Abstract: Manganese(III)-containing nickel(II) hydroxide powders produced by coprecipitation carried out by dropping an acidified metal salt solution containing Ni.sup.+2 and Mn.sup.+3 ions into a feed of constant pH value, such that manganese(III) is incorporated into the nickel(II) hydroxide lattice, thereby preventing disproportionation into separate phases and improving performance characteristics of secondary battery electrodes manufactured therefrom.