Patents Examined by Teddy S. Gron
-
Patent number: 4880560Abstract: An optically active lactic acid derivative represented by the following formula (Ia) or (Ib): ##STR1## wherein R is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 1-16 carbon atoms,R.sup.1 is an alkyl group having 4-16 carbon atoms,m and n are respectively 1 or 2,k is 0 or 1, andC* is an asymmetric carbon atom.A liquid crystal composition containing the lactic acid derivative and a liquid crystal device using the liquid crystal composition are also disclosed.Type: GrantFiled: January 3, 1989Date of Patent: November 14, 1989Assignee: Canon Kabushiki KaishaInventors: Kazuo Yoshinaga, Kazuharu Katagiri, Kenji Shinjo
-
Patent number: 4880562Abstract: A liquid crystalline compound useful as a component of liquid crystal compositions for TN mode display elements and having a large positive .DELTA..epsilon. value and also a low viscosity for the .DELTA..epsilon. value and a liquid crystal composition containing the compound are provided, which compound is expressed by the formula ##STR1## wherein n represents an integer of 0 to 20.Type: GrantFiled: February 17, 1989Date of Patent: November 14, 1989Assignee: Chisso CorporationInventors: Kisei Kitano, Manabu Uchida, Makoto Ushioda, Toshiharu Suzuki
-
Patent number: 4879061Abstract: A method of making liquid crystalline compounds of the formula ##STR1## where A represents a cyclohexane ring, n has values of 1, 2 or 3, R1 is an alkyl radical, R2 is an alkyl, alkoxy, or alkylcyclohexyl or cyanide radical, and X1 is lower alkyl and X2, X3 and X4 is alkyl and preferably methyl, ethyl or propyl, hydrogen, halogen and preferably fluorine or cyanide and to the compound.Type: GrantFiled: September 29, 1986Date of Patent: November 7, 1989Assignee: Crystaloid Electronics Co.Inventors: Joseph P. Ferrato, Julie C. Ferrato
-
Patent number: 4879060Abstract: 2-phenylpyridine derivatives represented by the general formula: ##STR1## wherein when Y is R--, Z is one of R--, RO--, ##STR2## when Y is RO--, Z is one of straight chain pentyl, ##STR3## and when Y is one of Z is one of R--, RO-- and --CN; when Y is --CN, Z is one of RO--, ##STR4## and R is a straight chain alkyl group from 1 to 12 carbon atoms, are disclosed. The 2-phenylpyridine derivatives in accordance with the invention are particularly well-suited for use in nematic liquid crystal compositions for reducing the steepness and response time of the liquid crystal compositions in a liquid crystal display device.Type: GrantFiled: May 22, 1987Date of Patent: November 7, 1989Assignee: Seiko Epson Kabushiki KaishaInventors: Yoshio Shionozaki, Hiroshi Mukai, Tsuyoshi Obikawa, Shuhei Yamada
-
Patent number: 4878968Abstract: A compound having the following formula: ##STR1## wherein R.sup.1 is --N.sup.+ H.sub.3 as found in claim 1 and R.sup.2 is either the same as F.sup.1 or hydrogen. "A" is an oxidizing anion, and X is selected to provide a neutral charge balance for the compound. A method of making a compound of the indicated structure from a compound of similar structure by an anion exchange process is also disclosed. Finally, propellant formulations incorporating the novel compounds of the present invention as fuels and oxidizers are disclosed.Type: GrantFiled: January 12, 1988Date of Patent: November 7, 1989Assignee: Morton Thiokol, Inc.Inventors: Rodney L. Willer, Glen T. Cunkle, Nathan Klein
-
Patent number: 4879059Abstract: A liquid crystal device comprises a pair of substrates and a ferroelectric liquid crystal disposed between the substrates. At least one of the pair of substrates has an alignment control film formed of an aliphatic polyimide resin having a function of aligning said plurality of layers preferentially in one direction. The aliphatic polyimide resin film stably provides a uniform alignment state with a large tilt angle than a conventional alignment control film of polyimide or polyvinyl alcohol over a long period. The liquid crystal device also provides a color tone of black in its darkest state.Type: GrantFiled: August 31, 1987Date of Patent: November 7, 1989Assignee: Canon Kabushiki KaishaInventors: Yukio Hanyu, Yukiko Futami
