Abstract: The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.
Type:
Grant
Filed:
October 11, 2012
Date of Patent:
April 7, 2015
Assignee:
Bayer Intellectual Property
Inventors:
Norbert Lui, Shanthan Rao Pamulaparthy, Srinivas Pvss, Thomas Vijaya, Sridhar Madabhushi, Rambabu Yadla, Narsaiah Banda, Sergii Pazenok