Patents Examined by Virginia B. Caress
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Patent number: 4904411Abstract: Slurries or suspensions for forming sintered ceramic or metallic articles are described as having a high volume fraction of sinterable particles, at least 55% by volume. while the slurries maintain a pourable viscosity, such as not more that 2000 cPs at 100 s.sup.-1 ; the slurries can be dilatant and/or pseudoplastic. The slurries are prepared by using specific families of dispersants; namely acrylic acid-based polymeric polyelectrolytes, polyethylene imine-based polyelectrolytes, and coupling agents from the subfamilies of oxy-silane esters and phosphate esters. Fabrication of the compositions includes milling under high energy and the addition of at least a portion of the particles in a step-wise manner.Type: GrantFiled: September 9, 1988Date of Patent: February 27, 1990Assignee: Ceramics Process Systems Corp.Inventors: Bruce E. Novich, Mark A. Occhionero, Richard L. Pober
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Patent number: 4904406Abstract: A quaternary ammonium-substituted peroxycarboxylic acid bleach precursor, its quaternary ammonium peroxycarboxylic acid derivative, and bleaching-detergent compositions containing these materials are disclosed herein. The bleach precursor structurally comprises a quaternized ammonium group linked to a carboxyl moiety having a leaving group via an aromatic or heterocyclic bridging group which, upon perhydrolysis in the presence of hydrogen peroxide, generates a highly effective, quaternary ammonium-substituted aromatic or heterocyclic peroxycarboxylic acid bleach.Type: GrantFiled: February 21, 1989Date of Patent: February 27, 1990Assignee: Lever Brothers CompanyInventors: James R. Darwent, Keith C. Francis, John Oakes, David W. Thornthwaite
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Patent number: 4898681Abstract: Dilute aqueous sodium hypochlorite solution is stabilized against decomposition during storage by incorporating in it a small proportion of the calcium chelate of disodium ethylenediaminetetraacetic acid. The solution preferably contains by weight at least 95 percent water, from 0.25 to 1 percent sodium hypochlorite, and from 0.005 to 0.25 percent of the calcium chelate. It may be stored for a period of many months and remains effective as a disinfectant for medical environmental surfaces. The solution may also be formulated to contain a synthetic detergent, such as sodium lauryl sulfate, 0.1 to 3 percent, and an alkaline builder, such as sodium metasilicate, to maintain a pH value above 11. Sodium hydroxide may be added to produce a pH above 12.Type: GrantFiled: August 31, 1988Date of Patent: February 6, 1990Inventor: Charles D. Burton
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Patent number: 4895960Abstract: A useful brain perfusion imaging agent comprises ##STR1## wherein R completes a four or five member ring. The agent is stable in vitro permitting its use up to six to eight hours after preparation.Type: GrantFiled: January 23, 1989Date of Patent: January 23, 1990Assignee: University of CincinnatiInventor: Edward A. Deutsch
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Patent number: 4894182Abstract: An improved organophillic clay gellant which is the reaction product of a smectite-type clay, an organic cation and, optionally, an organic anion. The cation from the smectite-type clay, the anion from the organic cation and, if present, the cation from the organic anion form a by-product which is water, a gas, an insoluble compound or a mixture thereof. The organophilic clay gellant can exhibit improved efficiency and dispersibility. In a process for preparing an organophilic clay gellant which constitutes a further aspect of the present invention, significant advantages can be observed since the liquid remaining after the organophilic clay gellant is separated from the reaction mixture can be recycled for further use without detrimental effect on the quality of the organophilic clay gellant thereafter produced.Type: GrantFiled: October 19, 1987Date of Patent: January 16, 1990Assignee: NL Chemicals, Inc.Inventors: Charles A. Cody, Steven J. Kemnetz
