Patents Examined by Teddy S. Gron
  • Patent number: 4880560
    Abstract: An optically active lactic acid derivative represented by the following formula (Ia) or (Ib): ##STR1## wherein R is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 1-16 carbon atoms,R.sup.1 is an alkyl group having 4-16 carbon atoms,m and n are respectively 1 or 2,k is 0 or 1, andC* is an asymmetric carbon atom.A liquid crystal composition containing the lactic acid derivative and a liquid crystal device using the liquid crystal composition are also disclosed.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: November 14, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuo Yoshinaga, Kazuharu Katagiri, Kenji Shinjo
  • Patent number: 4880562
    Abstract: A liquid crystalline compound useful as a component of liquid crystal compositions for TN mode display elements and having a large positive .DELTA..epsilon. value and also a low viscosity for the .DELTA..epsilon. value and a liquid crystal composition containing the compound are provided, which compound is expressed by the formula ##STR1## wherein n represents an integer of 0 to 20.
    Type: Grant
    Filed: February 17, 1989
    Date of Patent: November 14, 1989
    Assignee: Chisso Corporation
    Inventors: Kisei Kitano, Manabu Uchida, Makoto Ushioda, Toshiharu Suzuki
  • Patent number: 4879061
    Abstract: A method of making liquid crystalline compounds of the formula ##STR1## where A represents a cyclohexane ring, n has values of 1, 2 or 3, R1 is an alkyl radical, R2 is an alkyl, alkoxy, or alkylcyclohexyl or cyanide radical, and X1 is lower alkyl and X2, X3 and X4 is alkyl and preferably methyl, ethyl or propyl, hydrogen, halogen and preferably fluorine or cyanide and to the compound.
    Type: Grant
    Filed: September 29, 1986
    Date of Patent: November 7, 1989
    Assignee: Crystaloid Electronics Co.
    Inventors: Joseph P. Ferrato, Julie C. Ferrato
  • Patent number: 4879060
    Abstract: 2-phenylpyridine derivatives represented by the general formula: ##STR1## wherein when Y is R--, Z is one of R--, RO--, ##STR2## when Y is RO--, Z is one of straight chain pentyl, ##STR3## and when Y is one of Z is one of R--, RO-- and --CN; when Y is --CN, Z is one of RO--, ##STR4## and R is a straight chain alkyl group from 1 to 12 carbon atoms, are disclosed. The 2-phenylpyridine derivatives in accordance with the invention are particularly well-suited for use in nematic liquid crystal compositions for reducing the steepness and response time of the liquid crystal compositions in a liquid crystal display device.
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: November 7, 1989
    Assignee: Seiko Epson Kabushiki Kaisha
    Inventors: Yoshio Shionozaki, Hiroshi Mukai, Tsuyoshi Obikawa, Shuhei Yamada
  • Patent number: 4878968
    Abstract: A compound having the following formula: ##STR1## wherein R.sup.1 is --N.sup.+ H.sub.3 as found in claim 1 and R.sup.2 is either the same as F.sup.1 or hydrogen. "A" is an oxidizing anion, and X is selected to provide a neutral charge balance for the compound. A method of making a compound of the indicated structure from a compound of similar structure by an anion exchange process is also disclosed. Finally, propellant formulations incorporating the novel compounds of the present invention as fuels and oxidizers are disclosed.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: November 7, 1989
    Assignee: Morton Thiokol, Inc.
    Inventors: Rodney L. Willer, Glen T. Cunkle, Nathan Klein
  • Patent number: 4879059
    Abstract: A liquid crystal device comprises a pair of substrates and a ferroelectric liquid crystal disposed between the substrates. At least one of the pair of substrates has an alignment control film formed of an aliphatic polyimide resin having a function of aligning said plurality of layers preferentially in one direction. The aliphatic polyimide resin film stably provides a uniform alignment state with a large tilt angle than a conventional alignment control film of polyimide or polyvinyl alcohol over a long period. The liquid crystal device also provides a color tone of black in its darkest state.
