Abstract: A very compact Selective Catalytic Reduction (SCR) system with a very low footprint comprising an SCR reactor, an inlet flow system, and a vaporizer module is described. The SCR reactor comprises at least one SCR catalyst which is in communication with the inlet flow system and the vaporizer module. The inlet flow system is configured to provide an approximately uniform flow of the exhaust gas through the catalyst and to provide heat to the vaporizer module. The vaporizer module is configured to allow for the conversion of urea to ammonia and to contact the ammonia with the exhaust gases in the SCR reactor upstream of the SCR catalyst.
Type:
Grant
Filed:
February 4, 2015
Date of Patent:
April 11, 2017
Assignee:
Johnson Matthey Catalysts (Germany) GMBH
Inventors:
Dirk Reichert, Daniel Kuegel, Ilir Piluri
Abstract: Polysulfide intercalated layered double hydroxides and methods for their use in vapor and liquid-phase metal capture applications are provided. The layered double hydroxides comprise a plurality of positively charged host layers of mixed metal hydroxides separated by interlayer spaces. Polysulfide anions are intercalated in the interlayer spaces.
Abstract: Provided is a catalyst for the selective reduction of NOx comprising a two molecular sieve materials having a CHA structure, wherein the first molecular sieve has a mean crystal size of about 0.01 to 1 ?m and the second molecular sieve has a mean crystal size of about 1-5 ?m, and wherein the first molecular sieve contains a first extra-framework metal, the second molecular sieve contains a second extra-framework metal, and wherein said first and second extra-framework metals are independently selected from the group consisting of cesium, copper, nickel, zinc, iron, tin, tungsten, molybdenum, cobalt, bismuth, titanium, zirconium, antimony, manganese, chromium, vanadium, niobium, and combinations thereof.
Type:
Grant
Filed:
September 4, 2015
Date of Patent:
April 4, 2017
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Joseph M. Fedeyko, Hai-Ying Chen, Guy Richard Chandler, Alexander Nicholas Michael Green, Debnath De, Shadab Mulla, Wendy Manning, Philip Gerald Blakeman
Abstract: A catalyzed substrate monolith 12 for use in treating exhaust gas emitted from a lean-burn internal combustion engine, which catalyzed substrate monolith 12 comprising a first washcoat coating 16 and a second washcoat coating 18, wherein the first washcoat coating comprises a catalyst composition comprising at least one platinum group metal (PGM) and at least one support material for the at least one PGM, wherein at least one PGM in the first washcoat coating is liable to volatilize when the first washcoat coating is exposed to relatively extreme conditions including relatively high temperatures, wherein the second washcoat coating comprises at least one metal oxide for trapping volatilized PGM and wherein the second washcoat coating is oriented to contact exhaust gas that has contacted the first washcoat coating.
Type:
Grant
Filed:
May 12, 2015
Date of Patent:
March 21, 2017
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Philip Gerald Blakeman, Gavin Michael Brown, Sougato Chatterjee, Andrew Francis Chiffey, Jane Gast, Paul Richard Phillips, Raj Rao Rajaram, Glen Spreitzer, Andrew Peter Walker
Abstract: Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising an iron loaded medium- or large-pore molecular sieve having a first ammonia storage capacity; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve having a second ammonia storage capacity, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system and wherein the second ammonia storage capacity is greater than the first ammonia storage capacity. Also provided is a method for using the system to treat exhaust gas.
Type:
Grant
Filed:
July 30, 2015
Date of Patent:
March 21, 2017
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Olivier Sonntag, Tim Genschow, Andrew Newman, Isabel Zoe Tingay, Gudmund Smedler
Abstract: In an exhaust gas purification catalyst system for use in an automobile including an exhaust gas purification catalyst product disposed in both a front section and a rear section, the exhaust gas purification catalyst product of the front section has a layered catalyst including a lower layer which contains aluminum borate.
Abstract: Provided is a catalyst composition having an aluminosilicate molecular sieve having an AEI structure and a mole ratio of silica-to-alumina of about 20 to about 30 loaded with about 1 to about 5 weight percent of a promoter metal, based on the total weight of the molecular sieve material. Also provided are method, articles, and systems utilizing the catalyst composition.
