Abstract: The present invention relates to conjugated polymers and dendrimers containing styryl-triarylamine structural units, to the use thereof in electronic components, in particular in polymeric organic light-emitting diodes, to monomers for the preparation thereof, and to components and light-emitting diodes comprising polymers and dendrimers of this type.

Abstract: A resin composition includes an aliphatic polyester resin. The resin has carboxyl groups at the end termini of the molecular chain and at least one compound represented by the general formula (I), the compound being added to the resin to cap a part or all of the carboxyl groups at the end termini of the molecular chain of the resin. A process for producing a fiber includes mixing a pellet comprising an aliphatic polyester resin having carboxyl groups at the end termini of the molecular chain with a compound represented by the general formula (I) so that the content of the compound becomes 0.1 to 8% by weight and then melt-spinning the resulting mixture under the conditions of a spinning temperature of 200 to 250 C.°, a melt residence time of 180 to 1800 sec and a spinning rate of 500 to 10000 m/min.

Abstract: The present invention provides a polycarbonate resin produced by the continuous interfacial process characterized in that after alkaline hydrolysis with sodium hydroxide, the polycarbonate resin contains an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) said amount measured by high pressure liquid chromatography, wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen. C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, the process comprising phosgene reacting with at least one bisphenol at 8 to 17% molar excess of phosgene relative to the bisphenol.

Abstract: Polyesters whose polycondensation is catalyzed by titanium-containing catalysts and which are susceptible to acetaldehyde formation during polycondensation or subsequent molding operations are prepared with low finished acetaldehyde content and reduced acetaldehyde generation by adding an ammonium or amine salt of an oxyphosphorus-acid. Polyesters, especially polyethylene terephthalate, may be produced with high inherent viscosity in reduced processing time, without the necessity of further polymerization in the solid state.

Abstract: A tetracarboxylic acid compound of formula (1) or (2) wherein A represents a divalent group; X1, X2 and X3 respectively represent a hydrogen atom or the like; R1, R2, R3 and R4 respectively represent a carboxyl group or an acid anhydride group; n represents 1 or 2; and B represents a cyclic group.

Abstract: A method of isolating a PHA, includes combining the PHA, a first solvent and a second solvent to form a combination, the first solvent being capable of forming an azeotrope with the second solvent; and heating the combination to form the azeotrope of the first and second solvents.

Abstract: A method of preparing a material for use in a manufactured seed is provided. The method includes providing the material having a melting temperature. The method also includes subjecting the material to a heat treatment at a temperature about 10% below the melting temperature for a predetermined period of time.

Abstract: A process for the separation of volatile material from particulate polymer discharged from a polymerisation reactor in the form of a polymer slurry and which has been substantially freed from unreacted monomer in an earlier separation step, comprising (a) feeding the particulate polymer to a purge vessel and causing it to move through the vessel in substantially plug-flow mode, (b) heating the particulate polymer in the purge vessel to a temperature greater than 30° C.

Abstract: A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical.

Abstract: The present invention relates to novel copolymers comprising unsubstituted or R-substituted trimethylene carbonate and poly(trimethylene ether)glycol. The copolymers find use in areas including personal care, coatings and lubricants.

Abstract: This invention relates to solventless processes for the polymerization of an unsubstituted or substituted trimethylene carbonate to an unsubstituted or substituted poly(1,3-propanediol carbonate 1,3-propanediol ether)diol, using one or more solid acid catalysts.

Abstract: Method for enhancing the crystallization rates of engineering thermoplastics through the use and incorporation of particulate additives with dimensions on the order of 10-1000 nm is described. The presence of nanoparticles at concentrations of, e.g., less than 10 weight percent of the composition, reduces the viscosity of the thermoplastics as compared to the respective homopolymer, thereby increasing polymer chain transport and diffusion to the crystallizing growth front. The prescription of this technology has been shown to reduce crystallization half times of some engineering thermoplastics by as much as 40 percent at optimal crystallization temperatures, an effect that is magnified as the temperature is reduced towards the glassy state of the amorphous phase. Nano-modified engineering thermoplastics with rapid crystallization kinetics and relatively low viscosities can be utilized in component fabrication processes that require rapid processing times, e.g., for the sake of cost efficiency.

Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.

Abstract: Disclosed herein is an isosorbide-based polycarbonate polymer comprising: an isosorbide unit, an aliphatic unit derived from a C14-44 aliphatic diacid, C14-44 aliphatic diol, or combination of these; and a polysiloxane block.

Abstract: An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere; a means for supporting the polymeric material within the chamber; and, a source of plasma-derived gas containing at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at a selected temperature. The polymer may be directly exposed to the plasma, or alternatively, the plasma may be established in a separate volume from which the reactive species may be extracted and introduced into the vicinity of the polymer. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments.

Abstract: Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze having at least one layer contains one or more thermoplastic polymers selected from polyesters, polycarbonates, and homogeneous blends thereof, and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The thermoplastic polymer components and the polyamide components have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.

Abstract: Vector-directional polymers and polymer systems are disclosed. In accordance with the embodiments of the invention, the polymer has aromatic moieties that are restrained or fixed through conformational linkage units bonding nearest neighbor aromatic moieties together to form the polymer backbone. The conformational linkage units preferably include conformational ring structures which exhibit hydrogen bonding or other Lewis acid-Lewis base type of interactions. The conformational ring structures can include hetero-atoms and cationic metal atoms. The chemical groups and bonding features of the polymer backbone constrain bond movement and bond rotation along the polymer backbone. Accordingly, the vector-directional polymers of the present invention can assemble into or form extended three dimensional structures or arrays.

Abstract: A resin composition, and molded articles thereof, where the resin composition simultaneously satisfies resistances, such as heat and environmental resistance, and moldability at high levels, and has excellent optical properties, such as high refractivity and low birefringence. The resin composition contains a polyester resin formed from a dicarboxylic acid component and a diol component (a) and a polycarbonate resin formed from a carbonate-forming component and a diol component (b), the diol component (a) containing a specific fluorene-containing compound and the diol component (b) containing a specific fluorene-containing compound.

Abstract: A polymer comprising a tagging material is provided wherein the tagging material comprises at least one organic fluorophore dye, or at least one inorganic fluorophore, or at least one organometallic fluorophore, or at least one semi-conducting luminescent nanoparticle, or combination thereof, wherein the tagging material has a temperature stability of at least about 350° C. and is present in a sufficient quantity such that the tagging material is detectible via a spectrofluorometer at an excitation wavelength in a range between about 100 nanometers and about 1100 nanometers. Further embodiments of the present invention include a method for identifying a polymer and an article comprising a polymer wherein the polymer contains the aforementioned tagging material.

Abstract: Methods for roll-to-roll deposition of optically transparent and high conductivity metallic thin films are disclosed. In general, a method according to the present invention comprises: (1) providing a flexible plastic substrate; (2) depositing a multi-layered conductive metallic film on the flexible plastic substrate by a thin-film deposition technique to form a composite film; and (3) collecting the composite film in continuous rolls. Typically, the thin conductive metallic film is an InCeO—Ag—InCeO film. Typically, the thin-film deposition technique is DC magnetron sputtering. Another aspect of the invention is a composite film produced by a method according to the present invention.