Abstract: Methods of cleanup for hydraulic fracturing operations using a polymeric thickening agent may include use of exothermically reactive salts. For example, a method of cleanup may include use of a first fluid including a first exothermically reactive salt and a second fluid including a second exothermically reactive salt. Upon introduction into a subterranean reservoir, exothermically reactive salts may undergo an exothermic reaction to generate heat, and such heat generated from the exothermic reaction may break a polymeric thickening agent and decrease viscosity thereof.
Type:
Grant
Filed:
September 21, 2023
Date of Patent:
May 6, 2025
Assignees:
SAUDI ARABIA, KING FAHD UNIVERSITY OF PETROLEUM & MINERALSN OIL COMPANY
Inventors:
Ali Abdullah Al-Taq, Sajjad A. Aldarweesh, Murtada S. Al-Jawad
Abstract: Methods for initiating chemical reactions in a wellbore include delivering one or more reactive components via a carrier fluid to the wellbore. The one or more reactive components delivered to the wellbore are configured to enable one or more chemical reactions to occur. The one or more chemical reactions are carried out until a threshold volume of the one or more reactive components is delivered to the wellbore.
Type:
Grant
Filed:
November 6, 2023
Date of Patent:
April 22, 2025
Assignee:
SCHLUMBERGER TECHNOLOGY CORPORATION
Inventors:
Alhad Phatak, Garud Bindiganavale Sridhar, Douglas Pipchuk, Dmitriy Potapenko, Dean Michael Willberg, James Ernest Brown
Abstract: Wellbore treatment fluids are provided that include an aqueous component and an amphiphilic hyperbranched copolymer comprising the polymerized reaction product of at least a first monomer and a second monomer, where the first monomer comprises at least one surface reactive end group chosen from the group consisting of carboxylates, phosphonates, sulfonates, and zwitterions. Also provided are methods of modifying subsurface energy of a carbonate formation using the wellbore treatment fluids.
Type:
Grant
Filed:
June 23, 2023
Date of Patent:
April 22, 2025
Assignees:
Saudi Arabian Oil Company, Case Western Reserve University
Inventors:
Feng Liang, Hui-Hai Liu, Jin Ge, Jose I. Rueda, Mohammed A. Bataweel
Abstract: Methods and apparatus are provided for disposal of Fat, Oil and Grease (FOG) wastes in subterranean formations, and for disposal of low-density organic wastes in subterranean, brine-filled caverns.
Type:
Grant
Filed:
December 13, 2021
Date of Patent:
April 22, 2025
Assignee:
Adantek Waste Management Services, Inc.
Inventors:
Omar Abou-Sayed, Ibrahim Mohamed, Yeshesh Panchal, Mahmoud Ashwamy, Jay Cecil, Steve Pangburn, Omar Sameh
Abstract: A method may include: introducing a treatment fluid into a production fluid disposed in a surface well system, the treatment fluid comprising: a base fluid; and a supramolecular host guest product comprising: a treatment fluid additive comprising a surfactant; and a supramolecular host molecule, wherein the supramolecular host molecule is not covalently bonded to the treatment fluid additive; introducing the production fluid containing the treatment fluid into a production facility separator; and separating, in the production facility separator, at least a portion of the production fluid to form a water stream.
Type:
Grant
Filed:
May 8, 2023
Date of Patent:
April 15, 2025
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Jay Deville, Enrique Antonio Reyes, Antonio Recio, William W. Shumway, Ronald Bosch
Abstract: A method is provided for sequestering carbon dioxide while treating a zone in a wellbore. The method includes obtaining a hydrogel, mixing the hydrogel with an aqueous amine solution to form an amine infused hydrogel (AIH), and exposing the AIH to a gas comprising carbon dioxide, wherein the amine and the AIH absorbs the carbon dioxide, forming a well treatment composition. The well treatment composition is pumped into a wellbore comprising a treatment zone, wherein the well treatment composition at least partially plugs the treatment zone.
Abstract: Methods and compositions for treating a siliceous geologic formation are described herein. An aqueous treatment composition for treating such formations includes an acid having molecular weight less than about 200, or an ammonium or sodium salt thereof, an HF source, and from about 0.1 wt % to about 2.0 wt % of a fluoride scale inhibitor, the aqueous treatment composition having a pH from about 1.0 to about 3.0.
Abstract: Embodiments described herein provide enhanced low-density hollow glass bead (HGB) fluids, as well as methods for utilizing such HGB fluids for wellbore drilling operations, completion operations, and workover operations. Such low-density HGB fluids include the following combination of constituents: a base oil, an oil viscosifying agent, HGBs at a concentration in a range between 20 vol % and 60 vol %, an organophilic clay, a clay activator, a surfactant, and (optionally) an H2S scavenger. Moreover, the low-density HGB fluids are suitable for use as lower-density cap fluids for pressurized mudcap drilling (PMCD) operations, alternative drilling fluids for managed pressure drilling (MPD) operations, alternative drilling fluids for conventional drilling operations corresponding to very-low-pressure or highly-depleted reservoirs, and/or lightweight fluids for wellbore workover operations.
