a reaction product of an isocyanate component (A1) containing an aliphatic polyisocyanate, a chain extender (A2), and a polyol component (A3) containing a polycarbonate diol having a side-chain alkyl group and contains an ultraviolet absorber (B1) having a benzotriazole skeleton, an ultraviolet absorber (B2) having a maximum absorption wavelength in a range from greater than or equal to 250 nm to less than or equal to 290 nm and having a triazine skeleton, a hindered amine light stabilizer (C), and an antioxidant (D).