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Patent number: 4894208Abstract: A system for extracting sodium, particularly radioactive .sup.22 Na, from aluminum utilizes a monel exhaust system for exhausting sodium vapor emitted from a molten aluminum target, in a draft of helium gas. The aluminum target is heated until it is melted in a graphite support cup. The graphite support does not react with the sodium. Moreover, the graphite is understood to be permeable to the helium gas, its porosity being believed to provide the significant advantage that the graphite holder will not absorb much of the sodium vapor. The use of graphite avoids a disadvantageous monel-aluminum reaction whereby an alloy from which sodium cannot be distilled is formed. The resulting sodium vapor is precipitated in a monel exhaust tube which is subjected to temperature control. Sodium can be rinsed from the monel exhaust tube with water.Type: GrantFiled: July 14, 1988Date of Patent: January 16, 1990Assignee: The University of MichiganInventors: Henry C. Griffin, Thomas D. Steiger
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Patent number: 4894446Abstract: Homoleptic bis (.pi.-arene) yttrium or lanthanide complexes of formula ML.sub.2, wherein M is yttrium or a lanthanide metal and the L ligands are di or trisubstituted benzene derivatives, are provided. Certain of the complexes are volatile and are therefore of interest in the chemical vapour deposition. A process for their manufacture is described.Type: GrantFiled: June 13, 1988Date of Patent: January 16, 1990Assignee: The British Petroleum Company p.l.c.Inventor: Frederick G. N. Cloke
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Patent number: 4891192Abstract: Process for the purification of reprocessing uranium from which have previously been separated the fission products generated in a nuclear reactor and consisting of eliminating the U232 daughter products appearing during storage, by passing said uranium in its hexafluoride form through a chemically inert porous material.Type: GrantFiled: August 26, 1988Date of Patent: January 2, 1990Assignee: Uranium PechineyInventors: Alain Sarda, Jean-Pierre Segaud
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Patent number: 4889663Abstract: For manufacturing uranium oxide based nuclear fuel pellets, a fine and reactive U.sub.3 O.sub.8 powder is mixed with a fine UO.sub.2 powder obtained by dry conversion. The U.sub.3 O.sub.8 is obtained by oxidation in air of UO.sub.2 obtained by a dry process, at a temperture less than 800.degree. C.Type: GrantFiled: June 10, 1987Date of Patent: December 26, 1989Assignee: Societe Uranium Pechiney, Framatome & Cogema, & CieInventor: Pirsoul Michel
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Patent number: 4882304Abstract: A highly loaded, uniform ceramic composite can be made by first preparing a highly loaded suspension. Due to the particle-particle interactions of a highly concentrated system, virtually any dopant can be added, including other suspensions, fibers, and whiskers. The process is particularly useful for making composites of materials which coagulate when mixed at low concentration.Type: GrantFiled: April 9, 1987Date of Patent: November 21, 1989Assignee: Ceramics Process Systems Corp.Inventors: Bruce E. Novich, John W. Halloran
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Patent number: 4877789Abstract: Compound, corresponding to the formulaC.sub.8 H.sub.17 --(C.tbd.C--CH.sub.2).sub.3 --CH.sub.2 CH.sub.2 CH.sub.2 R O (I)in which R is a C.sub.1 -C.sub.8 lower alkoxy or C.sub.4 -C.sub.6 cycloalkoxy group, substituted with one or more hydroxyl groups and/or interrupted by one or more hetero atoms chosen from oxygen and sulphur, an amino group of structure ##STR1## in which R.sub.1 or R.sub.2, which may be identical or different, denote a hydrogen atom or a linear or branched C.sub.1 -C.sub.8 lower alkyl radical, optionally interrupted by one or more hetero atoms chosen from oxygen, sulphur and nitrogen, this alkyl radical being able to be substituted with one or more hydroxyl groups, R.sub.1 and R.sub.2 not being able to denote hydrogen simultaneously, or alternatively R.sub.1 and R.sub.2 form, together with the nitrogen atom, a heterocyclic system optionally containing oxygen, sulphur or nitrogen as an additional hetero atom, one of the radicals R.sub.1 and R.sub.Type: GrantFiled: July 3, 1986Date of Patent: October 31, 1989Assignee: Centre International de Recherches Dermatologiques dite C.I.R.D.Inventors: Braham Shroot, Christopher Hensby, Jean Maignan, Gerard Lang, Serge Restle, Michel Colin