-
Patent number: 4877548Abstract: A liquid crystalline compound and a liquid crystal composition containing the compound usable for liquid crystal display devices are provided, which liquid crystalline compound is expressed by the formulaR.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3.sub.n (CH.sub.2).sub.m CH.dbd.CF.sub.2wherein R.sup.1 is H or 1-20C alkyl or alkenyl wherein one --CH.sub.2 --group or two --CH.sub.2 -- groups not adjacent to each other may be substituted by --O--; the position and number of the double bond may be optionally chosen; A.sup.1, A.sup.2 and A.sup.3 each are ##STR1## and the H of the ##STR2## may be substituted by F, Cl or methyl; B.sup.1 and B.sup.2 each are --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 -- or a single bond; n is 0 or 1; and m is 0-20.Type: GrantFiled: December 27, 1988Date of Patent: October 31, 1989Assignee: Chisso CorporationInventors: Kisei Kitano, Makoto Ushioda, Manabu Uchida, Toshiharu Suzuki
-
Patent number: 4877547Abstract: The invention relates to a new liquid crystal display element with static or multiplex control with a low multiplex ratio and an operating voltage below 3.3 volts, containing a liquid crystal dielectric, wherein the operating temperature range extends from -30.degree. C. to +80.degree. C. and the viscosity of the dielectric at 20.degree. C. is less than 40 mPa.s.Type: GrantFiled: October 23, 1987Date of Patent: October 31, 1989Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Georg Weber, Bernhard Scheuble, Joachim Krause
-
Patent number: 4877549Abstract: A liquid crystal composition comprising at least one first component compound of formula (I), at least one second component compound of formula (II) and at least one third component compound of formula (III), ##STR1## wherein R.sup.1 is alkyl of 1 to 8 carbons; R.sup.2 is H or F; R.sup.3 is alkyl or alkoxy each of 1 to 8 carbons; and R.sup.4 is F, --CN, alkyl or alkoxy each of 1 to 8 carbons, the first, second and third component compounds contained in respective amounts of 20-40 wt. %, 10-40 wt. % and 20-50 wt. % and in a total amount of 70 wt. % or more in the composition is provided to improve a steepness of transmission vs. voltage curve in a SBE mode display cell which is operated at a high level of multiplexing.Type: GrantFiled: February 25, 1988Date of Patent: October 31, 1989Assignee: Chisso CorporationInventors: Shinichi Sawada, Tetsuya Matsushita, Toyoshiro Isoyama
-
Patent number: 4877220Abstract: Hexasubstituted cyclohexane compounds of the formula I ##STR1## in which Z.sup.1, Z.sup.2, Z.sup.3, X.sup.1, X.sup.2, A.sup.1, A.sup.2 and A.sup.3, p, R.sup.1 and R.sup.2, m and (n+m) have the meanings given in claim 1, are suitable as components of discotic liquid-crystalline phases.Type: GrantFiled: September 11, 1987Date of Patent: October 31, 1989Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Klaus Praefcke, Bernd Kohne, Werner Stephan
-