Type:
Grant
Filed:
February 3, 2022
Date of Patent:
April 8, 2025
Assignee:
ExxonMobil Technology and Engineering Company
Inventors:
Glenn Penny, Vishwas Gupta, Sai Sashankh Rao, Nikolay M. Kostov, Qian Wu
Abstract: Materials for manipulating hydraulic fracture geometry. In one embodiment, the materials comprises a tip screen-out mixture, which comprises water; a hydrophilic polymer of anionic polyacrylamide, wherein the hydrophilic polymer is hydrolized at least in part; and one or more crosslinking agents selected from a group of compounds consisting of polyvalent metal cations.
Type:
Grant
Filed:
October 24, 2023
Date of Patent:
April 1, 2025
Assignee:
Quidnet Energy, Inc.
Inventors:
Howard K. Schmidt, Scott Wright, Dmitry Kosynkin
Abstract: Methods including the steps of mixing a treatment fluid comprising: a base fluid; a strong acid; and a plant edible demulsifier (PED). Wherein the PED comprises a capsaicinoid extract at a wt % range of 0.5 wt % to 10 wt %, based on the total weight of the treatment fluid. And then pumping the treatment fluid into a wellbore drilled through a subterranean formation. Wherein the PED reduces or eliminates formation of an emulsion in the treatment fluid. Some methods take the further step of injecting the PED into a wellbore drilled through the subterranean formation. And systems using the PED.
Abstract: The present invention finds its field of application among the advanced oil recovery methods, which must occur simultaneously and integrated with the capture, utilization, and storage of CO2 through a cavern built in offshore saline rock. More particularly the invention refers to offshore oil wells where there is an evaporitic rock layer next to it and, suitable for constructing a cavern in the saline rock, for its use as a CO2 and brine control volume in the water-gas alternating injection process in the reservoir.
Abstract: A method for acidizing a subterranean formation may include: preparing a water-in-oil emulsion comprising a non-polar phase, a polar phase, an emulsifier an acid, and a drag reducing agent; pumping the water-in-oil emulsion into a wellbore penetrating a subterranean formation above a fracture gradient of the subterranean formation to create or extend at least one fracture in the subterranean formation.
Type:
Grant
Filed:
September 6, 2023
Date of Patent:
March 11, 2025
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Enrique Antonio Reyes, Kristina Henkel Holan, Antonio Recio, III, Nicole Mast
Abstract: Systems and processes for enhancing connectivity and/or permeability between injector and producer wells using sequenced stimulation. Methods of modeling same.
Abstract: Methods for the fracking or stimulation of a hydrocarbon-bearing formation are provided in multiple embodiments. According to one method, it comprises the steps of: providing a wellbore having a casing; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and an acidic composition into the wellbore; wherein the acidic composition includes a corrosion inhibiting composition comprising at least two compounds selected from: Group A-I, and wherein at least two compounds are selected from different groups of the Groups A-I.
Abstract: An engineered cementitious composite (ECC) has a tensile strain capacity ranging from 8.6 to 12.5% and includes a cement precursor, unprocessed desert sand, and polymer fibers. The polymer fibers may be ultra-high molecular weight polyethylene fibers, polypropylene fibers, or a combination thereof. A method of preparing an ECC structure includes providing a cementitious precursor mixture including a cement precursor and unprocessed desert sand, introducing water into the cementitious precursor mixture to form a cement slurry, and adding polymer fibers to the cement slurry. The polymer fibers may be ultra-high molecular weight polyethylene fibers, polypropylene fibers, or a combination thereof. Then, the method includes forming a structure with the cement slurry and curing the cement slurry.
Type:
Grant
Filed:
October 13, 2022
Date of Patent:
March 4, 2025
Assignees:
SAUDI ARABIAN OIL COMPANY, University of Michigan
Inventors:
Mohammed Al Mehthel, Victor Li, He Zhu, Thibault Villette, Waleed Nasser, Oscar Salazar Vidal
Abstract: The present invention relates to a method for applying scale inhibitor to completion fluids during injectivity test operations. Said method takes advantage of the completion fluid to inhibit scaling in the reservoir by filling the porous spaces of the reservoir rock with the inhibited completion fluid. When the well is put into production, this inhibited fluid positioned inside the reservoir will be produced together with the oil and will inhibit the formation of scale inside the reservoir and on production equipment.
Type:
Grant
Filed:
October 24, 2023
Date of Patent:
February 25, 2025
Assignee:
PETRÓLEO BRASILEIRO S.A.—PETROBRAS
Inventors:
Mario Germino Ferreira Da Silva, Valtair Marcos Cristante, Fernando Antonio Moreira Da Silva, Ciro Dos Santos Guimaraes
Abstract: Surfactants for use in formulations and processes suitable for hydrocarbon recovery. These formulations, include formulations suitable for fracking, enhancing oil and or gas recovery, and the recovery and/or production of bio-based oils.
Abstract: Methods for hydraulic fracturing may utilize a fracturing fluid that includes a dual-polymer base fluid for all stages of a hydraulic fracturing operation. The dual-polymer base fluid includes a polysaccharide polymer and a polyacrylamide polymer. The dual-polymer base fluid and a crosslinker may be pumped into a wellbore drilled into a formation. A pump rate may be increased to induce one or more fractures in the formation. Proppant may be added to the dual-polymer base fluid while pumping. The proppant may be injected into the one or more fractures. The pump rate may then be reduced, and the dual-polymer base fluid may flow back into the wellbore.
Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and manganese compared to the untreated brines. Exemplary compositions contain a concentration of manganese less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg, and the treated geothermal brine is derived from a Salton Sea geothermal reservoir.