Patents Examined by Shean C Wu
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Patent number: 9096794Abstract: A liquid crystalline polymer composition that contains a liquid crystalline polymer and an aromatic amide oligomer is provided. The oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. The oligomer is also not easily volatized or decomposed during compounding, molding, and/or use, which minimizes off-gassing and the formation of blisters that would otherwise impact the final mechanical properties of a part made from the polymer composition. While providing the benefits noted, the aromatic amide oligomer does not generally react with the polymer backbone of the liquid crystalline polymer to any appreciable extent so that the mechanical properties of the polymer are not adversely impacted.Type: GrantFiled: August 27, 2012Date of Patent: August 4, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Joseph J. Grenci, Steven D. Gray
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Patent number: 9085730Abstract: The invention provides a liquid crystal (LC) composition, a LC cell thereof, and a LC device thereof. The LC composition comprises (i) a mixture of two or more nematic liquid crystals, and (ii) at least one chiral dopant. The mixture of the liquid crystals can exist in a blue phase within a temperature range of from about 12-60° C. such as 21-28° C. The LC device can be a blue phase mode liquid crystal display (BPLCD) based on such a room-temperature blue phase LC. The BPLCD requires no alignment, and it exhibits merits such as a fast switching time (e.g. sub-millisecond), a low switching voltage and a large field-induced birefringence, among others.Type: GrantFiled: June 16, 2010Date of Patent: July 21, 2015Assignee: Kent State UniversityInventors: Liang-Chy Chien, Lu Lu, Jeoung Yeon Hwang
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Patent number: 9080100Abstract: To provide a polymerizable liquid crystal composition showing good coating properties even when a support substrate has a low solvent resistance, and having uniform alignment properties. A polymerizable liquid crystal composition is prepared by containing as components an acrylate polymerizable liquid crystal compound, a compound represented by formula (3), and a non-liquid crystalline compound having an acryloyl group or a methacryloyl group as a reactive moiety, and having a functional group including a hydroxyl group as a reactive dilution solvent in one molecule. When the polymerizable liquid crystal composition is applied onto the support substrate, dried and irradiated with light, the polymerizable liquid crystal composition showing good coating properties even when the support substrate has the low solvent resistance, and having the uniform alignment properties can be obtained.Type: GrantFiled: May 15, 2013Date of Patent: July 14, 2015Assignees: JNC CORPORATION, JNC PETROCHEMICAL CORPORATIONInventor: Yoshiharu Hirai
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Patent number: 9074070Abstract: A thermoplastic composition that contains a unique combination of a thermotropic liquid crystalline polymer, dielectric material, laser activatable additive, and a fibrous filler is provided. The nature of the components and/or their concentration are selectively controlled in the present invention to maintain a high dielectric constant, good mechanical properties (e.g., deflection under load), and good processibility (e.g., low viscosity), yet still be laser activatable. Thus, the thermoplastic composition can be readily shaped into a thin substrate and subsequently applied with one or more conductive elements using a laser direct structuring process (“LDS”).Type: GrantFiled: October 23, 2012Date of Patent: July 7, 2015Assignee: Ticona LLCInventors: Paul C. Yung, Rong Luo
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Patent number: 9074133Abstract: A thermotropic liquid crystalline polymer melt polymerized in the presence of a viscosity modifier that can help increase the “low shear” viscosity of the resulting composition is provided. The increased “low shear” viscosity can minimize drooling of the polymer composition during processing and also allow it to possess a greater melt strength, which facilitates its ability to be processed in a wide variety of applications without losing its physical integrity. Despite having a relatively high “low shear” viscosity, the present inventors have discovered that the viscosity modifier does not substantially increase the “high shear” melt viscosity of the polymer composition. In this regard, the ratio of the “low shear” viscosity to the melt viscosity is generally very high, such as within a range of from about 50 to about 1000.Type: GrantFiled: August 27, 2012Date of Patent: July 7, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Patent number: 9063358Abstract: A multi-functional photochromic chiral nematic liquid crystal window comprises at least a photochromic chiral nematic liquid crystal layer. The windows are able to not only to darken in color upon exposure to sunlight irradiation but also control the light and the heat passing through them, which can be used as the windows of buildings, vehicles, and the like.Type: GrantFiled: February 25, 2011Date of Patent: June 23, 2015Assignee: KENT STATE UNIVERSITYInventors: Quan Li, Yannian Li, Ji Ma
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Patent number: 9062249Abstract: The present invention relates to a nematic liquid crystal composition useful as a liquid crystal display material and showing a negative value of dielectric anisotropy (??), and to a liquid crystal display device using the liquid crystal composition. The present invention provides a liquid crystal composition which causes little dropping marks during manufacture without degrading characteristics, such as dielectric anisotropy, viscosity, an upper limit temperature of a nematic phase, ?1, and the like, and image sticking of a display device. The liquid crystal display device of the present invention has excellent fast response, the characteristic of causing little image sticking, and the characteristic of causing little dropping marks due to its manufacture, and are thus particularly useful for VA-mode and PSVA-mode liquid crystal display devices for active matrix driving and can be applied to liquid crystal display devices such as liquid crystal TV, a monitor, and the like.Type: GrantFiled: October 5, 2012Date of Patent: June 23, 2015Assignee: DIC CorporationInventors: Shinji Ogawa, Yoshinori Iwashita
