Patents Examined by Scott L. Hertzog
  • Patent number: 5755869
    Abstract: In accordance with the present invention, metal pigments are provided which are normally reactive with water or moisture to release hydrogen gas ("gassing") and which have been stabilized against such gassing by having their surfaces treated with an adduct of a maleinized fatty acid and/or a maleinized alpha-olefin and a polyol. Waterborne film-forming compositions which comprise an aqueous diluent medium, a film-forming polymer, and metal pigment stabilized against gassing by treatment with an adduct of a maleinized fatty acid or a maleinized alpha-olefin and a polyol are also provided.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: May 26, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Kurt G. Olson, James E. Poole, Paul H. Lamers
  • Patent number: 5755874
    Abstract: Process for preparing linear unsubstituted .beta.-phase quinacridone pigments A process for preparing linear unsubstituted .beta.-phase quinacridone pigments or pigment preparations, which comprisesa) cyclizing 2,5-dianilinoterephthalic acid in polyphosphoric acid or polyphosphoric ester with a phosphorus pentoxide content of at least 84% by weight to form the quinacridone,b) subsequently hydrolyzing this quinacridone with water or with an aqueous mineral acid solution, preferably orthophosphoric acid solution, at a temperature of at least 40.degree. C., preferably from 60.degree. to 105.degree. C., to form the crude quinacridone pigment which is predominantly in the .alpha.-phase,c) then heating the crude .alpha.-phase quinacridone pigment to a temperature between 120.degree. and 200.degree. C. in the presence of a from 0.1 to 3% strength by weight, preferably from 0.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: May 26, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Urban, Dieter Schnaitmann
  • Patent number: 5755872
    Abstract: A process for preparing quinacridone pigmentsA process for preparing pigments, mixed crystal pigments and pigment preparations based on linear unsubstituted or substituted quinacridones of the formula (I) ##STR1## in which the substituents R.sup.1 and R.sup.2 are identical or different and are hydrogen, chlorine, bromine or fluorine atoms or are C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or carboxamido groups which may be substituted by C.sub.1 -C.sub.6 -alkyl groups; or are phenoxy or C.sub.6 -C.sub.10 -aryl rings onto which further aromatic, aliphatic or heterocyclic rings can be fused, which process comprises hydrolyzing the reaction mixture resulting from cyclization of the respective dianilinoterephthalic acid with polyphosphoric acid or polyphosphate at a temperature of or above 110.degree. C.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: May 26, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Urban, Dieter Schnaitmann, Martin Bohmer
  • Patent number: 5753022
    Abstract: A method of preparing a non-aqueous dispersion of CuPc which comprises milling crude CuPc in a high boiling liquid at a temperature from 50.degree. to 150.degree. C. in the presence of a polyester amine or polyesterammonium salt and a CuPc fluidising agent. Preferred polyesterammonium salt is obtainable by reacting polyhydroxystearic acid with 3-dimethylaminopropylamine quaternised with dimethylsulphate.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: May 19, 1998
    Assignee: Zeneca Limited
    Inventors: John David Schofield, Dean Thetford
  • Patent number: 5753030
    Abstract: This invention relates to pigment compositions prepared by precipitating a blend of (a) about 60 to about 95 percent by weight of a perylene pigment having the formula ##STR1## wherein R.sup.1 and R.sup.2 are independently C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.7 cycloalkyl, C.sub.7 -C.sub.16 aralkyl, or C.sub.6 -C.sub.10 aryl; and (b) about 5 to about 40 percent by weight of a polycyclic aromatic compound containg at least 5 aromatic rings wherein at least one ring is substituted with at least one keto group.
    Type: Grant
    Filed: May 13, 1996
    Date of Patent: May 19, 1998
    Assignee: Bayer Corporation
    Inventors: Thomas R. Flatt, Mark W. Johnson
  • Patent number: 5753023
    Abstract: A method for manufacture of a small dimension product using a dissolvable crystal. The crystal is coated with at least one layer of vacuum deposited material to form a coated crystal. The coated crystal is mixed with a liquid to dissolve the crystal and permit the layer of material to break into flakes. The flakes are separated from the liquid.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: May 19, 1998
    Assignee: Flex Products, Inc.