    Type: Grant
    Filed: August 31, 1987
    Date of Patent: November 7, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yukio Hanyu, Yukiko Futami
  • Patent number: 4877548
    Abstract: A liquid crystalline compound and a liquid crystal composition containing the compound usable for liquid crystal display devices are provided, which liquid crystalline compound is expressed by the formulaR.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3.sub.n (CH.sub.2).sub.m CH.dbd.CF.sub.2wherein R.sup.1 is H or 1-20C alkyl or alkenyl wherein one --CH.sub.2 --group or two --CH.sub.2 -- groups not adjacent to each other may be substituted by --O--; the position and number of the double bond may be optionally chosen; A.sup.1, A.sup.2 and A.sup.3 each are ##STR1## and the H of the ##STR2## may be substituted by F, Cl or methyl; B.sup.1 and B.sup.2 each are --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 -- or a single bond; n is 0 or 1; and m is 0-20.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: October 31, 1989
    Assignee: Chisso Corporation
    Inventors: Kisei Kitano, Makoto Ushioda, Manabu Uchida, Toshiharu Suzuki
  • Patent number: 4877547
    Abstract: The invention relates to a new liquid crystal display element with static or multiplex control with a low multiplex ratio and an operating voltage below 3.3 volts, containing a liquid crystal dielectric, wherein the operating temperature range extends from -30.degree. C. to +80.degree. C. and the viscosity of the dielectric at 20.degree. C. is less than 40 mPa.s.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: October 31, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Georg Weber, Bernhard Scheuble, Joachim Krause
  • Patent number: 4877549
    Abstract: A liquid crystal composition comprising at least one first component compound of formula (I), at least one second component compound of formula (II) and at least one third component compound of formula (III), ##STR1## wherein R.sup.1 is alkyl of 1 to 8 carbons; R.sup.2 is H or F; R.sup.3 is alkyl or alkoxy each of 1 to 8 carbons; and R.sup.4 is F, --CN, alkyl or alkoxy each of 1 to 8 carbons, the first, second and third component compounds contained in respective amounts of 20-40 wt. %, 10-40 wt. % and 20-50 wt. % and in a total amount of 70 wt. % or more in the composition is provided to improve a steepness of transmission vs. voltage curve in a SBE mode display cell which is operated at a high level of multiplexing.
    Type: Grant
    Filed: February 25, 1988
    Date of Patent: October 31, 1989
    Assignee: Chisso Corporation
    Inventors: Shinichi Sawada, Tetsuya Matsushita, Toyoshiro Isoyama
  • Patent number: 4877220
    Abstract: Hexasubstituted cyclohexane compounds of the formula I ##STR1## in which Z.sup.1, Z.sup.2, Z.sup.3, X.sup.1, X.sup.2, A.sup.1, A.sup.2 and A.sup.3, p, R.sup.1 and R.sup.2, m and (n+m) have the meanings given in claim 1, are suitable as components of discotic liquid-crystalline phases.
    Type: Grant
    Filed: September 11, 1987
    Date of Patent: October 31, 1989
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Praefcke, Bernd Kohne, Werner Stephan
  • Patent number: 4876120
    Abstract: Disclosed are improved laminates useful in the manufacture of multi-layer printed wiring boards (MLPWB) and laminates. Such improved composites contain at least one layer which is formed from a liquid crystal polymer selected from the group consisting of poly(para-phenylene benzobisthiazole), poly(paraphenylene benzobisoxazole), poly(2,5-benzothiazole), poly(2,5-benzoxazole), and mixtures thereof. The presently preferred liquid crystal polymer comprises poly(para-phenylene benzobisthiazole). The negative coefficient of thermal expansion and high modulus of elasticity of the liquid crystal polymers enable a laminate and MLPWB to be manufactured therefrom having a tailored coefficient of thermal expansion, broadly ranging from about 0 to 15 ppm/.degree. C. MLPWBs constructed of polymeric core layers also are possible utilizing the preferred liquid crystal polymers of the present invention.
    Type: Grant
    Filed: April 21, 1987
    Date of Patent: October 24, 1989
    Assignee: General Electric Company
    Inventors: Robert E. Belke, Louis Zakraysek, Walter O. Pillar
  • Patent number: 4876026
    Abstract: An optically active-2-methylbutyrate capable of imparting a spontaneous polarization value to achiral smectic compositions and also constituting ferroelectric liquid crystal compositions exhibiting a fast response at room temperature, and a liquid crystal composition containing the same, and further a light-switching element therefrom, are provided, which optically active-2-methylbutyrate is expressed by the formula ##STR1## wherein R represents a linear or branched alkyl group or alkoxy group, each of 1 to 18 carbon atoms; A represents ##STR2## wherein X represents any one of F, Cl, Br or cyano group; and * indicates an optically active carbon atom.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: October 24, 1989
    Assignee: Chisso Corporation
    Inventors: Shinichi Saito, Hiromichi Inoue, Kazutoshi Miyazawa, Kouji Ohno, Makoto Ushioda
  • Patent number: 4876027
    Abstract: 4-Alkoxybenzenethiol, bis-(4-alkoxyphenyl)disulfide, and mesomorphic compound deviced therefrom represented by the formula: ##STR1## wherein R.sub.1 is an alkyl or alkoxy group having 1-18 carbon atoms, R* is an alkyl group having 4-12 carbon atoms including an asymmetric carbon atom, 1=1 or 2, and m=0 or 1.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: October 24, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuo Yoshinaga, Kazuharu Katagiri, Toyoko Kobayashi, Kenji Shinjo
  • Patent number: 4874543
    Abstract: A liquid crystal composition includes a tolan liquid crystal compound having a large optical anisotropy, another tolan liquid crystal compound having a large optical anisotropy and a high N-I point, a low-viscosity polycyclic liquid crystal compound (wherein the rings are directly bonded together) having an alkyl or alkoxy group, and a polycyclic liquid crystal compound (wherein the rings are directly bonded together) having a large optical anisotropy and a cyano group with a large dielectric anisotropy .DELTA..epsilon.. These compounds are mixed so as to obtain a positive dielectric anisotropy.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: October 17, 1989
    Assignee: Casio Computer Co., Ltd.