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Patent number: 9061905Abstract: Methods for preparing ferroelectric nanoparticles, liquid crystal compositions containing the ferroelectric nanoparticles, and electronic devices utilizing the ferroelectric nanoparticles are described. The methods of preparing the ferroelectric nanoparticles may include size-reducing a starting material comprising particles of a bulk intrinsically nonferroelectric glass to form glass nanoparticles having an average size of less than 20 nm, the glass nanoparticles comprising ferroelectric nanoparticles. Exemplary bulk intrinsically nonferroelectric glasses may include borosilicate glasses, tellurite glasses, bismuthate glasses, gallate glasses, and mixtures thereof, for example. The size reduction may be accomplished using ball milling with a solvent combination such as n-heptane and oleic acid. Liquid crystal compositions may include the ferroelectric nanoparticles in combination with a liquid crystal.Type: GrantFiled: December 12, 2012Date of Patent: June 23, 2015Assignee: Azimuth CorporationInventors: Gary Cook, Dean R. Evans, Sergey A. Basun
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Patent number: 9057017Abstract: A liquid crystal composition exhibiting a blue phase, which enables higher contrast, and a liquid crystal display device including the liquid crystal composition. The liquid crystal composition contains a chiral agent and liquid crystal containing a compound having three electron-withdrawing groups as end groups of a structure where a plurality of rings including at least one aromatic ring is linked to each other directly or with a linking group laid therebetween. At least one of the three electron-withdrawing groups includes a trifluoromethyl group. The peak of the diffracted wavelength on the longest wavelength side in the reflectance spectrum of the liquid crystal composition is less than or equal to 450 nm, preferably less than or equal to 420 nm. Furthermore, a liquid crystal display device can be provided with the use of the liquid crystal composition.Type: GrantFiled: November 15, 2012Date of Patent: June 16, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Manabu Kobayashi, Tetsuji Ishitani, Yuko Kawata, Tomohiro Tamura
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Patent number: 9057020Abstract: Described is a black dichroic dye composition comprising 2 or more dyes, wherein at least one dye, generally a red dye and optionally a yellow dye, conforms to the formula A and at least one dye, usually a blue dye, conforms to the formula B Ar1—N?N—[Ar2—N?N—]qAr3—N?N—Ar4 (B) with symbols as defined in present claims. The dye composition is well suited for combination with liquid crystal material for use, inter alia, as polarizing film and/or in liquid crystal displays, showing, inter alia, high dichroic ratio and excellent compatibility with the LC material.Type: GrantFiled: June 9, 2011Date of Patent: June 16, 2015Assignee: BASF SEInventors: Jean-Pierre Bacher, Gerardus De Keyzer, Urs Lehmann
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Patent number: 9051514Abstract: A liquid crystalline polymer composition that contains a liquid crystalline polymer and an aromatic amide oligomer is provided. The oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. The oligomer is also not easily volatized or decomposed during compounding, molding, and/or use, which minimizes off-gassing and the formation of blisters that would otherwise impact the final mechanical properties of a part made from the polymer composition. While providing the benefits noted, the aromatic amide oligomer does not generally react with the polymer backbone of the liquid crystalline polymer to any appreciable extent so that the mechanical properties of the polymer are not adversely impacted.Type: GrantFiled: August 27, 2012Date of Patent: June 9, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Joseph J. Grenci, Sayanti Basu, Steven D. Gray
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Patent number: 9052548Abstract: The present invention relates to a photo-curable composition that can provide a film, etc. showing excellent optical anisotropy even without need for separately forming a liquid crystal layer and an alignment layer, an optical anisotropic film using the same, and its preparation method. The photo-curable composition comprises a photo-alignable polymer, a noncrosslinkable liquid crystal compound and a photo-curable binder.Type: GrantFiled: November 26, 2012Date of Patent: June 9, 2015Assignee: LG CHEM, LTD.Inventors: Dai-Seung Choi, Dong-Woo Yoo, Sung-Ho Chun, Mi-Ra Hong, Jeong-Yoon Han, Hyeong-Bin Jang
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Patent number: 9045686Abstract: The present application relates to a liquid crystal composition, a liquid crystal cell, a liquid crystal film, and methods of preparing the same. As an exemplary liquid crystal composition, according to the present application can provide a liquid crystal layer aligned without a special alignment layer. According to the liquid crystal composition, all of the liquid crystal cell, in which the liquid crystal layer is maintained in a non-polymerized state, and the liquid crystal film prepared by polymerizing the liquid crystal layer can be provided.Type: GrantFiled: December 19, 2013Date of Patent: June 2, 2015Assignee: LG Chem, Ltd.Inventors: Sin Young Kim, Moon Soo Park, Dae Hee Lee, Da Mi Lee