Type:
Grant
Filed:
April 29, 2015
Date of Patent:
March 21, 2017
Assignee:
Johnson Matthey Public Limited Company
Inventors:
John Leonello Casci, Jillian Elaine Collier, Lucia Gaberova
Abstract: An enrichment apparatus and process for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feed to a Claus. The enrichment apparatus comprises a hydrocarbon selective separation unit operable to separate the acid gas stream into a hydrocarbon rich stream and a purified acid gas stream, wherein the acid gas stream comprises hydrogen sulfide, carbon dioxide, and hydrocarbons, a hydrogen sulfide selective separation unit operable to separate the purified acid gas stream to create the hydrogen sulfide rich stream and a hydrogen sulfide lean stream, the hydrogen sulfide rich stream having a concentration of hydrogen sulfide, and the Claus unit operable to recover sulfur from the carbon dioxide lean stream. The enrichment apparatus can include a carbon dioxide selective separation unit in fluid communication with the hydrogen sulfide selective separation unit, operable to separate the hydrogen sulfide rich stream.
Type:
Grant
Filed:
April 15, 2015
Date of Patent:
March 14, 2017
Assignee:
SAUDI ARABIAN OIL COMPANY
Inventors:
Jean-Pierre R. Ballaguet, Milind M. Vaidya, Sebastien A. Duval, Aadesh Harale, Anwar H. Khawajah, Veera Venkata R. Tammana
Abstract: A process for removing sulfur from a gas containing sulfur compounds as H2S, SO2, COS, CS2 . . . , in a quantity of up to 15% wt; particularly gases emanating from the Claus process: A first hydrogenation of the sulfur compounds into H2S, the hydrogenation gas being used to regenerate a deactivated bed of oxidation catalyst, both being carried out at 200-500° C. After sulfur removal, the resulting gas undergoes a second hydrogenation step and then a direct oxidation step, said step being operated under the dew point of sulfur to trap the formed sulfur in the catalyst. In the further cycle, the gas streams are switched so as to regenerate the catalyst in run which is deactivated.
Abstract: Describes a method of producing a magnesium sulfate and hydrous ammonia double salt or Boussingaultite ((NH4)2SO4.MgSO4.6H2O), using as a source of magnesium a liquid effluent rich in magnesium sulfate originally from hydrometallurgical processes for the production of metals such as nickel, copper, rare earths. According to the invention, the process route for the production of Boussingaultite with physical properties suitable for use in fertilizer mixtures involves the steps of precipitating the Boussingaultite double salt, filtration and thermal drying.
Type:
Grant
Filed:
April 16, 2015
Date of Patent:
March 7, 2017
Assignee:
VALE S.A.
Inventors:
Angela Nair Avelar, Ruberlan Gomes Da Silva
Abstract: An exhaust gas after-treatment system for an internal combustion engine, with a particle filter arranged downstream of an internal combustion engine for filtering soot out of the exhaust gas, and with an oxidation catalytic converter arranged upstream of the particle filter and downstream of the internal combustion engine for the oxidation of SO2 into SO3. The SO3 and/or precipitated H2SO4 serves for the oxidation of soot in the particle filter and thus for the regeneration of the particle filter.
Abstract: Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system. Also provided is a method for using the system to treat exhaust gas.
Type:
Grant
Filed:
August 14, 2015
Date of Patent:
February 28, 2017
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Olivier Sonntag, Tim Genschow, Andrew Newman, Isabel Zoe Tingay, Gudmund Smedler
Abstract: A flue gas treatment apparatus for removing sulfur contents contained in combustion flue gas, includes a treatment agent feeder to feed a treatment agent into a flue through which the combustion flue gas flows, a cooler to cool the combustion flue gas to which the treatment agent has been fed and condense SO3 components in the combustion flue gas, an electric dust collection apparatus provided in the flue, a desulfurization apparatus based on a lime-gypsum process, and a circulation line for feeding a portion of the dust particles recovered by the electric dust collection apparatus into the flue that is provided on an upstream side of the cooler in the direction of flow of the flue gas for circulated use thereof as the treatment agent.