    Inventor: Tetsushi Yoshida
  • Patent number: 4874546
    Abstract: A novel phenylprimidinecarboxylate derivative which, when used as a component of liquid crystal compositions, can raise the clearing point of the mesomorphic range of the liquid crystal compositions and/or increase the dielectric anisotrophy value of the compositions, and a liquid crystal compositions containing the derivative are provided, which derivative is expressed by the formula ##STR1## wherein X.sup.1 represents an alkyl or alkoxy each of 1-10 C; X.sup.2 represents a 4-substituted phenyl having an alkyl, of 1-10 C, F, Cl, Br or --CN at 4-position or a 3,4-disubstituted phenyl having f, Cl, Br or CN at 4-position and F, Cl or Br at 3-position; and either one of L or M represents .dbd.N-- and the other represents --C.dbd..
    Type: Grant
    Filed: July 20, 1987
    Date of Patent: October 17, 1989
    Assignee: Chisso Corporation
    Inventors: Naoyuki Yoshida, Kisei Kitano, Tetsuya Ogawa
  • Patent number: 4874542
    Abstract: A phenyl-pyrimidine liquid crystal compound represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represent an alkyl group having 1 to 18 carbon atoms, and X and Y each represent one of a single bond, --O--, --OCO--, --COO-- and --OCOO--, provided that one of X and Y is --OCOO--.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: October 17, 1989
    Assignee: Ajinomoto Co., Inc.
    Inventors: Ryoichi Higuchi, Takao Sakurai, Tadahiko Yokota, Naoko Mikami, Eri Yamamoto, Koji Takeuchi
  • Patent number: 4874544
    Abstract: Fast-switching displays with memory properties are provided, which can display digits, symbols, and images, and which contain as chemically and thermally stable ferroelectric liquid crystalline substances, according to the invention, liquid crystalline derivatives which contain a chiral alkyl halide residue corresponding to the general formula ##STR1## are used in mixtures of one another as well as in conjunction with other liquid crystalline or non-crystalline liquid substances.
    Type: Grant
    Filed: February 3, 1988
    Date of Patent: October 17, 1989
    Assignee: VEB Werk fuer Fernsehelektronik im VEB Kombinat Mikroelektronik
    Inventors: Bak G. Yong, Barth Petra, Demus Dietrich, Joachimi Detlev, Barbara Kampa, Saskia Kohler, Kristine Mohr, Reinhard Paschke, Gerhard Pelzl, Ulrich Rosenfeld, Wolfgang Schafer, Klaus-Dieter Scherf, Carsten Tschirske, Wolfgang Weissflog, Horst Zaschke
  • Patent number: 4873018
    Abstract: An optically active 2-fluoro-1-alkanol compound represented by the formula (Ia): ##STR1## wherein R is an alkyl group having 1-16 carbon atoms, and C* is an asymmetric carbon atom; and an optically active compound derived from the fluoroalkanol and represented by the formula (Ib): ##STR2## wherein R and C* are the same as above, m is 1 or 2, n is 0 or 1, and A is a releasable substitutent. Because of the fluorine atom directly attached to an asymmetric carbon atom, these compounds are particularly effective in increasing a spontaneous polarization, improving a electric field responsive characteristic of a liquid crystal composition, and controlling the liquid crystal state.
    Type: Grant
    Filed: October 27, 1987
    Date of Patent: October 10, 1989
    Assignees: Canon Kabushiki Kaisha, Yamakawa Yakuhin Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Nohira, Masanao Kamei, Shinichi Nakamura, Kazuo Yoshinaga, Mariko Kai, Kazuharu Katagiri
  • Patent number: 4873019
    Abstract: 1,3-Cyclopentylene compounds of the formula IR.sup.1 -A.sup.1 -Z.sup.1 -A.sup.2 --(Z.sup.2 -A.sup.3).sub.n -R.sup.2 Iin which R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, Z.sup.1, Z.sup.2 and n have the meaning given herein, can be used as components of liquid-crystalline phases.
    Type: Grant
    Filed: December 18, 1987
    Date of Patent: October 10, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Joachim Krause, Andreas Wachtler, Bernard Scheuble, Georg Weber
  • Patent number: 4871472
    Abstract: Compounds of the formula I ##STR1## wherein R.sup.1 and R.sup.2 each independently of one another are R, OR, OCOR, COOR or OCOOR,is alkyl with 1 to 15 C atoms, wherein one or more CH.sub.2 groups which are not adjacent and are not linked by O can also be replaced by --O--, --CO--, --O--CO--, --CO--O--, --CH--halogen, --CHCN-- and/or --CH.dbd.CH--,A.sup.1, A.sup.2 and A.sup.3 each independently of one another are 1,4-phenylene or trans-1,4-cyclohexylene,m, n and o are each 0 or 1,m+n+o is 0, 1 or 2,Z.sup.1 and Z.sup.2 each independently of one another are --CH.sub.2 --O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or a single bond andX is F, Cl, Br, I or CN,with the provisos given in claim 1, can be used as components of ferroelectric liquid crystal phases.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: October 3, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Joachim Krause, Volker Reiffenrath, Thomas Geelhaar