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Patent number: 9045685Abstract: A molded part having a predetermined shape is provided. The molded part may be formed by casting a liquid crystalline polymer composition into a mold cavity at a relatively low shear rate. Due to the use of a relatively low shear rate, the polymer composition does not generally undergo extensive shear orientation, which can allow the resulting part to be further processed using standard finishing techniques. The ability to use relatively low shear rates during casting is achieved in the present invention through the use of an aromatic amide oligomer. More particularly, the present inventors have discovered that the aromatic amide oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix to “ultralow” levels without having a significant impact on the mechanical properties.Type: GrantFiled: August 27, 2012Date of Patent: June 2, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray, Joseph J. Grenci
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Patent number: 9045683Abstract: The present invention relates to polymerizable compounds, to processes and intermediates for the preparation thereof, and to the use thereof for optical, electro-optical and electronic purposes, in particular in liquid-crystal (LC) media and LC displays, especially in LC displays of the PS (“polymer sustained”) or PSA (“polymer sustained alignment”) type.Type: GrantFiled: June 1, 2011Date of Patent: June 2, 2015Assignee: Merck Patent GmbHInventors: Andreas Taugerbeck, Achim Goetz, Stephan Derow
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Patent number: 9039930Abstract: A blue phase liquid crystal display panel and a fabricating method thereof are provided. A first substrate and a second substrate are provided, and then a blue phase liquid crystal composition is filled between the first substrate and the second substrate, wherein the blue phase liquid crystal composition includes a blue phase liquid crystal and a reactive monomer. Next, an irradiation process is performed to induce a polymerization reaction in the reactive monomer of the blue phase liquid crystal composition, wherein a light utilized in the irradiation process has a wavelength ranged from 200 nm to 350 nm.Type: GrantFiled: March 31, 2013Date of Patent: May 26, 2015Assignee: Au Optronics CorporationInventors: Yi-Fen Lan, Ling-Yung Wang, Pu-Jung Huang, Cheng-Yeh Tsai
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Patent number: 9039929Abstract: A nematic liquid crystal composition of the present invention is used in liquid crystal display devices of the TN mode, OCB mode, ECB mode, IPS mode, or VA-IPS mode. The liquid crystal composition has positive dielectric anisotropy. Since the refractive index anisotropy and the nematic phase-isotropic liquid phase transition temperature are decreased and the increase in the lower limit temperature of the nematic phase is suppressed, the viscosity of the liquid crystal composition is sufficiently low without degrading the nematic phase temperature range. The liquid crystal composition also offers excellent features such as high-speed response, good display quality, and less display failures and is thus suitable as a practical liquid crystal composition.Type: GrantFiled: July 31, 2012Date of Patent: May 26, 2015Assignee: DIC CORPORATIONInventors: Masakazu Kaneoya, Kiyofumi Takeuchi, Masashi Osawa, Kenta Tojo, Tetsuo Kusumoto
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Patent number: 9039931Abstract: A liquid crystal composition including a dioxolane compound represented by the general formula (G1) as a chiral agent is provided. In the general formula (G1), R1 and R2 individually represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms, and an alkyl group having 1 to 20 carbon atoms and having a phenyl group as a substituent; R1 and R2 may be bonded to each other to form a ring; R3 and R4 individually represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, and a cycloalkyl group; and R5 to R40 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, and an aryl group having 6 to 12 carbon atoms.Type: GrantFiled: January 7, 2014Date of Patent: May 26, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Tomohiro Tamura, Yasuhiro Niikura, Tetsuji Ishitani, Sachiko Kawakami, Yuko Kawata
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Patent number: 9036119Abstract: Several aspects of the present invention provide a liquid crystal composition capable of shortening the takt time and achieving excellent display qualities, and a liquid crystal display device and a method for producing a liquid crystal display device which use the liquid crystal composition. The liquid crystal composition of several aspects of the present invention includes a liquid crystal material and one or more kinds of radical polymerizable monomers, at least one kind of the radical polymerizable monomers being a compound generating radicals through a self-cleavage reaction by exposure to light and having at least two radical polymerizable groups.Type: GrantFiled: March 8, 2012Date of Patent: May 19, 2015Assignees: SHARP KABUSHIKI KAISHA, TOYO GOSEI CO., LTD.Inventors: Masanobu Mizusaki, Yuichiro Yamada, Satoshi Enomoto, Yuki Hara, Hideo Kikuchi
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Patent number: 9036114Abstract: The occurrence of a defective orientation of a polymer/liquid crystal composite is suppressed. In addition, the occurrence of defective display of a liquid crystal display device including the polymer/liquid crystal composite is suppressed. In the polymer/liquid crystal composite exhibiting a blue phase, a plurality of domains are included and defective orientations easily occur at boundaries between the domains. Thus, by lowering orientation periodicities at boundaries between the domains, a defect-free orientation to high orientation periodicities at the boundary between adjacent domains can be obtained. Specifically, the polymer/liquid crystal composite exhibiting the blue phase includes the plurality of domains each of which has a size of 3 ?m or less.Type: GrantFiled: May 23, 2013Date of Patent: May 19, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Daisuke Kubota