    Inventor: Charles A. Bishop
  • Patent number: 5749946
    Abstract: A pigment preparation comprising(i) 10-80% by wt. of a platelet-shaped substrate coated with a metal oxide, and(ii) 20-90% by wt. of an active pigment.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: May 12, 1998
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Ralf Glausch, Georg Reinhard, Renate Jircik, Ursula Rammelt
  • Patent number: 5743952
    Abstract: A process for improving the rheological properties of an aqueous suspension of a particulate inorganic material which comprises the steps of: (a) forming an aqueous suspension of the particulate inorganic material and an effective amount of an anionic polyelectrolyte dispersing agent; (b) diluting the suspension formed in step (a) with water while maintaining the particulate in the dispersed state of step (a) to give a solids concentration of not less than 20% by weight of the particulate inorganic material; and (c) reconcentrating the diluted suspension formed in step (b) to give a solids concentration of at least 50% by weight of the particulate inorganic material.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: April 28, 1998
    Assignee: ECC International Ltd.
    Inventors: David Robert Skuse, Warren Paul Eagles, Keith Robert Rogan
  • Patent number: 5738716
    Abstract: A color ink jet ink set for color printing is disclosed. The set comprises:(a) a first ink comprises a carrier and a bridged aluminum phthalocyanine pigment as a cyan colorant;(b) a second ink comprising a carrier and a quinacridone pigment as a magenta colorant; and(c) a third ink comprising a carrier and a non-benzidine yellow pigment.A fourth ink comprising pigment black 7 may also be included in the set.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: April 14, 1998
    Assignee: Eastman Kodak Company
    Inventors: Domenic Santilli, Douglas Eugene Bugner, Alexandra DeLauro Bermel, David Joseph Oldfield
  • Patent number: 5738719
    Abstract: A pigment composition, comprisinga) 80-99.8 mol % of a diketopyrrolopyrrole of formula ##STR1## wherein A and B are each independently of the other a ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.2 -C.sub.19 alkoxycarbonyl, C.sub.2 -C.sub.19 alkylcarbamoyl, C.sub.1 -C.sub.18 alkylmercapto, C.sub.1 -C.sub.18 alkylamino, C.sub.5 -C.sub.6 cycloalkyl, G is a direct bond or --O--, --S--, --SO--, --SO.sub.2 -- or --NR.sub.5 --, R.sub.3 and R.sub.4 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.18 alkoxy or C.sub.1 -C.sub.18 alkylamino, and R.sub.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, andb) 20-0.2 mol % of a diketopyrrolopyrrole of formula ##STR3## wherein one of R.sub.6 or R.sub.7 is hydrogen and the other is --CN. Such pigment compositions are distinguished by excellent resistance to recrystallisation and heat.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 14, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Olof Wallquist, Ingo Schloder, Gary Wooden
  • Patent number: 5735939
    Abstract: A pigment preparation for anti-corrosion coating materials, comprising(i) 3-40% by weight of a monomeric or polymeric, metal-free or metal-containing chelate-forming compound, preferably a phthalocyanine,(ii) 3-40% by weight of a material in flake form, preferably mica, and(iii) 25-80% by weight of a hydroxide ion-binding material, preferably a metaphosphate, di- or triphosphate. In a further embodiment, the pigment preparation additionally contains 5-65% by weight of a conductive pigment.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: April 7, 1998
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Ralf Glausch, Georg Reinhard, Renate Jircik, Ursula Rammelt
  • Patent number: 5733365
    Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: March 31, 1998
    Assignee: Kerr-McGee Corporation
    Inventors: John E. Halko, Phillip M. Story, James W. Kauffman, Kelly A. Green
  • Patent number: 5733364
    Abstract: Goniochromatic luster pigments based on multiply coated platelet-shaped metallic substrates comprising at least one layer packet ofA) a layer consisting essentially of silicon oxide, silicon oxide hydrate, aluminum oxide and/or aluminum oxide hydrate, andB) a metallic layer which consists essentially of aluminum and is at least partially transparent to visible light,and also, if desired, additionallyC) an outer layer which consists essentially of colorless or selectively absorbing metal oxide and/or is phosphate-, chromate- and/or vanadate-containing,are useful for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: March 31, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Jorg Adel
  • Patent number: 5730795
    Abstract: This invention provides a process for making titanium dioxide pigment, wherein an aqueous slurry of hydrous oxide surface-treated TiO.sub.2 particles is subjected to media milling. The TiO.sub.2 particles are surface-treated with a coating comprising a hydrous oxide such as silica and/or alumina, and the slurry is filtered prior to media milling. The milled slurry is dried and the dried product is fluid-energy milled to produce TiO.sub.2 pigment having good particle size distribution. The TiO.sub.2 pigments may be used to make coating formulations having high gloss.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: March 24, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Scott Matthew Herkimer
  • Patent number: 5730793
    Abstract: A method for dispersing a pigment is disclosed, wherein the pigment is dispersed in a medium solution by using sintered zirconia beads having an average particle diameter of 40 to 192 .mu.m, a density of 5.9 g/cm.sup.3 or more, and a sphericity of 1.07 or smaller. The method is particularly useful for providing an excellent coating gloss when the medium solution is a binder for forming a paint or a coating composition or a binder for forming an ink composition.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: March 24, 1998
    Assignee: Nikkato Corp.