Abstract: A process of producing degassed liquid sulfur using agitation gas to agitate the liquid sulfur being degassed while in contact with a degassing catalyst. Process gas may be blended with the agitation gas wherein the process gas contains H2S to accomplish substantial degassing rendering the liquid sulfur much safer in storage and transportation.
Abstract: An air pollution control system includes: a desulfurization device which removes sulfur oxides in a flue gas generated from a boiler; a cooler which is provided at the downstream side of the desulfurization device, decreases a flue gas temperature and enlarges a particle diameter of SO3 mist contained in the flue gas through cooling or heating the flue gas by a temperature adjustment means for adjusting a gas dew point temperature of the flue gas; and a CO2 recovery device which includes a CO2 absorber bringing CO2 in the flue gas into contact with the CO2 absorbent so as to remove CO2 therefrom and a regenerator recovering CO2 by dissociating CO2 from the CO2 absorbent and regenerating the CO2 absorbent, wherein the flue gas is cooled by a cooling unit so as to enlarge the SO3 mist in the flue gas.
Abstract: A horizontal scrubber may be configured for removal of sulfur dioxide and particulate matter from a gaseous stream derived from the combustion of biomass, including, for example, sugar cane bagasse. The scrubber may include a horizontally disposed housing including an inlet configured to receive a gas stream derived from combusted biomass and an outlet. The scrubber may further include a manifold of liquid nozzles disposed within the housing that are configured to provide a spray of liquid droplets in a co-current orientation to the gas stream. An array of tubes may be oriented adjacent to the manifold of liquid nozzles and may be configured to receive the gas stream and liquid droplets from the nozzle array, but providing minimal resistance to material flow. To encourage flow, members of the tube array may include circular walls with a substantially uniform cross section.
Abstract: The invention is a process for absorbing sulfur dioxide from a gaseous stream with the aid of an ionic liquid, followed by the release of sulfur dioxide from the ionic liquid on addition of a polar solvent and the regeneration of the ionic liquid.
Type:
Grant
Filed:
July 13, 2015
Date of Patent:
February 7, 2017
Assignee:
YISSUM RESEARCH DEVELOPMENT COMPANY OF THE HEBREW UNIVERSITY OF JERUSALEM LTD.
Abstract: Methods are disclosed for generating electrical power from a compound comprising carbon, oxygen, and hydrogen. Water is combined with the compound to produce a wet form of the compound. The wet form of the compound is transferred into a reaction processing chamber. The wet form of the compound is heated within the reaction chamber such that elements of the compound dissociate and react, with one reaction product comprising hydrogen gas. The hydrogen gas is processed to generate electrical power.
Type:
Grant
Filed:
April 6, 2015
Date of Patent:
February 7, 2017
Assignee:
Proton Power, Inc.
Inventors:
Samuel C. Weaver, Samuel P. Weaver, Daniel C. Weaver, Daniel L. Hensley
Abstract: The present invention concerns the elimination of heavy metals, in particular mercury and possibly arsenic and lead, present in a gaseous or liquid effluent by means of a capture mass comprising a support essentially based on alumina obtained by the gel method and at least one element selected from the group constituted by copper, molybdenum, tungsten, iron, nickel and cobalt. The invention is advantageously applicable to the treatment of gas of industrial origin, synthesis gas, natural gas, gas phase condensates and liquid hydrocarbon feeds.
Type:
Grant
Filed:
September 12, 2012
Date of Patent:
February 7, 2017
Assignee:
IFP ENERGIES NOUVELLES
Inventors:
Fabien Porcheron, Karin Barthelet, Arnaud Baudot, Antoine Daudin, Marc-Antoine Lelias, Yannick Gelie, Alexandre Nicolaos
Abstract: A method in which the exhaust gas that is to be purified is passed through an exhaust-gas line containing a diesel oxidation catalyst (DOC) for the oxidation of residual gaseous hydrocarbons (HC) and carbon monoxide (CO) in order to form carbon dioxide (CO2) and for the at least proportional oxidation of the nitrogen monoxide (NO) contained in the exhaust gas in order to form nitrogen dioxide (NO2) is provided.