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Patent number: 4876073Abstract: There is provided a generator for short-lived radionuclides. The generator comprises a support, an ion-exchange agent and a parent radionuclide in a steady-state equilibrium with a daughter nuclide, which daughter nuclide can be selectively eluted from said column. A suitable parent radionuclide is .sup.191 OS in equilibrium with .sup.191m Ir. There is also provided a specific Os(VI) complex which has certain advantages.Type: GrantFiled: December 18, 1987Date of Patent: October 24, 1989Assignee: State of Israel, Prime Minister's Office Israel Atomic Energy Commission, Soreq Nuclear Research CenterInventors: David Issachar, Jacob Trumper, Shmuel Abrashkin
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Patent number: 4873021Abstract: An azeotrope or azeotrope-like composition of 1,1,2-trichloro-1,2,2-trifluoroethane (FC-113) and 1,2-dichloro-1,1-difluoroethane (FC-132b), the azeotrope being useful in solvent cleaning applications.Type: GrantFiled: December 30, 1986Date of Patent: October 10, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert A. Gorski, Bernhardt J. Eiseman, Jr., Donovan E. Kvalnes
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Patent number: 4871836Abstract: Boronic acid adducts of radioactive isotopes of rhenium dioxime complexes are useful for labeling biologically active compounds as agents for radiotherapy. These boronic acid adducts of radioactive isotopes of rhenium dioxime complexes have the formulaI. ReX(Y).sub.3 Z,whereinX is an anion;Y is a vicinal dioxime having the formulaII. ##STR1## or a pharmaceutically acceptable salt thereof, and R.sub.1 and R.sub.2 are each independently hydrogen, halogen, alkyl, aryl, amino or a 5 or 6-membered nitrogen or oxygen containing heterocycle, or together R.sub.1 and R.sub.2 are --CR.sub.8 R.sub.9).sub.n --wherein n is 3, 4, 5 or 6 and R.sub.8 and R.sub.9 are each independently hydrogen or alkyl;Z is a boron derivative having the formulaIII. B--R.sub.3wherein R.sub.3 is hydroxy, alkyl, alkenyl, cycloalkyl, cycloaLkenyl, alkoxy, carboxyalkyl, carboxyalkenyl, hydroxyalkyl, hydroxyalkenyl, alkoxyalkyl, alkoxyalkenyl, haloalkyl, haloalkenyl, aryl, arylalkyl or (R.sub.4 R.sub.5 N)-alkyl and R.sub.4 and R.sub.Type: GrantFiled: October 13, 1987Date of Patent: October 3, 1989Assignee: E. R. Squibb & Sons, Inc.Inventors: Lynn C. Francesconi, Elizabeth N. Treher
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Patent number: 4871518Abstract: This invention can treat a uranium-containing solution of high or low concentration and/or the waste generated from uranium conversion processes, etc. It is characterized by the use of acorns, nuts of oak tree, which can be easily obtained in our botanical system. By coprecipitating the uranium or other heavy metal elements with the extract of acorns, this invention can not only recover the uranium of other heavy metal elements but also can reduce them before being discharged to the environmental radioactivity level.Type: GrantFiled: December 21, 1987Date of Patent: October 3, 1989Assignee: Korea Advanced Energy Reasearch InstituteInventors: Myongwhan Yoon, Seongtae Whang, Insoon Chang, Pilsoon Han
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Patent number: 4867902Abstract: An oxygen generating microencapsulated composition includes an oxygen generating core material and a coating which is water swellable. When exposed to water, the coating ruptures in an exfoliating manner, exposing the core material to water and thereby generating oxygen. The rate of oxygen release from the microcapsule can be controlled by altering wall continuity, thickness, capsule diameter, and coating characteristics. In other embodiments, combustion resistant materials are included in the wall material.Type: GrantFiled: March 23, 1988Date of Patent: September 19, 1989Assignee: Z-Gard, Inc.Inventor: Donald H. Russell