    Inventors: Masayoshi Nakamura, Hiroyoshi Kawase, Shougo Kodama
  • Patent number: 5730796
    Abstract: Pigmentary titanium dioxide having a high durability when used in paint or the like exposed to solar radiation and methods of producing such pigmentary titanium dioxide are provided. The durable pigmentary titanium dioxide of the invention is comprised of rutile titanium dioxide particles having cerium oxide and dense amorphous silica deposited thereon. The particles preferably also have an outer coating of hydrous alumina deposited thereon.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: March 24, 1998
    Assignee: Kerr-McGee Chemical Corporation
    Inventors: John R. Brand, Roger A. Baldwin, Thomas Ian Brownbridge
  • Patent number: 5730788
    Abstract: Correction products known in the art are typically in a liquid form which are applied to a surface by a small brush. However, the present invention provides a correction product in the form of a bar that can be directly and easily applied to a desired surface. The present invention provides a correction product in the form of a bar having a composition compound of (a) 30-60 wt. % pigment; (b) 5-20 wt. % gelifying agent; (c) 0.5-10 wt. % adhesive resin; (d) 10-40 wt. % water; and (e) 0.5-5 wt. % emulsifier, and a method of producing the same.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: March 24, 1998
    Inventor: Enrique Gil Soriano
  • Patent number: 5728204
    Abstract: This invention relates to water-dispersible phthalocyanine pigment formulations that are mixtures of(a) about 60 to about 99.5% by weight, based on the total amount of components (a) and (b), of a conditioned metal phthalocyanine pigment, and(b) about 0.5 to about 40% by weight, based on the total amount of components (a) and (b), of a water-insoluble sulfonated phthalocyanine having the formulaPc(SO.sub.2 OR).sub.x (I)whereinPc represents a phthalocyanine moiety;R is H or M, wherein M is a monovalent metal, divalent metal, trivalent metal, or ammonium cation, andx is a from about 0.2 to about 4.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: March 17, 1998
    Assignee: Bayer Corporation
    Inventors: Abdul Sattar, Michael J. Greene, Herman Gerson
  • Patent number: 5725647
    Abstract: Pigmented inks are disclosed comprising an aqueous medium, a pigment, a dispersant, and a humectant. Inks are disclosed where the humectant is a sulfonated polyethylene oxide which provides long decap times and fast drying of the printed image. Inks are further disclosed where the dispersant is an alkyl(sulfophenoxy)benzenesulfonic acid or its salt. Such dispersants reduce the agglomeration of pigment particles and reduce or eliminate the deposition of foreign substances on heater elements during the jetting process. A variety of pigments, dispersants, humectants, and aqueous media can be used. Combinations of a sulfonated polyethylene oxide humectant and an alkyl(sulfophenoxy)benzenesulfonic acid (salt) dispersant provide inks with good stability, few kogation problems, long decap times and relatively fast drying times.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: March 10, 1998
    Assignee: Minnesota Mining And Manufacturing Company
    Inventors: James G. Carlson, Richard J. Kuo
  • Patent number: 5725651
    Abstract: Mono-N-alkyl-quinacridone pigments are disclosed. They exhibit high light fastness, high temperature stability and high migration fastness. Moreover, they show hypsochromic shifts, fluorescence and high photoconductivity. These pigments are suited for coloring high molecular weight organic materials, for use as light emitting materials of organic electroluminescent elements as well as photoreceptors of electrophotography.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: March 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: John Zambounis, Jin Mizuguchi