Patent number: 4876120Abstract: Disclosed are improved laminates useful in the manufacture of multi-layer printed wiring boards (MLPWB) and laminates. Such improved composites contain at least one layer which is formed from a liquid crystal polymer selected from the group consisting of poly(para-phenylene benzobisthiazole), poly(paraphenylene benzobisoxazole), poly(2,5-benzothiazole), poly(2,5-benzoxazole), and mixtures thereof. The presently preferred liquid crystal polymer comprises poly(para-phenylene benzobisthiazole). The negative coefficient of thermal expansion and high modulus of elasticity of the liquid crystal polymers enable a laminate and MLPWB to be manufactured therefrom having a tailored coefficient of thermal expansion, broadly ranging from about 0 to 15 ppm/.degree. C. MLPWBs constructed of polymeric core layers also are possible utilizing the preferred liquid crystal polymers of the present invention.Type: GrantFiled: April 21, 1987Date of Patent: October 24, 1989Assignee: General Electric CompanyInventors: Robert E. Belke, Louis Zakraysek, Walter O. Pillar
-
Patent number: 4876026Abstract: An optically active-2-methylbutyrate capable of imparting a spontaneous polarization value to achiral smectic compositions and also constituting ferroelectric liquid crystal compositions exhibiting a fast response at room temperature, and a liquid crystal composition containing the same, and further a light-switching element therefrom, are provided, which optically active-2-methylbutyrate is expressed by the formula ##STR1## wherein R represents a linear or branched alkyl group or alkoxy group, each of 1 to 18 carbon atoms; A represents ##STR2## wherein X represents any one of F, Cl, Br or cyano group; and * indicates an optically active carbon atom.Type: GrantFiled: December 15, 1987Date of Patent: October 24, 1989Assignee: Chisso CorporationInventors: Shinichi Saito, Hiromichi Inoue, Kazutoshi Miyazawa, Kouji Ohno, Makoto Ushioda
-
Patent number: 4876027Abstract: 4-Alkoxybenzenethiol, bis-(4-alkoxyphenyl)disulfide, and mesomorphic compound deviced therefrom represented by the formula: ##STR1## wherein R.sub.1 is an alkyl or alkoxy group having 1-18 carbon atoms, R* is an alkyl group having 4-12 carbon atoms including an asymmetric carbon atom, 1=1 or 2, and m=0 or 1.Type: GrantFiled: January 27, 1989Date of Patent: October 24, 1989Assignee: Canon Kabushiki KaishaInventors: Kazuo Yoshinaga, Kazuharu Katagiri, Toyoko Kobayashi, Kenji Shinjo
-
Patent number: 4874543Abstract: A liquid crystal composition includes a tolan liquid crystal compound having a large optical anisotropy, another tolan liquid crystal compound having a large optical anisotropy and a high N-I point, a low-viscosity polycyclic liquid crystal compound (wherein the rings are directly bonded together) having an alkyl or alkoxy group, and a polycyclic liquid crystal compound (wherein the rings are directly bonded together) having a large optical anisotropy and a cyano group with a large dielectric anisotropy .DELTA..epsilon.. These compounds are mixed so as to obtain a positive dielectric anisotropy.Type: GrantFiled: November 12, 1987Date of Patent: October 17, 1989Assignee: Casio Computer Co., Ltd.Inventor: Tetsushi Yoshida
-
Patent number: 4874546Abstract: A novel phenylprimidinecarboxylate derivative which, when used as a component of liquid crystal compositions, can raise the clearing point of the mesomorphic range of the liquid crystal compositions and/or increase the dielectric anisotrophy value of the compositions, and a liquid crystal compositions containing the derivative are provided, which derivative is expressed by the formula ##STR1## wherein X.sup.1 represents an alkyl or alkoxy each of 1-10 C; X.sup.2 represents a 4-substituted phenyl having an alkyl, of 1-10 C, F, Cl, Br or --CN at 4-position or a 3,4-disubstituted phenyl having f, Cl, Br or CN at 4-position and F, Cl or Br at 3-position; and either one of L or M represents .dbd.N-- and the other represents --C.dbd..Type: GrantFiled: July 20, 1987Date of Patent: October 17, 1989Assignee: Chisso CorporationInventors: Naoyuki Yoshida, Kisei Kitano, Tetsuya Ogawa
-