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Patent number: 4867951Abstract: An organic extracting solution and an extraction method useful for separating elements of the actinide series of the periodic table from elements of the lanthanide series, where both are in trivalent form. The extracting solution consists of a primary ligand and a secondary ligand, preferably in an organic solvent. The primary ligand is a substituted monothio-1,3-dicarbonyl, which includes a substituted 4-acyl-2-pyrazolin-5-thione, such as 4-benzoyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-thione (BMPPT). The secondary ligand is a substituted phosphine oxide, such as trioctylphosphine oxide (TOPO).Type: GrantFiled: March 31, 1988Date of Patent: September 19, 1989Assignee: The United States of America as represented by the United States Department of EnergyInventors: Barbara F. Smith, Gordon D. Jarvinen, Robert R. Ryan
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Patent number: 4868288Abstract: The invention relates to a process for the preparation of compounds of formula Ia[R.sup.1 FeR.sup.2' ].sup..sym..sub.q [LQ.sub.m ].sup.q.crclbar.(Ia),wherein R.sup.1 is a .pi.-arene, R.sup.2' is an anion of a .pi.-arene, L is a divalent to heptavalent metal or non-metal, Q is a halogen atom, q is an integer from 1 to 3 and m is an integer corresponding to the valency of L+q, said process comprises reacting an uncharged .pi.-complex of the formula IIIa[(R.sup.2').sub.2 Fe] (IIIa)with a .pi.arene R.sup.1 is in the presence of Al and a Lewis-acid followed by treatment with an acid or a salt of an acid of the anion [LQ.sub.m ].sup.q-, the improvement consisting essentially of using TiCl.sub.4 as a Lewis-acid.Type: GrantFiled: September 30, 1988Date of Patent: September 19, 1989Assignee: Ciba-Geigy CorporationInventor: Kurt Meier
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Patent number: 4865759Abstract: A dry bleach product is based upon diperacid, particularly diperoxydodecanedioic acid. The dry product comprises separate granular, particulate and beaded components wherein the granular component is diperacid stabilized with an exotherm control agent, diluent and a binder that includes unneutralized polymeric acid. The beaded component is fragrance admixed with a water soluble starch; the particulate components include an agglomerated extender or bulking agent, a pH control agent, and protected fluorescent whitening agents, all as separate particulate components. The water content of the granular diperacid is carefully controlled, as is the ratio of exotherm control agent to diperacid.Type: GrantFiled: November 21, 1988Date of Patent: September 12, 1989Assignee: The Clorox CompanyInventors: Thomas S. Coyne, Daniel H. Klapprott, Eric A. Lutkin, Frances E. Mitchell, Ute H. Riggin, Dale S. Steichen, Suzanne M. Thompson
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Patent number: 4865760Abstract: Granular calcium hypochlorite containing from about 0.001 to about 1.0 weight percent of finely-divided polyfluorinated polymer, e.g., polytetrafluoroethylene, dispersed throughout the granules is described. The product may be compressed and formed into shaped articles, e.g., tablets. The granules may be prepared by admixing the polyfluorinated polymer with particulate calcium hypochlorite, compacting the mixture and granulating the compacted product. Tablets prepared from the polyfluorinated polymer containing granular clacium hypochlorite dissolve in water at a rate slower than tablets prepared without the polyfluorinated polymer. Finely-divided calcium hypochlorite powder, e.g., powder of less than about 10 microns in size, is rendered more conveyable and compactible by the addition of the finely-divided polyfluorinated polymer; and mixtures of finely-divided calcium hypochlorite powder and particulate calcium hypochlorite is rendered more readily compactible.Type: GrantFiled: April 6, 1988Date of Patent: September 12, 1989Assignee: PPG Industries, Inc.Inventors: Harlan B. Johnson, Charles R. Wiedrich, Ernie I. Allen, Peter P. Howell