Abstract: Porphyrins substituted with, for example, vinyl and acetylene groups are provided, along with polymers containing the same. In preferred embodiments, the substituted porphyrins are prepared by coupling halogenated porphyrins with anionic groups via metal-mediated cross-coupling reactions under stoichiometric or catalytic conditions.
Type:
Grant
Filed:
May 22, 1998
Date of Patent:
November 16, 1999
Assignee:
The Trustees of the University of Pennsylvania