Patent number: 4874542Abstract: A phenyl-pyrimidine liquid crystal compound represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represent an alkyl group having 1 to 18 carbon atoms, and X and Y each represent one of a single bond, --O--, --OCO--, --COO-- and --OCOO--, provided that one of X and Y is --OCOO--.Type: GrantFiled: March 31, 1988Date of Patent: October 17, 1989Assignee: Ajinomoto Co., Inc.Inventors: Ryoichi Higuchi, Takao Sakurai, Tadahiko Yokota, Naoko Mikami, Eri Yamamoto, Koji Takeuchi
-
Patent number: 4874544Abstract: Fast-switching displays with memory properties are provided, which can display digits, symbols, and images, and which contain as chemically and thermally stable ferroelectric liquid crystalline substances, according to the invention, liquid crystalline derivatives which contain a chiral alkyl halide residue corresponding to the general formula ##STR1## are used in mixtures of one another as well as in conjunction with other liquid crystalline or non-crystalline liquid substances.Type: GrantFiled: February 3, 1988Date of Patent: October 17, 1989Assignee: VEB Werk fuer Fernsehelektronik im VEB Kombinat MikroelektronikInventors: Bak G. Yong, Barth Petra, Demus Dietrich, Joachimi Detlev, Barbara Kampa, Saskia Kohler, Kristine Mohr, Reinhard Paschke, Gerhard Pelzl, Ulrich Rosenfeld, Wolfgang Schafer, Klaus-Dieter Scherf, Carsten Tschirske, Wolfgang Weissflog, Horst Zaschke
-
Optically active compound, process for producing same and liquid crystal composition containing same
Patent number: 4873018Abstract: An optically active 2-fluoro-1-alkanol compound represented by the formula (Ia): ##STR1## wherein R is an alkyl group having 1-16 carbon atoms, and C* is an asymmetric carbon atom; and an optically active compound derived from the fluoroalkanol and represented by the formula (Ib): ##STR2## wherein R and C* are the same as above, m is 1 or 2, n is 0 or 1, and A is a releasable substitutent. Because of the fluorine atom directly attached to an asymmetric carbon atom, these compounds are particularly effective in increasing a spontaneous polarization, improving a electric field responsive characteristic of a liquid crystal composition, and controlling the liquid crystal state.Type: GrantFiled: October 27, 1987Date of Patent: October 10, 1989Assignees: Canon Kabushiki Kaisha, Yamakawa Yakuhin Kogyo Kabushiki KaishaInventors: Hiroyuki Nohira, Masanao Kamei, Shinichi Nakamura, Kazuo Yoshinaga, Mariko Kai, Kazuharu Katagiri -
Patent number: 4873019Abstract: 1,3-Cyclopentylene compounds of the formula IR.sup.1 -A.sup.1 -Z.sup.1 -A.sup.2 --(Z.sup.2 -A.sup.3).sub.n -R.sup.2 Iin which R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, Z.sup.1, Z.sup.2 and n have the meaning given herein, can be used as components of liquid-crystalline phases.Type: GrantFiled: December 18, 1987Date of Patent: October 10, 1989Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Joachim Krause, Andreas Wachtler, Bernard Scheuble, Georg Weber
-
Patent number: 4871472Abstract: Compounds of the formula I ##STR1## wherein R.sup.1 and R.sup.2 each independently of one another are R, OR, OCOR, COOR or OCOOR,is alkyl with 1 to 15 C atoms, wherein one or more CH.sub.2 groups which are not adjacent and are not linked by O can also be replaced by --O--, --CO--, --O--CO--, --CO--O--, --CH--halogen, --CHCN-- and/or --CH.dbd.CH--,A.sup.1, A.sup.2 and A.sup.3 each independently of one another are 1,4-phenylene or trans-1,4-cyclohexylene,m, n and o are each 0 or 1,m+n+o is 0, 1 or 2,Z.sup.1 and Z.sup.2 each independently of one another are --CH.sub.2 --O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or a single bond andX is F, Cl, Br, I or CN,with the provisos given in claim 1, can be used as components of ferroelectric liquid crystal phases.Type: GrantFiled: October 9, 1987Date of Patent: October 3, 1989Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Joachim Krause, Volker Reiffenrath, Thomas Geelhaar